276
A. R. Jupp
40. Hong M, Chen J, Chen EY-X (2018) Polymerization of Polar Monomers Mediated by MainGroup Lewis Acid-Base Pairs. Chem Rev 118:10551–10616. https://doi.org/10.1021/acs.che
mrev.8b00352
41. Hou L, Liang Y, Wang Q, Zhang Y, Dong D, Zhang N (2018) Lewis Pair-Mediated SurfaceInitiated Polymerization. ACS Macro Lett 7:65–69. https://doi.org/10.1021/acsmacrolett.7b0
0903
42. Patrow JG, Wang Y, Dawlaty JM (2018) Interfacial Lewis Acid-Base Adduct Formation
Probed by Vibrational Spectroscopy. J Phys Chem Lett 9:3631–3638. https://doi.org/10.1021/
acs.jpclett.8b00470
43. Xing J-Y, Buffet J-C, Rees NH, Nørby P, O’Hare D (2016) Hydrogen Cleavage by SolidPhase Frustrated Lewis Pairs. Chem Commun 52:10478–10481. https://doi.org/10.1039/C6C
C04937K
44. Wanglee Y-J, Hu J, White RE, Lee M-Y, Stewart SM, Perrotin P, Scott SL (2012) BoraneInduced Dehydration of Silica and the Ensuing Water-Catalyzed Grafting of B(C 6 F 5 ) 3 to Give
a Supported, Single-Site Lewis Acid, ≡ SiOB(C 6 F 5 ) 2 . J Am Chem Soc 134:355–366. https://
doi.org/10.1021/ja207838j
45. Tian J, Wang S, Feng Y, Li J, Collins S (1999) Borane-Functionalized Oxide Supports: Development of Active Supported Metallocene Catalysts at Low Aluminoxane Loading. J Mol Catal
Chem 144:137–150. https://doi.org/10.1016/S1381-1169(98)00341-0
46. Wass DF, Chapman AM (2013) Frustrated Lewis Pairs Beyond the Main Group: Transition Metal-Containing Systems. In: Erker G, Stephan DW (eds) Frustrated Lewis pairs II:
Expanding the Scope. Springer, Berlin, Heidelberg, pp 261–280
47. Flynn SR, Wass DF (2013) Transition Metal Frustrated Lewis Pairs. ACS Catal 3:2574–2581.
https://doi.org/10.1021/cs400754w
48. Campos J (2017) Dihydrogen and Acetylene Activation by a Gold(I)/Platinum(0) Transition
Metal Only Frustrated Lewis Pair. J Am Chem Soc 139:2944–2947. https://doi.org/10.1021/
jacs.7b00491
49. Bullock RM, Chambers GM (2017) Frustration Across the Periodic Table: Heterolytic
Cleavage of Dihydrogen by Metal Complexes. Philos Trans R Soc Math Phys Eng Sci
375:20170002. https://doi.org/10.1098/rsta.2017.0002
50. Habraken ERM, Jupp AR, Brands MB, Nieger M, Ehlers AW, Slootweg JC (2019) Parallels Between Metal-Ligand Cooperativity and Frustrated Lewis Pairs. Eur J Inorg Chem
2019:2436–2442. https://doi.org/10.1002/ejic.201900169
51. Lu G, Zhang P, Sun D, Wang L, Zhou K, Wang Z-X, Guo G-C (2014) Gold Catalyzed
Hydrogenations of Small Imines and Nitriles: Enhanced Reactivity of Au Surface Toward H 2
via Collaboration With a Lewis Base. Chem Sci 5:1082–1090. https://doi.org/10.1039/C3S
C52851K
52. Rokob TA, Hamza A, Stirling A, Pápai I (2009) On the Mechanism of B(C 6 F 5 ) 3 -Catalyzed
Direct Hydrogenation of Imines: Inherent and Thermally Induced Frustration. J Am Chem
Soc 131:2029–2036. https://doi.org/10.1021/ja809125r
53. Arndt S, Rudolph M, Hashmi ASK (2017) Gold-Based Frustrated Lewis Acid/Base Pairs
(FLPs). Gold Bull 50:267–282. https://doi.org/10.1007/s13404-017-0219-7
54. Preti D, Resta C, Squarcialupi S, Fachinetti G (2011) Carbon Dioxide Hydrogenation to
Formic Acid by Using a Heterogeneous Gold Catalyst. Angew Chem Int Ed 50:12551–12554.
https://doi.org/10.1002/anie.201105481
55. Lv X, Lu G, Wang Z-Q, Xu Z-N, Guo G-C (2017) Computational Evidence for Lewis BasePromoted CO 2 Hydrogenation to Formic Acid on Gold Surfaces. ACS Catal 7:4519–4526.
https://doi.org/10.1021/acscatal.7b00277
56. Cano I, Chapman AM, Urakawa A, van Leeuwen PWNM (2014) Air-Stable Gold Nanoparticles Ligated by Secondary Phosphine Oxides for the Chemoselective Hydrogenation of
Aldehydes: Crucial Role of the Ligand. J Am Chem Soc 136:2520–2528. https://doi.org/10.
1021/ja411202h
57. Almora-Barrios N, Cano I, van Leeuwen PWNM, López N (2017) Concerted Chemoselective
Hydrogenation of Acrolein on Secondary Phosphine Oxide Decorated Gold Nanoparticles.
ACS Catal 7:3949–3954. https://doi.org/10.1021/acscatal.7b00355
A. R. Jupp
40. Hong M, Chen J, Chen EY-X (2018) Polymerization of Polar Monomers Mediated by MainGroup Lewis Acid-Base Pairs. Chem Rev 118:10551–10616. https://doi.org/10.1021/acs.che
mrev.8b00352
41. Hou L, Liang Y, Wang Q, Zhang Y, Dong D, Zhang N (2018) Lewis Pair-Mediated SurfaceInitiated Polymerization. ACS Macro Lett 7:65–69. https://doi.org/10.1021/acsmacrolett.7b0
0903
42. Patrow JG, Wang Y, Dawlaty JM (2018) Interfacial Lewis Acid-Base Adduct Formation
Probed by Vibrational Spectroscopy. J Phys Chem Lett 9:3631–3638. https://doi.org/10.1021/
acs.jpclett.8b00470
43. Xing J-Y, Buffet J-C, Rees NH, Nørby P, O’Hare D (2016) Hydrogen Cleavage by SolidPhase Frustrated Lewis Pairs. Chem Commun 52:10478–10481. https://doi.org/10.1039/C6C
C04937K
44. Wanglee Y-J, Hu J, White RE, Lee M-Y, Stewart SM, Perrotin P, Scott SL (2012) BoraneInduced Dehydration of Silica and the Ensuing Water-Catalyzed Grafting of B(C 6 F 5 ) 3 to Give
a Supported, Single-Site Lewis Acid, ≡ SiOB(C 6 F 5 ) 2 . J Am Chem Soc 134:355–366. https://
doi.org/10.1021/ja207838j
45. Tian J, Wang S, Feng Y, Li J, Collins S (1999) Borane-Functionalized Oxide Supports: Development of Active Supported Metallocene Catalysts at Low Aluminoxane Loading. J Mol Catal
Chem 144:137–150. https://doi.org/10.1016/S1381-1169(98)00341-0
46. Wass DF, Chapman AM (2013) Frustrated Lewis Pairs Beyond the Main Group: Transition Metal-Containing Systems. In: Erker G, Stephan DW (eds) Frustrated Lewis pairs II:
Expanding the Scope. Springer, Berlin, Heidelberg, pp 261–280
47. Flynn SR, Wass DF (2013) Transition Metal Frustrated Lewis Pairs. ACS Catal 3:2574–2581.
https://doi.org/10.1021/cs400754w
48. Campos J (2017) Dihydrogen and Acetylene Activation by a Gold(I)/Platinum(0) Transition
Metal Only Frustrated Lewis Pair. J Am Chem Soc 139:2944–2947. https://doi.org/10.1021/
jacs.7b00491
49. Bullock RM, Chambers GM (2017) Frustration Across the Periodic Table: Heterolytic
Cleavage of Dihydrogen by Metal Complexes. Philos Trans R Soc Math Phys Eng Sci
375:20170002. https://doi.org/10.1098/rsta.2017.0002
50. Habraken ERM, Jupp AR, Brands MB, Nieger M, Ehlers AW, Slootweg JC (2019) Parallels Between Metal-Ligand Cooperativity and Frustrated Lewis Pairs. Eur J Inorg Chem
2019:2436–2442. https://doi.org/10.1002/ejic.201900169
51. Lu G, Zhang P, Sun D, Wang L, Zhou K, Wang Z-X, Guo G-C (2014) Gold Catalyzed
Hydrogenations of Small Imines and Nitriles: Enhanced Reactivity of Au Surface Toward H 2
via Collaboration With a Lewis Base. Chem Sci 5:1082–1090. https://doi.org/10.1039/C3S
C52851K
52. Rokob TA, Hamza A, Stirling A, Pápai I (2009) On the Mechanism of B(C 6 F 5 ) 3 -Catalyzed
Direct Hydrogenation of Imines: Inherent and Thermally Induced Frustration. J Am Chem
Soc 131:2029–2036. https://doi.org/10.1021/ja809125r
53. Arndt S, Rudolph M, Hashmi ASK (2017) Gold-Based Frustrated Lewis Acid/Base Pairs
(FLPs). Gold Bull 50:267–282. https://doi.org/10.1007/s13404-017-0219-7
54. Preti D, Resta C, Squarcialupi S, Fachinetti G (2011) Carbon Dioxide Hydrogenation to
Formic Acid by Using a Heterogeneous Gold Catalyst. Angew Chem Int Ed 50:12551–12554.
https://doi.org/10.1002/anie.201105481
55. Lv X, Lu G, Wang Z-Q, Xu Z-N, Guo G-C (2017) Computational Evidence for Lewis BasePromoted CO 2 Hydrogenation to Formic Acid on Gold Surfaces. ACS Catal 7:4519–4526.
https://doi.org/10.1021/acscatal.7b00277
56. Cano I, Chapman AM, Urakawa A, van Leeuwen PWNM (2014) Air-Stable Gold Nanoparticles Ligated by Secondary Phosphine Oxides for the Chemoselective Hydrogenation of
Aldehydes: Crucial Role of the Ligand. J Am Chem Soc 136:2520–2528. https://doi.org/10.
1021/ja411202h
57. Almora-Barrios N, Cano I, van Leeuwen PWNM, López N (2017) Concerted Chemoselective
Hydrogenation of Acrolein on Secondary Phosphine Oxide Decorated Gold Nanoparticles.
ACS Catal 7:3949–3954. https://doi.org/10.1021/acscatal.7b00355