14
1 Theoretical View of Rh-Catalyzed C–H Functionalization
44. Liu C, Liu D, Lei A (2014) Recent advances of transition-metal catalyzed radical oxidative
cross-couplings. Acc Chem Res 47:3459–3470
45. Liu C, Zhang H, Shi W, Lei A (2011) Bond formations between two nucleophiles: transition
metal catalyzed oxidative cross-coupling reactions. Chem Rev 111:1780–1824
46. Shi W, Liu C, Lei A (2011) Transition-metal catalyzed oxidative cross-coupling reactions to
form C–C bonds involving organometallic reagents as nucleophiles. Chem Soc Rev 40:2761–
2776
47. Yuan Y, Lei A (2019) Electrochemical oxidative cross-coupling with hydrogen evolution
reactions. Acc Chem Res 52:3309–3324
48. McNaught AD, Wilkinson A (1997) Compendium of chemical terminology: IUPAC recommendations. Blackwell Science, Oxford, Malden
49. Cartmell E, Fowles GWA (1996) Valency and molecular structure. D Van Nostrand Co,
Princeton
50. Scudder PH (2013) Electron flow in organic chemistry: a decision based guide to organic
mechanisms. Wiley, New York
51. Cho YH, Zunic V, Senboku H, Olsen M, Lautens M (2006) Rhodium-catalyzed ring-opening
reactions of N-boc-azabenzonorbornadienes with amine nucleophiles. J Am Chem Soc
128:6837–6846
52. Hartwig JF (2008) Evolution of a fourth generation catalyst for the amination and thioetherification of aryl halides. Acc Chem Res 41:1534–1544
53. Hartwig JF (2008) Carbon-heteroatom bond formation catalysed by organometallic
complexes. Nature 455:314–322
54. Staubitz A, Robertson AP, Sloan ME, Manners I (2010) Amine- and phosphine-borane
adducts: new interest in old molecules. Chem Rev 110:4023–4078
55. Watanabe Y, Morisaki Y, Kondo T, Mitsudo Ta TA (1996) Ruthenium complex-controlled
catalytic N-Mono- or N, N-Dialkylation of heteroaromatic amines with alcohols. J Org Chem
61:4214–4218
56. Domingo LR, Saez JA, Zaragoza RJ, Arno M (2008) Understanding the participation of
quadricyclane as nucleophile in polar [2sigma + 2sigma + 2pi] cycloadditions toward
electrophilic pi molecules. J Org Chem 73:8791–8799
57. Muller TE, Hultzsch KC, Yus M, Foubelo F, Tada M (2008) Hydroamination: direct addition
of amines to alkenes and alkynes. Chem Rev 108:3795–3892
58. Rosenberg L (2013) Mechanisms of metal-catalyzed hydrophosphination of alkenes and
alkynes. ACS Catal 3:2845–2855
59. Canty AJ, van Koten G (2002) Mechanisms of d8 organometallic reactions involving
electrophiles and intramolecular assistance by nucleophiles. Acc Chem Res 28:406–413
60. Gring M, Kuhnert M, Langen T, Kitagawa T, Rauer B, Schreitl M, Mazets I, Smith DA,
Demler E, Schmiedmayer J (2012) Relaxation and prethermalization in an isolated quantum
system. Science 337:1318–1322
61. Gunay A, Theopold KH (2010) C–H bond activations by metal oxo compounds. Chem Rev
110:1060–1081
62. Hashiguchi BG, Bischof SM, Konnick MM, Periana RA (2012) Designing catalysts for functionalization of unactivated C–H bonds based on the CH activation reaction. Acc Chem Res
45:885–898
63. Hashiguchi BG, Young KJ, Yousufuddin M, Goddard WA 3rd, Periana RA (2010) Acceleration of nucleophilic CH activation by strongly basic solvents. J Am Chem Soc 132:12542–
12545
64. Liu C, Yuan J, Gao M, Tang S, Li W, Shi R, Lei A (2015) Oxidative coupling between two
hydrocarbons: an update of recent C–H functionalizations. Chem Rev 115:12138–12204
65. Zhu D, Chen L, Fan H, Yao Q, Zhu S (2020) Recent progress on donor and donor-donor
carbenes. Chem Soc Rev 49:908–950
66. Cheng W-M, Shang R (2020) Transition metal-catalyzed organic reactions under visible light:
recent developments and future perspectives. ACS Catal 10:9170–9196
1 Theoretical View of Rh-Catalyzed C–H Functionalization
44. Liu C, Liu D, Lei A (2014) Recent advances of transition-metal catalyzed radical oxidative
cross-couplings. Acc Chem Res 47:3459–3470
45. Liu C, Zhang H, Shi W, Lei A (2011) Bond formations between two nucleophiles: transition
metal catalyzed oxidative cross-coupling reactions. Chem Rev 111:1780–1824
46. Shi W, Liu C, Lei A (2011) Transition-metal catalyzed oxidative cross-coupling reactions to
form C–C bonds involving organometallic reagents as nucleophiles. Chem Soc Rev 40:2761–
2776
47. Yuan Y, Lei A (2019) Electrochemical oxidative cross-coupling with hydrogen evolution
reactions. Acc Chem Res 52:3309–3324
48. McNaught AD, Wilkinson A (1997) Compendium of chemical terminology: IUPAC recommendations. Blackwell Science, Oxford, Malden
49. Cartmell E, Fowles GWA (1996) Valency and molecular structure. D Van Nostrand Co,
Princeton
50. Scudder PH (2013) Electron flow in organic chemistry: a decision based guide to organic
mechanisms. Wiley, New York
51. Cho YH, Zunic V, Senboku H, Olsen M, Lautens M (2006) Rhodium-catalyzed ring-opening
reactions of N-boc-azabenzonorbornadienes with amine nucleophiles. J Am Chem Soc
128:6837–6846
52. Hartwig JF (2008) Evolution of a fourth generation catalyst for the amination and thioetherification of aryl halides. Acc Chem Res 41:1534–1544
53. Hartwig JF (2008) Carbon-heteroatom bond formation catalysed by organometallic
complexes. Nature 455:314–322
54. Staubitz A, Robertson AP, Sloan ME, Manners I (2010) Amine- and phosphine-borane
adducts: new interest in old molecules. Chem Rev 110:4023–4078
55. Watanabe Y, Morisaki Y, Kondo T, Mitsudo Ta TA (1996) Ruthenium complex-controlled
catalytic N-Mono- or N, N-Dialkylation of heteroaromatic amines with alcohols. J Org Chem
61:4214–4218
56. Domingo LR, Saez JA, Zaragoza RJ, Arno M (2008) Understanding the participation of
quadricyclane as nucleophile in polar [2sigma + 2sigma + 2pi] cycloadditions toward
electrophilic pi molecules. J Org Chem 73:8791–8799
57. Muller TE, Hultzsch KC, Yus M, Foubelo F, Tada M (2008) Hydroamination: direct addition
of amines to alkenes and alkynes. Chem Rev 108:3795–3892
58. Rosenberg L (2013) Mechanisms of metal-catalyzed hydrophosphination of alkenes and
alkynes. ACS Catal 3:2845–2855
59. Canty AJ, van Koten G (2002) Mechanisms of d8 organometallic reactions involving
electrophiles and intramolecular assistance by nucleophiles. Acc Chem Res 28:406–413
60. Gring M, Kuhnert M, Langen T, Kitagawa T, Rauer B, Schreitl M, Mazets I, Smith DA,
Demler E, Schmiedmayer J (2012) Relaxation and prethermalization in an isolated quantum
system. Science 337:1318–1322
61. Gunay A, Theopold KH (2010) C–H bond activations by metal oxo compounds. Chem Rev
110:1060–1081
62. Hashiguchi BG, Bischof SM, Konnick MM, Periana RA (2012) Designing catalysts for functionalization of unactivated C–H bonds based on the CH activation reaction. Acc Chem Res
45:885–898
63. Hashiguchi BG, Young KJ, Yousufuddin M, Goddard WA 3rd, Periana RA (2010) Acceleration of nucleophilic CH activation by strongly basic solvents. J Am Chem Soc 132:12542–
12545
64. Liu C, Yuan J, Gao M, Tang S, Li W, Shi R, Lei A (2015) Oxidative coupling between two
hydrocarbons: an update of recent C–H functionalizations. Chem Rev 115:12138–12204
65. Zhu D, Chen L, Fan H, Yao Q, Zhu S (2020) Recent progress on donor and donor-donor
carbenes. Chem Soc Rev 49:908–950
66. Cheng W-M, Shang R (2020) Transition metal-catalyzed organic reactions under visible light:
recent developments and future perspectives. ACS Catal 10:9170–9196