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65. Sato F, Togo M, Islam MK, Matsue T, Kosuge J, Fukasaku N, Kurosawa S, Nishizawa M
(2005) Enzyme-based glucose fuel cell using vitamin K3-immobilized polymer as an electron
mediator. Electrochem Commun 7:643–647
66. Milton RD, Hickey DP, Abdellaoui S, Lim K, Wu F, Tan B, Minteer SD (2015) Rational
design of quinones for high power density biofuel cells. Chem Sci 6:4867–4875
67. Pinyou P, Ruff A, Pöller S, Ma S, Ludwig R, Schuhmann W (2016) Design of an Os complexmodified hydrogel with optimized redox potential for biosensors and biofuel cells. Chem Eur
J 22:5319–5326
68. Silva SD, Shan D, Cosnier S (2004) Improvement of biosensor performances for nitrate
determination using a new hydrophilic poly(pyrrole-viologen) film. Sens Actuat B Chem
103:397–402
69. Nieh CH, Tsujimura S, Shirai O, Kano K (2013a) Electrostatic and steric interaction between
redox polymers and some flavoenzymes in mediated bioelectrocatalysis. J Electroanal Chem
689:26–30
70. Nieh CH, Tsujimura S, Shirai O, Kano K (2013b) Amperometric biosensor based on reductive
H 2 O 2 detection using pentacyanoferrate-bound polymer for creatinine determination. Anal
Chim Acta 767:128–133
71. Contin A, Frasca S, Vivekananthan J, Leimkühler S, Wollenberger U, Plumeré N, Schuhmann
W (2015) A pH responsive redox hydrogel for electrochemical detection of redox silent
biocatalytic processes control of hydrogel solvation. Electroanalysis 27:938–944
72. Pinyou P, Ruff A, Pöller S, Barwe S, Nebel M (2016) Thermoresponsive amperometric glucose
biosensor. Biointerphases 11:011001
73. Heller A (2006) Electron-conducting redox hydrogels: design, characteristics and synthesis.
Curr Opin Chem Biol 10:664–672
74. Ruff A (2017) Redox polymers in bioelectrochemistry: common playgrounds and novel
concepts. Curr Opin Electrochem 5:66–73
75. Barton SC, Kim HH, Binyamin G, Zhang Y, Heller A (2001) Electroreduction of O 2 to water
on the “Wired” laccase cathode. J Phys Chem B 105:11917–11921
76. Barton SC, Kim HH, Binyamin G, Zhang Y, Heller A (2001) The “Wired” laccase cathode:
high current density electroreduction of O 2 to water at +0.7 V (NHE) at pH 5. J Am Chem
Soc 123:5802–5803
77. Tsujimura S, Murata K (2015) Electrochemical oxygen reduction catalyzed by bilirubin
oxidase with the aid of 2,2 -Azinobis(3-ethylbenzothiazolin-6-sulfonate) on a MgO-template
carbon electrode. Electrochim. Acta 180:555–559
78. Sakai K, Kitazumi Y, Shirai O, Kano K (2016) Bioelectrocatalytic formate oxidation and
carbon dioxide reduction at high current density and low overpotential with tungstencontaining formate dehydrogenase and mediators. Electrochem Commun 65:31–34
79. So K, Ozawa H, Onizuka M, Komukai T, Kitazumi Y, Shirai O, Kano K (2017) Highly permeable gas diffusion electrodes with hollow carbon nanotubes for bilirubin oxidase-catalyzed
dioxygen reduction. Electrochim Acta 246:794–799
80. Tsujimura S, Aya K, Kano K (2006) Osmium complex grafted on a carbon electrode surface
as a mediator for a bioelectrocatalytic reaction. Chem Lett 35:1244–1245
81. Tamaki T, Ito T, Yamaguchi T (2007) Immobilization of hydroquinone through a spacer to
polymer grafted on carbon black for a high-surface-area biofuel cell electrode. J Phys Chem
B 111:10312–10319
82. Jeon S, Bruice TC (1992) Redox chemistry of water-soluble iron, manganese, and chromium
metalloporphyrins and acid-base behavior of their lyate axial ligands in aqueous solution:
influence of electronic effects. Inorg Chem 31:4843–4848
83. Bard AJ, Parsons R, Jordan J (1985) Standard potentials in aqueous solution. Marcel Dekker
84. Nakabayashi Y, Omayu A, Yagi S, Nakamura K, Motonaka J (2001) Evaluation of osmium(II)
complexes as electron transfer mediators accessible for amperometric glucose sensors. Anal
Sci 17:945–950
85. Koval CA, Pravata RLA, Reidsema CM (1984) Steric effects in electron-transfer reactions. 1.
Trends in homogeneous rate constants for reactions between members of structurally related
redox series. Inorg Chem 23:545–553
53
65. Sato F, Togo M, Islam MK, Matsue T, Kosuge J, Fukasaku N, Kurosawa S, Nishizawa M
(2005) Enzyme-based glucose fuel cell using vitamin K3-immobilized polymer as an electron
mediator. Electrochem Commun 7:643–647
66. Milton RD, Hickey DP, Abdellaoui S, Lim K, Wu F, Tan B, Minteer SD (2015) Rational
design of quinones for high power density biofuel cells. Chem Sci 6:4867–4875
67. Pinyou P, Ruff A, Pöller S, Ma S, Ludwig R, Schuhmann W (2016) Design of an Os complexmodified hydrogel with optimized redox potential for biosensors and biofuel cells. Chem Eur
J 22:5319–5326
68. Silva SD, Shan D, Cosnier S (2004) Improvement of biosensor performances for nitrate
determination using a new hydrophilic poly(pyrrole-viologen) film. Sens Actuat B Chem
103:397–402
69. Nieh CH, Tsujimura S, Shirai O, Kano K (2013a) Electrostatic and steric interaction between
redox polymers and some flavoenzymes in mediated bioelectrocatalysis. J Electroanal Chem
689:26–30
70. Nieh CH, Tsujimura S, Shirai O, Kano K (2013b) Amperometric biosensor based on reductive
H 2 O 2 detection using pentacyanoferrate-bound polymer for creatinine determination. Anal
Chim Acta 767:128–133
71. Contin A, Frasca S, Vivekananthan J, Leimkühler S, Wollenberger U, Plumeré N, Schuhmann
W (2015) A pH responsive redox hydrogel for electrochemical detection of redox silent
biocatalytic processes control of hydrogel solvation. Electroanalysis 27:938–944
72. Pinyou P, Ruff A, Pöller S, Barwe S, Nebel M (2016) Thermoresponsive amperometric glucose
biosensor. Biointerphases 11:011001
73. Heller A (2006) Electron-conducting redox hydrogels: design, characteristics and synthesis.
Curr Opin Chem Biol 10:664–672
74. Ruff A (2017) Redox polymers in bioelectrochemistry: common playgrounds and novel
concepts. Curr Opin Electrochem 5:66–73
75. Barton SC, Kim HH, Binyamin G, Zhang Y, Heller A (2001) Electroreduction of O 2 to water
on the “Wired” laccase cathode. J Phys Chem B 105:11917–11921
76. Barton SC, Kim HH, Binyamin G, Zhang Y, Heller A (2001) The “Wired” laccase cathode:
high current density electroreduction of O 2 to water at +0.7 V (NHE) at pH 5. J Am Chem
Soc 123:5802–5803
77. Tsujimura S, Murata K (2015) Electrochemical oxygen reduction catalyzed by bilirubin
oxidase with the aid of 2,2 -Azinobis(3-ethylbenzothiazolin-6-sulfonate) on a MgO-template
carbon electrode. Electrochim. Acta 180:555–559
78. Sakai K, Kitazumi Y, Shirai O, Kano K (2016) Bioelectrocatalytic formate oxidation and
carbon dioxide reduction at high current density and low overpotential with tungstencontaining formate dehydrogenase and mediators. Electrochem Commun 65:31–34
79. So K, Ozawa H, Onizuka M, Komukai T, Kitazumi Y, Shirai O, Kano K (2017) Highly permeable gas diffusion electrodes with hollow carbon nanotubes for bilirubin oxidase-catalyzed
dioxygen reduction. Electrochim Acta 246:794–799
80. Tsujimura S, Aya K, Kano K (2006) Osmium complex grafted on a carbon electrode surface
as a mediator for a bioelectrocatalytic reaction. Chem Lett 35:1244–1245
81. Tamaki T, Ito T, Yamaguchi T (2007) Immobilization of hydroquinone through a spacer to
polymer grafted on carbon black for a high-surface-area biofuel cell electrode. J Phys Chem
B 111:10312–10319
82. Jeon S, Bruice TC (1992) Redox chemistry of water-soluble iron, manganese, and chromium
metalloporphyrins and acid-base behavior of their lyate axial ligands in aqueous solution:
influence of electronic effects. Inorg Chem 31:4843–4848
83. Bard AJ, Parsons R, Jordan J (1985) Standard potentials in aqueous solution. Marcel Dekker
84. Nakabayashi Y, Omayu A, Yagi S, Nakamura K, Motonaka J (2001) Evaluation of osmium(II)
complexes as electron transfer mediators accessible for amperometric glucose sensors. Anal
Sci 17:945–950
85. Koval CA, Pravata RLA, Reidsema CM (1984) Steric effects in electron-transfer reactions. 1.
Trends in homogeneous rate constants for reactions between members of structurally related
redox series. Inorg Chem 23:545–553