52
2 MET-Type Bioelectrocatalysis
46. Heller A (1990) Electrical wiring of redox enzymes. Acc Chem Res 23:128–134
47. Vreeke M, Maidan R, Heller A (1992) Hydrogen peroxide and β-nicotinamide adenine
dinucleotide sensing amperometric electrodes based on electrical connection of horseradish
peroxidase redox centers to electrodes through a three-dimensional electron relaying polymer
network. Anal Chem 64:3084–3090
48. Ye MHL, Olsthoorn AJJ, Schuhmann W, Schmidt HL, Duine JA, Heller A (1993) High current
density “Wired” quinoprotein glucose dehydrogenase electrode. Anal Chem 65:238–241
49. Tsujimura S, Murata K, Akatsuka W (2014) exceptionally high glucose current on a hierarchically structured porous carbon electrode with “Wired” flavin adenine dinucleotide-dependent
glucose dehydrogenase. J Am Chem Soc 136:14432–14437
50. Mano N, Poulpiquet AD (2018) O 2 reduction in enzymatic biofuel cells. Chem Rev 118:2392–
2468
51. Zafar MN, Tasca F, Boland S, Kujawa M, Patel I, Peterbauer CK, Leech D, Gorton L (2010)
Wiring of pyranose dehydrogenase with osmium polymers of different redox potentials.
Bioelectrochemistry 80:38–42
52. Kenausis G, Chen Q, Heller A (1997) Electrochemical glucose and lactate sensors based on
“Wired” thermostable soybean peroxidase operating continuously and stably at 37 °C. Anal
Chem 69:1054–1060
53. Antiochia R, Gorton L (2014) A new osmium-polymer modified screen-printed graphene
electrode for fructose detection. Sens Actuat B Chem 195:287–293
54. Campbell AS, Murata H, Carmali S, Matyjaszewski K, Islam MF, Russell AJ (2016) Polymerbased protein engineering grown ferrocene-containing redox polymers improve current
generation in an enzymatic biofuel cell. Biosens Bioelectron 86:446–453
55. Knoche KL, Hickey DP, Milton RD, Curchoe CL, Minteer SD (2016) Hybrid glucose/O 2
biobattery and supercapacitor utilizing a pseudocapacitive dimethylferrocene redox polymer
at the bioanode. ACS Energy Lett. 1:380–385
56. Koide S, Yokoyama K (1999) Electrochemical characterization of an enzyme electrode based
on a ferrocene-containing redox polymer. J Electroanal Chem 468:193–201
57. Nieh CH, Kitazumi Y, Shirai O, Kano K (2013) Sensitive d-amino acid biosensor based
on oxidase/peroxidase system mediated by pentacyanoferrate-bound polymer. Biosens
Bioelectron 47:350–355
58. Tapia C, Milton RD, Pankratova G, Minteer SD, Åkerlund H-E, Leech D, De Lacey AL,
Pita M, Gorton L (2017) Wiring of photosystem I and hydrogenase on an electrode for
photoelectrochemical H 2 production by using redox polymers for relatively positive onset
potential. ChemElectroChem 4:90–95
59. Eng LH, Elmgren M, Komlos P, Nordling M, Lindquist SE, Neujahr HY (1994) Viologenbased redox polymer for contacting the low-potential redox enzyme hydrogenase at an
electrode surface. J Phys Chem 98:7068–7072
60. Oughli AA, Conzuelo F, Winkler M, Happe T, Lubitz W, Schuhmann W, Rüdiger O, Plumeré N
(2015) A redox hydrogel protects the O 2 -sensitive [FeFe]-hydrogenase from Chlamydomonas
reinhardtii from oxidative damage. Angew Chem Int Ed 54:12329–12333
61. Plumeré N, Rüdiger O, Oughli AA, Williams R, Vivekananthan J, Pöller S, Schuhmann W,
Lubitz W (2014) A redox hydrogel protects hydrogenase from high-potential deactivation
and oxygen damage. Nat Chem 6:822–827
62. Sakai K, Kitazumi Y, Shirai O, Takagi K, Kano K (2017) High-power formate/dioxygen
biofuel cell based on mediated electron transfer type bioelectrocatalysis. ACS Catal 7:5668–
5673
63. Pinyou P, Ruff A, Pöller S, Alsaoub S, Leimkühler S, Wollenberger U, Schuhmann W (2016)
Wiring of the aldehyde oxidoreductase PaoABC to electrode surfaces via entrapment in low
potential phenothiazine-modified redox polymers. Bioelectrochemistry 109:24–30
64. Abdellaoui S, Milton RD, Quah T, Minteer SD (2016) NAD-dependent dehydrogenase
bioelectrocatalysis: the ability of a naphthoquinone redox polymer to regenerate NAD. Chem
Commun 52:1147–1150
2 MET-Type Bioelectrocatalysis
46. Heller A (1990) Electrical wiring of redox enzymes. Acc Chem Res 23:128–134
47. Vreeke M, Maidan R, Heller A (1992) Hydrogen peroxide and β-nicotinamide adenine
dinucleotide sensing amperometric electrodes based on electrical connection of horseradish
peroxidase redox centers to electrodes through a three-dimensional electron relaying polymer
network. Anal Chem 64:3084–3090
48. Ye MHL, Olsthoorn AJJ, Schuhmann W, Schmidt HL, Duine JA, Heller A (1993) High current
density “Wired” quinoprotein glucose dehydrogenase electrode. Anal Chem 65:238–241
49. Tsujimura S, Murata K, Akatsuka W (2014) exceptionally high glucose current on a hierarchically structured porous carbon electrode with “Wired” flavin adenine dinucleotide-dependent
glucose dehydrogenase. J Am Chem Soc 136:14432–14437
50. Mano N, Poulpiquet AD (2018) O 2 reduction in enzymatic biofuel cells. Chem Rev 118:2392–
2468
51. Zafar MN, Tasca F, Boland S, Kujawa M, Patel I, Peterbauer CK, Leech D, Gorton L (2010)
Wiring of pyranose dehydrogenase with osmium polymers of different redox potentials.
Bioelectrochemistry 80:38–42
52. Kenausis G, Chen Q, Heller A (1997) Electrochemical glucose and lactate sensors based on
“Wired” thermostable soybean peroxidase operating continuously and stably at 37 °C. Anal
Chem 69:1054–1060
53. Antiochia R, Gorton L (2014) A new osmium-polymer modified screen-printed graphene
electrode for fructose detection. Sens Actuat B Chem 195:287–293
54. Campbell AS, Murata H, Carmali S, Matyjaszewski K, Islam MF, Russell AJ (2016) Polymerbased protein engineering grown ferrocene-containing redox polymers improve current
generation in an enzymatic biofuel cell. Biosens Bioelectron 86:446–453
55. Knoche KL, Hickey DP, Milton RD, Curchoe CL, Minteer SD (2016) Hybrid glucose/O 2
biobattery and supercapacitor utilizing a pseudocapacitive dimethylferrocene redox polymer
at the bioanode. ACS Energy Lett. 1:380–385
56. Koide S, Yokoyama K (1999) Electrochemical characterization of an enzyme electrode based
on a ferrocene-containing redox polymer. J Electroanal Chem 468:193–201
57. Nieh CH, Kitazumi Y, Shirai O, Kano K (2013) Sensitive d-amino acid biosensor based
on oxidase/peroxidase system mediated by pentacyanoferrate-bound polymer. Biosens
Bioelectron 47:350–355
58. Tapia C, Milton RD, Pankratova G, Minteer SD, Åkerlund H-E, Leech D, De Lacey AL,
Pita M, Gorton L (2017) Wiring of photosystem I and hydrogenase on an electrode for
photoelectrochemical H 2 production by using redox polymers for relatively positive onset
potential. ChemElectroChem 4:90–95
59. Eng LH, Elmgren M, Komlos P, Nordling M, Lindquist SE, Neujahr HY (1994) Viologenbased redox polymer for contacting the low-potential redox enzyme hydrogenase at an
electrode surface. J Phys Chem 98:7068–7072
60. Oughli AA, Conzuelo F, Winkler M, Happe T, Lubitz W, Schuhmann W, Rüdiger O, Plumeré N
(2015) A redox hydrogel protects the O 2 -sensitive [FeFe]-hydrogenase from Chlamydomonas
reinhardtii from oxidative damage. Angew Chem Int Ed 54:12329–12333
61. Plumeré N, Rüdiger O, Oughli AA, Williams R, Vivekananthan J, Pöller S, Schuhmann W,
Lubitz W (2014) A redox hydrogel protects hydrogenase from high-potential deactivation
and oxygen damage. Nat Chem 6:822–827
62. Sakai K, Kitazumi Y, Shirai O, Takagi K, Kano K (2017) High-power formate/dioxygen
biofuel cell based on mediated electron transfer type bioelectrocatalysis. ACS Catal 7:5668–
5673
63. Pinyou P, Ruff A, Pöller S, Alsaoub S, Leimkühler S, Wollenberger U, Schuhmann W (2016)
Wiring of the aldehyde oxidoreductase PaoABC to electrode surfaces via entrapment in low
potential phenothiazine-modified redox polymers. Bioelectrochemistry 109:24–30
64. Abdellaoui S, Milton RD, Quah T, Minteer SD (2016) NAD-dependent dehydrogenase
bioelectrocatalysis: the ability of a naphthoquinone redox polymer to regenerate NAD. Chem
Commun 52:1147–1150