11 Frustrated Lewis Pair Pedagogy: Expanding Core Undergraduate Curriculum …
399
References
1. Stephan DW, Erker G (2010) Frustrated Lewis Pairs: Metal-Free Hydrogen Activation and
More. Angew Chem, Int Ed 49(1):46–76. https://doi.org/10.1002/anie.200903708
2. Stephan DW, Erker G (2015) Frustrated Lewis Pair Chemistry: Development and Perspectives.
Angew Chem, Int Ed 54(22):6400–6441. https://doi.org/10.1002/anie.201409800
3. Stephan DW (2015) Frustrated Lewis Pairs. J Am Chem Soc 137(32):10018–10032. https://
doi.org/10.1021/jacs.5b06794
4. Welch GC, Juan RRS, Masuda JD, Stephan DW (2006) Reversible, Metal-Free Hydrogen
Activation. Science 314(5802):1124–1126. https://doi.org/10.1126/science.1134230
5. Stephan DW (2012) “Frustrated Lewis Pair” Hydrogenations. Org Biomol Chem 10(30):5740–
5746. https://doi.org/10.1039/c2ob25339a
6. Cardenas AJP, Culotta BJ, Warren TH, Grimme S, Stute A, Fröhlich R, Kehr G, Erker G (2011)
Capture of NO by a Frustrated Lewis Pair: a New Type of Persistent N-Oxyl Radical. Angew
Chem, Int Ed 50(33):7567–7571. https://doi.org/10.1002/anie.201101622
7. Otten E, Neu RC, Stephan DW (2009) Complexation of Nitrous Oxide by Frustrated Lewis
Pairs. J Am Chem Soc 131(29):9918–9919. https://doi.org/10.1021/ja904377v
8. Ye K-Y, Bursch M, Qu Z-W, Daniliuc CG, Grimme S, Kehr G, Erker G (2017) Reversible
Formylborane/SO 2 Coupling at a Frustrated Lewis Pair Framework. Chem Commun
53(3):633–635. https://doi.org/10.1039/c6cc07071j
9. Jian Z, Kehr G, Daniliuc CG, Wibbeling B, Wiegand T, Siedow M, Eckert H, Bursch M,
Grimme S, Erker G (2017) CO-Reduction Chemistry: Reaction of a CO-Derived Formylhydridoborate with Carbon Monoxide, with Carbon Dioxide, and with Dihydrogen. J Am Chem
Soc 139(18):6474–6483. https://doi.org/10.1021/jacs.7b02548
10. Chen J, Falivene L, Caporaso L, Cavallo L, Chen EY-X (2016) Selective Reduction of CO 2 to
CH 4 by Tandem Hydrosilylation with Mixed Al/B Catalysts. J Am Chem Soc 138(16):5321–
5333. https://doi.org/10.1021/jacs.6b01497
11. Fontaine F-G, Stephan DW (2017) On the Concept of Frustrated Lewis Pairs. Philos Trans R
Soc, a 375(2101):20170004. https://doi.org/10.1098/rsta.2017.0004
12. Stephan DW (2016) The Broadening Reach of Frustrated Lewis Pair Chemistry. Science 354
(6317):aaf7229. doi:https://doi.org/10.1126/science.aaf7229
13. Jupp AR, Stephan DW (2019) New Directions for Frustrated Lewis Pair Chemistry. Trends
Chem 1(1):35–48. https://doi.org/10.1016/j.trechm.2019.01.006
14. Paradies J (2019) From Structure to Novel Reactivity in Frustrated Lewis Pairs. Coord Chem
Rev 380:170–183. https://doi.org/10.1016/j.ccr.2018.09.014
15. Rokob TA, Hamza A, Stirling A, Soós T, Pápai I (2008) Turning Frustration into Bond Activation: a Theoretical Mechanistic Study on Heterolytic Hydrogen Splitting by Frustrated Lewis
Pairs. Angew Chem, Int Ed 47(13):2435–2438. https://doi.org/10.1002/anie.200705586
16. Grimme S, Kruse H, Goerigk L, Erker G (2010) The Mechanism of Dihydrogen Activation by
Frustrated Lewis Pairs Revisited. Angew Chem, Int Ed 49(8):1402–1405. https://doi.org/10.
1002/anie.200905484
17. Bakó I, Stirling A, Bálint S, Pápai I (2012) Association of Frustrated Phosphine–Borane Pairs
in Toluene: Molecular Dynamics Simulations. Dalton Trans 41(30):9023–9025. https://doi.
org/10.1039/c2dt30370a
18. Brown LC, Hogg JM, Gilmore M, Moura L, Imberti S, Gärtner S, Gunaratne HQN, O’Donnell
RJ, Artioli N, Holbrey JD, Swad´ zba-Kwa´ sny M (2018) Frustrated Lewis Pairs in Ionic Liquids
and Molecular Solvents – a Neutron Scattering and NMR Study of Encounter Complexes.
Chem Commun 54(63):8689–8692. https://doi.org/10.1039/c8cc03794a
19. Liu L, Cao LL, Shao Y, Ménard G, Stephan DW (2017) A Radical Mechanism for Frustrated
Lewis Pair Reactivity. Chem 3(2):259–267. https://doi.org/10.1016/j.chempr.2017.05.022
20. Liu LL, Stephan DW (2019) Radicals Derived from Lewis Acid/Base Pairs. Chem Soc Rev
48(13):3454–3463. https://doi.org/10.1039/c8cs00940f
399
References
1. Stephan DW, Erker G (2010) Frustrated Lewis Pairs: Metal-Free Hydrogen Activation and
More. Angew Chem, Int Ed 49(1):46–76. https://doi.org/10.1002/anie.200903708
2. Stephan DW, Erker G (2015) Frustrated Lewis Pair Chemistry: Development and Perspectives.
Angew Chem, Int Ed 54(22):6400–6441. https://doi.org/10.1002/anie.201409800
3. Stephan DW (2015) Frustrated Lewis Pairs. J Am Chem Soc 137(32):10018–10032. https://
doi.org/10.1021/jacs.5b06794
4. Welch GC, Juan RRS, Masuda JD, Stephan DW (2006) Reversible, Metal-Free Hydrogen
Activation. Science 314(5802):1124–1126. https://doi.org/10.1126/science.1134230
5. Stephan DW (2012) “Frustrated Lewis Pair” Hydrogenations. Org Biomol Chem 10(30):5740–
5746. https://doi.org/10.1039/c2ob25339a
6. Cardenas AJP, Culotta BJ, Warren TH, Grimme S, Stute A, Fröhlich R, Kehr G, Erker G (2011)
Capture of NO by a Frustrated Lewis Pair: a New Type of Persistent N-Oxyl Radical. Angew
Chem, Int Ed 50(33):7567–7571. https://doi.org/10.1002/anie.201101622
7. Otten E, Neu RC, Stephan DW (2009) Complexation of Nitrous Oxide by Frustrated Lewis
Pairs. J Am Chem Soc 131(29):9918–9919. https://doi.org/10.1021/ja904377v
8. Ye K-Y, Bursch M, Qu Z-W, Daniliuc CG, Grimme S, Kehr G, Erker G (2017) Reversible
Formylborane/SO 2 Coupling at a Frustrated Lewis Pair Framework. Chem Commun
53(3):633–635. https://doi.org/10.1039/c6cc07071j
9. Jian Z, Kehr G, Daniliuc CG, Wibbeling B, Wiegand T, Siedow M, Eckert H, Bursch M,
Grimme S, Erker G (2017) CO-Reduction Chemistry: Reaction of a CO-Derived Formylhydridoborate with Carbon Monoxide, with Carbon Dioxide, and with Dihydrogen. J Am Chem
Soc 139(18):6474–6483. https://doi.org/10.1021/jacs.7b02548
10. Chen J, Falivene L, Caporaso L, Cavallo L, Chen EY-X (2016) Selective Reduction of CO 2 to
CH 4 by Tandem Hydrosilylation with Mixed Al/B Catalysts. J Am Chem Soc 138(16):5321–
5333. https://doi.org/10.1021/jacs.6b01497
11. Fontaine F-G, Stephan DW (2017) On the Concept of Frustrated Lewis Pairs. Philos Trans R
Soc, a 375(2101):20170004. https://doi.org/10.1098/rsta.2017.0004
12. Stephan DW (2016) The Broadening Reach of Frustrated Lewis Pair Chemistry. Science 354
(6317):aaf7229. doi:https://doi.org/10.1126/science.aaf7229
13. Jupp AR, Stephan DW (2019) New Directions for Frustrated Lewis Pair Chemistry. Trends
Chem 1(1):35–48. https://doi.org/10.1016/j.trechm.2019.01.006
14. Paradies J (2019) From Structure to Novel Reactivity in Frustrated Lewis Pairs. Coord Chem
Rev 380:170–183. https://doi.org/10.1016/j.ccr.2018.09.014
15. Rokob TA, Hamza A, Stirling A, Soós T, Pápai I (2008) Turning Frustration into Bond Activation: a Theoretical Mechanistic Study on Heterolytic Hydrogen Splitting by Frustrated Lewis
Pairs. Angew Chem, Int Ed 47(13):2435–2438. https://doi.org/10.1002/anie.200705586
16. Grimme S, Kruse H, Goerigk L, Erker G (2010) The Mechanism of Dihydrogen Activation by
Frustrated Lewis Pairs Revisited. Angew Chem, Int Ed 49(8):1402–1405. https://doi.org/10.
1002/anie.200905484
17. Bakó I, Stirling A, Bálint S, Pápai I (2012) Association of Frustrated Phosphine–Borane Pairs
in Toluene: Molecular Dynamics Simulations. Dalton Trans 41(30):9023–9025. https://doi.
org/10.1039/c2dt30370a
18. Brown LC, Hogg JM, Gilmore M, Moura L, Imberti S, Gärtner S, Gunaratne HQN, O’Donnell
RJ, Artioli N, Holbrey JD, Swad´ zba-Kwa´ sny M (2018) Frustrated Lewis Pairs in Ionic Liquids
and Molecular Solvents – a Neutron Scattering and NMR Study of Encounter Complexes.
Chem Commun 54(63):8689–8692. https://doi.org/10.1039/c8cc03794a
19. Liu L, Cao LL, Shao Y, Ménard G, Stephan DW (2017) A Radical Mechanism for Frustrated
Lewis Pair Reactivity. Chem 3(2):259–267. https://doi.org/10.1016/j.chempr.2017.05.022
20. Liu LL, Stephan DW (2019) Radicals Derived from Lewis Acid/Base Pairs. Chem Soc Rev
48(13):3454–3463. https://doi.org/10.1039/c8cs00940f