316
M. Hong
52. Weger M, Grötsch RK, Knaus MG, Giuman MM, Mayer DC, Altmann PJ, Mossou E, Dittrich
B, Pöthig A, Rieger B (2019) Non-Innocent Methylene Linker in Bridged Lewis Pair Initiators.
Angew Chem Int Ed 58:9797–9801. https://doi.org/10.1002/anie.201902833
53. McGraw ML, Clarke RW, Chen EYX (2020) Compounded Sequence Control in Polymerization
of One-Pot Mixtures of Highly Reactive Acrylates by Differentiating Lewis Pairs. J Am Chem
Soc 142:5969–5973. https://doi.org/10.1021/jacs.0c01127
54. Hillmyer MA (2017) The Promise of Plastics from Plants. Science 358:868–870. https://doi.
org/10.1126/science.aao6711
55. Zhu Y, Romain C, Williams CK (2016) Sustainable Polymers from Renewable Resources.
Nature 540:354–362. https://doi.org/10.1038/nature21001
56. Bomgardner MM (2014) Biobased Polymers. Chem Eng News 92:10–14
57. Hong M, Chen EYX (2019) Future Directions for Sustainable Polymers. Trends Chem 1:148–
151. https://doi.org/10.1016/j.trechm.2019.03.004
58. Yao T, Xu P, Xu X (2019) Scandium Complexes Containing β-Diketiminato Ligands with
Pendant Phosphanyl Groups: Competition Between Sc/γ -C [4+2] Cycloaddition and Sc/P
Frustrated Lewis Pair Reactions. Dalton Trans 48:7743–7754. https://doi.org/10.1039/C9D
T01035A
59. McGraw ML, Chen EYX (2018) Catalytic Lewis Pair Polymerization of Renewable Methyl
Crotonate to High-Molecular-Weight Polymers. ACS Catal 8:9877–9887. https://doi.org/10.
1021/acscatal.8b03017
60. Clarke RW, McGraw ML, Gowda RR, Chen EYX (2020) Lewis Pair Polymerization of
Renewable Indenone to Erythro-Ditactic High-T g Polymers with an Upcycling Avenue.
Macromolecules 53:640–648. https://doi.org/10.1021/acs.macromol.9b02285
61. Wang XJ, Hong M (2020) Lewis-Pair-Mediated Selective Dimerization and Polymerization of
Lignocellulose-Based β-Angelica Lactone into Biofuel and Acrylic Bioplastic. Angew Chem
Int Ed 59:2664–2668. https://doi.org/10.1002/anie.201913136
62. Hillmyer MA, Tolman WB (2014) Aliphatic Polyester Block Polymers: Renewable, Degradable, and Sustainable. Acc Chem Res 47:2390–2396. https://doi.org/10.1021/ar500121d
63. Lecomte P, Jérôme C (2011) Recent Developments in Ring-Opening Polymerization of
Lactones. In: Rieger B., Künkel A., Coates G., Reichardt R., Dinjus E., Zevaco T. (eds) Synthetic
Biodegradable Polymers. Adv Polym Sci 245:173–217. https://doi.org/10.1007/12_2011_144
64. Dechy-Cabaret O, Martin-Vaca B, Bourissou D (2004) Controlled Ring-Opening Polymerization of Lactide and Glycolide. Chem Rev 104:6147–6176. https://doi.org/10.1021/cr0
40002s
65. Thomas CM (2010) Stereocontrolled Ring-Opening Polymerization of Cyclic Esters: Synthesis
of New Polyester Microstructures. Chem Soc Rev 39:165–173. https://doi.org/10.1039/B81
0065A
66. Stanford MJ, Dove AP (2010) Stereocontrolled Ring-Opening Polymerisation of Lactide. Chem
Soc Rev 39:486–494. https://doi.org/10.1039/B815104K
67. Dove AP (2012) Organic Catalysis for Ring-Opening Polymerization. ACS Macro Lett 1:1409–
1412. https://doi.org/10.1021/mz3005956
68. Fèvre M, Vignolle J, Gnanou Y, Taton D (2012) Organocatalyzed Ring-Opening Polymerizations. In: Möller M, Matyjaszewski K (eds) Polymer Science: A Comprehensive Reference.
Elsevier, Amsterdam, 4:67–115. https://doi.org/10.1016/B978-0-444-53349-4.00119-9
69. Nie Y, Wang P, Du H, Meng W, Yang J (2018) An Efficient Strategy for Achieving Controlled
Ring-Opening Polymerization of O-Carboxyanhydrides via Amine Initiation in Collaboration
with Metal Alkoxide Catalysis. Polym Chem 9:5014–5023. https://doi.org/10.1039/C8PY01
090K
70. Jiang J, Cui Y, Lu Y, Zhang B, Pan X, Wu J (2020) Weak Lewis Pairs as Catalysts for Highly
Isoselective Ring-Opening Polymerization of Epimerically Labile rac-O-Carboxyanhydride of
Mandelic Acid. Macromolecules 53:946–955. https://doi.org/10.1021/acs.macromol.9b02302
71. Walther P, Krauß A, Naumann S (2019) Lewis Pair Polymerization of Epoxides via Zwitterionic Species as a Route to High-Molar-Mass Polyethers. Angew Chem Int Ed 58:10737–
10741. https://doi.org/10.1002/anie.201904806
M. Hong
52. Weger M, Grötsch RK, Knaus MG, Giuman MM, Mayer DC, Altmann PJ, Mossou E, Dittrich
B, Pöthig A, Rieger B (2019) Non-Innocent Methylene Linker in Bridged Lewis Pair Initiators.
Angew Chem Int Ed 58:9797–9801. https://doi.org/10.1002/anie.201902833
53. McGraw ML, Clarke RW, Chen EYX (2020) Compounded Sequence Control in Polymerization
of One-Pot Mixtures of Highly Reactive Acrylates by Differentiating Lewis Pairs. J Am Chem
Soc 142:5969–5973. https://doi.org/10.1021/jacs.0c01127
54. Hillmyer MA (2017) The Promise of Plastics from Plants. Science 358:868–870. https://doi.
org/10.1126/science.aao6711
55. Zhu Y, Romain C, Williams CK (2016) Sustainable Polymers from Renewable Resources.
Nature 540:354–362. https://doi.org/10.1038/nature21001
56. Bomgardner MM (2014) Biobased Polymers. Chem Eng News 92:10–14
57. Hong M, Chen EYX (2019) Future Directions for Sustainable Polymers. Trends Chem 1:148–
151. https://doi.org/10.1016/j.trechm.2019.03.004
58. Yao T, Xu P, Xu X (2019) Scandium Complexes Containing β-Diketiminato Ligands with
Pendant Phosphanyl Groups: Competition Between Sc/γ -C [4+2] Cycloaddition and Sc/P
Frustrated Lewis Pair Reactions. Dalton Trans 48:7743–7754. https://doi.org/10.1039/C9D
T01035A
59. McGraw ML, Chen EYX (2018) Catalytic Lewis Pair Polymerization of Renewable Methyl
Crotonate to High-Molecular-Weight Polymers. ACS Catal 8:9877–9887. https://doi.org/10.
1021/acscatal.8b03017
60. Clarke RW, McGraw ML, Gowda RR, Chen EYX (2020) Lewis Pair Polymerization of
Renewable Indenone to Erythro-Ditactic High-T g Polymers with an Upcycling Avenue.
Macromolecules 53:640–648. https://doi.org/10.1021/acs.macromol.9b02285
61. Wang XJ, Hong M (2020) Lewis-Pair-Mediated Selective Dimerization and Polymerization of
Lignocellulose-Based β-Angelica Lactone into Biofuel and Acrylic Bioplastic. Angew Chem
Int Ed 59:2664–2668. https://doi.org/10.1002/anie.201913136
62. Hillmyer MA, Tolman WB (2014) Aliphatic Polyester Block Polymers: Renewable, Degradable, and Sustainable. Acc Chem Res 47:2390–2396. https://doi.org/10.1021/ar500121d
63. Lecomte P, Jérôme C (2011) Recent Developments in Ring-Opening Polymerization of
Lactones. In: Rieger B., Künkel A., Coates G., Reichardt R., Dinjus E., Zevaco T. (eds) Synthetic
Biodegradable Polymers. Adv Polym Sci 245:173–217. https://doi.org/10.1007/12_2011_144
64. Dechy-Cabaret O, Martin-Vaca B, Bourissou D (2004) Controlled Ring-Opening Polymerization of Lactide and Glycolide. Chem Rev 104:6147–6176. https://doi.org/10.1021/cr0
40002s
65. Thomas CM (2010) Stereocontrolled Ring-Opening Polymerization of Cyclic Esters: Synthesis
of New Polyester Microstructures. Chem Soc Rev 39:165–173. https://doi.org/10.1039/B81
0065A
66. Stanford MJ, Dove AP (2010) Stereocontrolled Ring-Opening Polymerisation of Lactide. Chem
Soc Rev 39:486–494. https://doi.org/10.1039/B815104K
67. Dove AP (2012) Organic Catalysis for Ring-Opening Polymerization. ACS Macro Lett 1:1409–
1412. https://doi.org/10.1021/mz3005956
68. Fèvre M, Vignolle J, Gnanou Y, Taton D (2012) Organocatalyzed Ring-Opening Polymerizations. In: Möller M, Matyjaszewski K (eds) Polymer Science: A Comprehensive Reference.
Elsevier, Amsterdam, 4:67–115. https://doi.org/10.1016/B978-0-444-53349-4.00119-9
69. Nie Y, Wang P, Du H, Meng W, Yang J (2018) An Efficient Strategy for Achieving Controlled
Ring-Opening Polymerization of O-Carboxyanhydrides via Amine Initiation in Collaboration
with Metal Alkoxide Catalysis. Polym Chem 9:5014–5023. https://doi.org/10.1039/C8PY01
090K
70. Jiang J, Cui Y, Lu Y, Zhang B, Pan X, Wu J (2020) Weak Lewis Pairs as Catalysts for Highly
Isoselective Ring-Opening Polymerization of Epimerically Labile rac-O-Carboxyanhydride of
Mandelic Acid. Macromolecules 53:946–955. https://doi.org/10.1021/acs.macromol.9b02302
71. Walther P, Krauß A, Naumann S (2019) Lewis Pair Polymerization of Epoxides via Zwitterionic Species as a Route to High-Molar-Mass Polyethers. Angew Chem Int Ed 58:10737–
10741. https://doi.org/10.1002/anie.201904806