28
D. W. Stephan
of Frustrated Lewis Pairs to Nitric Oxide: An Easy Entry to a Unique Family of Aminoxyl
Radicals. J Am Chem Soc 134(24):10156–10168. https://doi.org/10.1021/ja302652a
139. Xu PF, Xu X (2018) Homoleptic Rare-Earth Aryloxide Based Lewis Pairs for Polymerization
of Conjugated Polar Alkenes. ACS Catalysis 8(1):198–202. https://doi.org/10.1021/acscatal.
7b02875
140. Mömming CM, Otten E, Kehr G, Fröhlich R, Grimme S, Stephan DW, Erker G (2009)
Reversible Metal-Free Carbon Dioxide Binding by Frustrated Lewis Pairs. Angew Chem Int
Ed 48(36):6643–6646. https://doi.org/10.1002/anie.200901636
141. Ashley AE, Thompson AL, O’Hare D (2009) Non-Metal-Mediated Homogeneous Hydrogenation of CO 2 to CH 3 OH. Angew Chem Int Ed 48(52):9839–9843. https://doi.org/10.
1002/anie.200905466
142. Dobrovetsky R, Stephan DW (2013) Catalytic Reduction of CO 2 to CO by Using Zinc(II)
and In Situ Generated Carbodiphosphoranes. Angew Chem Int Ed 52(9):2516–2519. https://
doi.org/10.1002/anie.201208817
143. Wang T, Stephan DW (2014) Phosphine Catalyzed Reduction of CO 2 with Boranes. Chem
Commun 50(53):7007–7010. https://doi.org/10.1039/C4cc02103g
144. Courtemanche MA, Legare MA, Maron L, Fontaine FG (2014) Reducing CO 2 to Methanol
Using Frustrated Lewis Pairs: On the Mechanism of Phosphine-Borane-Mediated Hydroboration of CO 2 . J Am Chem Soc 136(30):10708–10717. https://doi.org/10.1021/ja5047846
145. Fontaine FG, Courtemanche MA, Legare MA (2014) Transition-Metal-Free Catalytic Reduction of Carbon Dioxide. Chem Eur J 20(11):2990–2996. https://doi.org/10.1002/chem.201
304376
146. Gomes CD, Blondiaux E, Thuery P, Cantat T (2014) Metal-Free Reduction of CO 2 with
Hydroboranes: Two Efficient Pathways at Play for the Reduction of CO 2 to Methanol. Chem
Eur J 20(23):7098–7106. https://doi.org/10.1002/chem.201400349
147. Ghuman KK, Wood TE, Hoch LB, Mims CA, Ozin GA, Singh CV (2015) Illuminating CO 2
Reduction on Frustrated Lewis Pair Surfaces: Investigating the Role of Surface Hydroxides and Oxygen Vacancies on Nanocrystalline In 2 O 3-x (OH) y . Phys Chem Chem Phys
17(22):14623–14635. https://doi.org/10.1039/c5cp02613j
148. Ghuman KK, Hoch LB, Szymanski P, Loh JY, Kherani NP, El-Sayed MA, Ozin GA, Singh
CV (2016) Photoexcited Surface Frustrated Lewis Pairs for Heterogeneous Photocatalytic
CO 2 Reduction. J Am Chem Soc 138(4):1206–1214. https://doi.org/10.1021/jacs.5b10179
149. Caputo CB, Stephan DW (2012) Activation of Alkyl C-F Bonds by B(C 6 F 5 ) 3 : Stoichiometric
and Catalytic Transformations. Organometallics 31(1):27–30. https://doi.org/10.1021/Om2
00885c
150. Zhu JT, Pérez M, Stephan DW (2016) C-C Coupling of Benzyl Fluorides Catalyzed by an
Electrophilic Phosphonium Cation. Angew Chem Int Ed 55(29):8448–8451. https://doi.org/
10.1002/anie.201603627
151. Zhu J, Pérez M, Caputo CB, Stephan DW (2016) Use of Trifluoromethyl Groups for Catalytic
Benzylation and Alkylation with Subsequent Hydrodefluorination. Angew Chem Int Ed
55(4):1417–1421. https://doi.org/10.1002/anie.201510494
152. Chitnis S, Kirscher F, Stephan DW (2018) Catalytic Hydrodefluorination of C-F Bonds by
Air-Stable P(III) Lewis Acids. Chem Eur J 4:6543–6546. https://doi.org/10.1002/chem.201
801305
D. W. Stephan
of Frustrated Lewis Pairs to Nitric Oxide: An Easy Entry to a Unique Family of Aminoxyl
Radicals. J Am Chem Soc 134(24):10156–10168. https://doi.org/10.1021/ja302652a
139. Xu PF, Xu X (2018) Homoleptic Rare-Earth Aryloxide Based Lewis Pairs for Polymerization
of Conjugated Polar Alkenes. ACS Catalysis 8(1):198–202. https://doi.org/10.1021/acscatal.
7b02875
140. Mömming CM, Otten E, Kehr G, Fröhlich R, Grimme S, Stephan DW, Erker G (2009)
Reversible Metal-Free Carbon Dioxide Binding by Frustrated Lewis Pairs. Angew Chem Int
Ed 48(36):6643–6646. https://doi.org/10.1002/anie.200901636
141. Ashley AE, Thompson AL, O’Hare D (2009) Non-Metal-Mediated Homogeneous Hydrogenation of CO 2 to CH 3 OH. Angew Chem Int Ed 48(52):9839–9843. https://doi.org/10.
1002/anie.200905466
142. Dobrovetsky R, Stephan DW (2013) Catalytic Reduction of CO 2 to CO by Using Zinc(II)
and In Situ Generated Carbodiphosphoranes. Angew Chem Int Ed 52(9):2516–2519. https://
doi.org/10.1002/anie.201208817
143. Wang T, Stephan DW (2014) Phosphine Catalyzed Reduction of CO 2 with Boranes. Chem
Commun 50(53):7007–7010. https://doi.org/10.1039/C4cc02103g
144. Courtemanche MA, Legare MA, Maron L, Fontaine FG (2014) Reducing CO 2 to Methanol
Using Frustrated Lewis Pairs: On the Mechanism of Phosphine-Borane-Mediated Hydroboration of CO 2 . J Am Chem Soc 136(30):10708–10717. https://doi.org/10.1021/ja5047846
145. Fontaine FG, Courtemanche MA, Legare MA (2014) Transition-Metal-Free Catalytic Reduction of Carbon Dioxide. Chem Eur J 20(11):2990–2996. https://doi.org/10.1002/chem.201
304376
146. Gomes CD, Blondiaux E, Thuery P, Cantat T (2014) Metal-Free Reduction of CO 2 with
Hydroboranes: Two Efficient Pathways at Play for the Reduction of CO 2 to Methanol. Chem
Eur J 20(23):7098–7106. https://doi.org/10.1002/chem.201400349
147. Ghuman KK, Wood TE, Hoch LB, Mims CA, Ozin GA, Singh CV (2015) Illuminating CO 2
Reduction on Frustrated Lewis Pair Surfaces: Investigating the Role of Surface Hydroxides and Oxygen Vacancies on Nanocrystalline In 2 O 3-x (OH) y . Phys Chem Chem Phys
17(22):14623–14635. https://doi.org/10.1039/c5cp02613j
148. Ghuman KK, Hoch LB, Szymanski P, Loh JY, Kherani NP, El-Sayed MA, Ozin GA, Singh
CV (2016) Photoexcited Surface Frustrated Lewis Pairs for Heterogeneous Photocatalytic
CO 2 Reduction. J Am Chem Soc 138(4):1206–1214. https://doi.org/10.1021/jacs.5b10179
149. Caputo CB, Stephan DW (2012) Activation of Alkyl C-F Bonds by B(C 6 F 5 ) 3 : Stoichiometric
and Catalytic Transformations. Organometallics 31(1):27–30. https://doi.org/10.1021/Om2
00885c
150. Zhu JT, Pérez M, Stephan DW (2016) C-C Coupling of Benzyl Fluorides Catalyzed by an
Electrophilic Phosphonium Cation. Angew Chem Int Ed 55(29):8448–8451. https://doi.org/
10.1002/anie.201603627
151. Zhu J, Pérez M, Caputo CB, Stephan DW (2016) Use of Trifluoromethyl Groups for Catalytic
Benzylation and Alkylation with Subsequent Hydrodefluorination. Angew Chem Int Ed
55(4):1417–1421. https://doi.org/10.1002/anie.201510494
152. Chitnis S, Kirscher F, Stephan DW (2018) Catalytic Hydrodefluorination of C-F Bonds by
Air-Stable P(III) Lewis Acids. Chem Eur J 4:6543–6546. https://doi.org/10.1002/chem.201
801305