References
15
67. Kaga A, Chiba S (2017) Engaging radicals in transition metal-catalyzed cross-coupling with
alkyl electrophiles: recent advances. ACS Catal 7:4697–4706
68. Lautens M, Klute W, Tam W (1996) Transition metal-mediated cycloaddition reactions. Chem
Rev 96:49–92
69. Müller TE, Grosche M, Herdtweck E, Pleier A-K, Walter E, Yan Y-K (2000) Developing
transition-metal catalysts for the intramolecular hydroamination of alkynes. Organometallics
19:170–183
70. Park Y, Kim Y, Chang S (2017) Transition metal-catalyzed C–H amination: scope, mechanism,
and applications. Chem Rev 117:9247–9301
71. Park YJ, Park JW, Jun CH (2008) Metal-organic cooperative catalysis in C–H and C–C bond
activation and its concurrent recovery. Acc Chem Res 41:222–234
72. Saint-Denis TG, Zhu RY, Chen G, Wu QF, Yu JQ (2018) Enantioselective C(sp(3))H bond
activation by chiral transition metal catalysts. Science 359
73. Wang F, Yu S, Li X (2016) Transition metal-catalysed couplings between arenes and strained or
reactive rings: combination of C–H activation and ring scission. Chem Soc Rev 45:6462–6477
74. Xu X, Doyle MP (2014) The [3 + 3]-cycloaddition alternative for heterocycle syntheses:
catalytically generated metalloenolcarbenes as dipolar adducts. Acc Chem Res 47:1396–1405
75. Kakiuchi F, Murai S, Murai S, Alper H, Gossage RA, Grushin VV, Hidai M, Ito Y, Jones
WD, Kakiuchi F, van Koten G, Lin YS (1999) Activation of C–H bonds: catalytic reactions.
Activation of unreactive bonds and organic synthesis. Springer, Berlin, pp 47–79
76. Huang Z, Lim HN, Mo F, Young MC, Dong G (2015) Transition metal-catalyzed ketonedirected or mediated C–H functionalization. Chem Soc Rev 44:7764–7786
77. Ritleng V, Sirlin C, Pfeffer M (2002) Ru-, Rh-, and Pd-catalyzed C–C bond formation
involving C–H activation and addition on unsaturated substrates: reactions and mechanistic
aspects. Chem Rev 102:1731–1770
78. Shilov AE, Shul’pin GB (1997) Activation of cminus signH bonds by metal complexes. Chem
Rev 97:2879–2932
79. Alberico D, Scott ME, Lautens M (2007) Aryl-aryl bond formation by transition-metalcatalyzed direct arylation. Chem Rev 107:174–238
80. Bellina F, Rossi R (2010) Transition metal-catalyzed direct arylation of substrates with activated sp3-hybridized C–H bonds and some of their synthetic equivalents with aryl halides
and pseudohalides. Chem Rev 110:1082–1146
81. Chen F, Wang T, Jiao N (2014) Recent advances in transition-metal-catalyzed functionalization of unstrained carbon-carbon bonds. Chem Rev 114:8613–8661
82. Cho SH, Kim JY, Kwak J, Chang S (2011) Recent advances in the transition metal-catalyzed
twofold oxidative C–H bond activation strategy for C–C and C–N bond formation. Chem Soc
Rev 40:5068–5083
83. Gao DW, Gu Q, Zheng C, You SL (2017) Synthesis of planar chiral ferrocenes via transitionmetal-catalyzed direct C–H bond functionalization. Acc Chem Res 50:351–365
84. Iwai T, Sawamura M (2015) Transition-metal-catalyzed site-selective C–H functionalization
of quinolines beyond C2 selectivity. ACS Catal 5:5031–5040
85. Miao J, Ge H (2015) Recent advances in first-row-transition-metal-catalyzed Dehydrogenative
cou-pling of C(sp3)-H Bonds. European J Org Chem 2015:7859–7868
86. Zhang X-S, Chen K, Shi Z-J (2014) Transition metal-catalyzed direct nucleophilic addition
of C–H bonds to carbon–heteroatom double bonds. Chem Sci 5:2146–2159
87. He J, Wasa M, Chan KSL, Shao Q, Yu JQ (2017) Palladium-catalyzed transformations of
alkyl C–H bonds. Chem Rev 117:8754–8786
88. Lewis JC, Bergman RG, Ellman JA (2008) Direct functionalization of nitrogen heterocycles
via Rh-catalyzed C–H bond activation. Acc Chem Res 41:1013–1025
89. Newton CG, Wang SG, Oliveira CC, Cramer N (2017) Catalytic enantioselective transformations involving C–H bond cleavage by transition-metal complexes. Chem Rev 117:8908–8976
90. Shan C, Zhu L, Qu LB, Bai R, Lan Y (2018) Mechanistic view of Ru-catalyzed C–H bond
activation and functionalization: computational advances. Chem Soc Rev 47:7552–7576
15
67. Kaga A, Chiba S (2017) Engaging radicals in transition metal-catalyzed cross-coupling with
alkyl electrophiles: recent advances. ACS Catal 7:4697–4706
68. Lautens M, Klute W, Tam W (1996) Transition metal-mediated cycloaddition reactions. Chem
Rev 96:49–92
69. Müller TE, Grosche M, Herdtweck E, Pleier A-K, Walter E, Yan Y-K (2000) Developing
transition-metal catalysts for the intramolecular hydroamination of alkynes. Organometallics
19:170–183
70. Park Y, Kim Y, Chang S (2017) Transition metal-catalyzed C–H amination: scope, mechanism,
and applications. Chem Rev 117:9247–9301
71. Park YJ, Park JW, Jun CH (2008) Metal-organic cooperative catalysis in C–H and C–C bond
activation and its concurrent recovery. Acc Chem Res 41:222–234
72. Saint-Denis TG, Zhu RY, Chen G, Wu QF, Yu JQ (2018) Enantioselective C(sp(3))H bond
activation by chiral transition metal catalysts. Science 359
73. Wang F, Yu S, Li X (2016) Transition metal-catalysed couplings between arenes and strained or
reactive rings: combination of C–H activation and ring scission. Chem Soc Rev 45:6462–6477
74. Xu X, Doyle MP (2014) The [3 + 3]-cycloaddition alternative for heterocycle syntheses:
catalytically generated metalloenolcarbenes as dipolar adducts. Acc Chem Res 47:1396–1405
75. Kakiuchi F, Murai S, Murai S, Alper H, Gossage RA, Grushin VV, Hidai M, Ito Y, Jones
WD, Kakiuchi F, van Koten G, Lin YS (1999) Activation of C–H bonds: catalytic reactions.
Activation of unreactive bonds and organic synthesis. Springer, Berlin, pp 47–79
76. Huang Z, Lim HN, Mo F, Young MC, Dong G (2015) Transition metal-catalyzed ketonedirected or mediated C–H functionalization. Chem Soc Rev 44:7764–7786
77. Ritleng V, Sirlin C, Pfeffer M (2002) Ru-, Rh-, and Pd-catalyzed C–C bond formation
involving C–H activation and addition on unsaturated substrates: reactions and mechanistic
aspects. Chem Rev 102:1731–1770
78. Shilov AE, Shul’pin GB (1997) Activation of cminus signH bonds by metal complexes. Chem
Rev 97:2879–2932
79. Alberico D, Scott ME, Lautens M (2007) Aryl-aryl bond formation by transition-metalcatalyzed direct arylation. Chem Rev 107:174–238
80. Bellina F, Rossi R (2010) Transition metal-catalyzed direct arylation of substrates with activated sp3-hybridized C–H bonds and some of their synthetic equivalents with aryl halides
and pseudohalides. Chem Rev 110:1082–1146
81. Chen F, Wang T, Jiao N (2014) Recent advances in transition-metal-catalyzed functionalization of unstrained carbon-carbon bonds. Chem Rev 114:8613–8661
82. Cho SH, Kim JY, Kwak J, Chang S (2011) Recent advances in the transition metal-catalyzed
twofold oxidative C–H bond activation strategy for C–C and C–N bond formation. Chem Soc
Rev 40:5068–5083
83. Gao DW, Gu Q, Zheng C, You SL (2017) Synthesis of planar chiral ferrocenes via transitionmetal-catalyzed direct C–H bond functionalization. Acc Chem Res 50:351–365
84. Iwai T, Sawamura M (2015) Transition-metal-catalyzed site-selective C–H functionalization
of quinolines beyond C2 selectivity. ACS Catal 5:5031–5040
85. Miao J, Ge H (2015) Recent advances in first-row-transition-metal-catalyzed Dehydrogenative
cou-pling of C(sp3)-H Bonds. European J Org Chem 2015:7859–7868
86. Zhang X-S, Chen K, Shi Z-J (2014) Transition metal-catalyzed direct nucleophilic addition
of C–H bonds to carbon–heteroatom double bonds. Chem Sci 5:2146–2159
87. He J, Wasa M, Chan KSL, Shao Q, Yu JQ (2017) Palladium-catalyzed transformations of
alkyl C–H bonds. Chem Rev 117:8754–8786
88. Lewis JC, Bergman RG, Ellman JA (2008) Direct functionalization of nitrogen heterocycles
via Rh-catalyzed C–H bond activation. Acc Chem Res 41:1013–1025
89. Newton CG, Wang SG, Oliveira CC, Cramer N (2017) Catalytic enantioselective transformations involving C–H bond cleavage by transition-metal complexes. Chem Rev 117:8908–8976
90. Shan C, Zhu L, Qu LB, Bai R, Lan Y (2018) Mechanistic view of Ru-catalyzed C–H bond
activation and functionalization: computational advances. Chem Soc Rev 47:7552–7576