7 Heterogeneous Catalysis by Frustrated Lewis Pairs
275
20. Stephan DW (2016) The Broadening Reach of Frustrated Lewis Pair Chemistry. Science
354:aaf7229. https://doi.org/10.1126/science.aaf7229
21. Scott DJ, Fuchter MJ, Ashley AE (2017) Designing Effective ‘Frustrated Lewis Pair’
Hydrogenation Catalysts. Chem Soc Rev 46:5689–5700. https://doi.org/10.1039/C7CS00
154A
22. Boom DHA, Jupp AR, Slootweg JC (2019) Dehydrogenation of Amine–Boranes Using pBlock Compounds. Chem – Eur J 25:9133–9152. https://doi.org/10.1002/chem.201900679
23. Paradies J (2019) Mechanisms in Frustrated Lewis Pair-Catalyzed Reactions. Eur J Org Chem
2019:283–294. https://doi.org/10.1002/ejoc.201800944
24. Jupp AR, Stephan DW (2019) New Directions for Frustrated Lewis Pair Chemistry. Trends
Chem 1:35–48. https://doi.org/10.1016/j.trechm.2019.01.006
25. Ertl G, Knözinger H, Schüth F, Weitkamp J (2008) Handbook of Heterogeneous Catalysis.
Wiley-VCH, Weinheim, Germany
26. Rothenberg G (2017) Catalysis: Concepts and Green Applications, 2nd edn. Wiley-VCH,
Weinheim, Germany
27. Primo A, Garcia H (2014) Zeolites as Catalysts in Oil Refining. Chem Soc Rev 43:7548–7561.
https://doi.org/10.1039/C3CS60394F
28. Ma Y, Zhang S, Chang C-R, Huang Z-Q, Ho JC, Qu Y (2018) Semi-Solid and Solid Frustrated
Lewis Pair Catalysts. Chem Soc Rev 47:5541–5553. https://doi.org/10.1039/C7CS00691H
29. Szeto KC, Sahyoun W, Merle N, Castelbou JL, Popoff N, Lefebvre F, Raynaud J, Godard
C, Claver C, Delevoye L, Gauvin RM, Taoufik M (2016) Development of Silica-Supported
Frustrated Lewis Pairs: Highly Active Transition Metal-Free Catalysts for the Z-Selective
Reduction of Alkynes. Catal Sci Technol 6:882–889. https://doi.org/10.1039/C5CY01372K
30. Pelletier J, Espinas J, Vu N, Norsic S, Baudouin A, Delevoye L, Trébosc J, Roux EL,
Santini C, Basset J-M, Gauvin RM, Taoufik M (2011) A Well-Defined Silica-Supported
Aluminium Alkyl Through an Unprecedented, Consecutive Two-Step Protonolysis–Alkyl
Transfer Mechanism. Chem Commun 47:2979–2981. https://doi.org/10.1039/C0CC04986G
31. Johnstone TC, Wee GNJH, Stephan DW (2018) Accessing Frustrated Lewis Pair Chemistry
from a Spectroscopically Stable and Classical Lewis Acid-Base Adduct. Angew Chem Int Ed
57:5881–5884. https://doi.org/10.1002/anie.201802385
32. Chernichenko K, Madarász Á, Pápai I, Nieger M, Leskelä M, Repo T (2013) A FrustratedLewis-Pair Approach to Catalytic Reduction of Alkynes to cis-Alkenes. Nat Chem 5:718–723.
https://doi.org/10.1038/nchem.1693
33. Trunk M, Teichert JF, Thomas A (2017) Room-Temperature Activation of Hydrogen by
Semi-Immobilized Frustrated Lewis Pairs in Microporous Polymer Networks. J Am Chem
Soc 139:3615–3618. https://doi.org/10.1021/jacs.6b13147
34. Schmidt J, Werner M, Thomas A (2009) Conjugated Microporous Polymer Networks
via Yamamoto Polymerization. Macromolecules 42:4426–4429. https://doi.org/10.1021/ma9
005473
35. Willms A, Schumacher H, Tabassum T, Qi L, Scott SL, Hausoul PJC, Rose M (2018) Solid
Molecular Frustrated Lewis Pairs in a Polyamine Organic Framework for the Catalytic MetalFree Hydrogenation of Alkenes. ChemCatChem 10:1835–1843. https://doi.org/10.1002/cctc.
201701783
36. Inés B, Palomas D, Holle S, Steinberg S, Nicasio JA, Alcarazo M (2012) Metal-Free Hydrogenation of Electron-Poor Allenes and Alkenes. Angew Chem Int Ed 51:12367–12369. https://
doi.org/10.1002/anie.201205348
37. Mahdi T, Stephan DW (2014) Enabling Catalytic Ketone Hydrogenation by Frustrated Lewis
Pairs. J Am Chem Soc 136:15809–15812. https://doi.org/10.1021/ja508829x
38. Scott DJ, Fuchter MJ, Ashley AE (2014) Nonmetal Catalyzed Hydrogenation of Carbonyl
Compounds. J Am Chem Soc 136:15813–15816. https://doi.org/10.1021/ja5088979
39. Mahdi T, Stephan DW (2015) Facile Protocol for Catalytic Frustrated Lewis Pair Hydrogenation and Reductive Deoxygenation of Ketones and Aldehydes. Angew Chem Int Ed
54:8511–8514. https://doi.org/10.1002/anie.201503087
275
20. Stephan DW (2016) The Broadening Reach of Frustrated Lewis Pair Chemistry. Science
354:aaf7229. https://doi.org/10.1126/science.aaf7229
21. Scott DJ, Fuchter MJ, Ashley AE (2017) Designing Effective ‘Frustrated Lewis Pair’
Hydrogenation Catalysts. Chem Soc Rev 46:5689–5700. https://doi.org/10.1039/C7CS00
154A
22. Boom DHA, Jupp AR, Slootweg JC (2019) Dehydrogenation of Amine–Boranes Using pBlock Compounds. Chem – Eur J 25:9133–9152. https://doi.org/10.1002/chem.201900679
23. Paradies J (2019) Mechanisms in Frustrated Lewis Pair-Catalyzed Reactions. Eur J Org Chem
2019:283–294. https://doi.org/10.1002/ejoc.201800944
24. Jupp AR, Stephan DW (2019) New Directions for Frustrated Lewis Pair Chemistry. Trends
Chem 1:35–48. https://doi.org/10.1016/j.trechm.2019.01.006
25. Ertl G, Knözinger H, Schüth F, Weitkamp J (2008) Handbook of Heterogeneous Catalysis.
Wiley-VCH, Weinheim, Germany
26. Rothenberg G (2017) Catalysis: Concepts and Green Applications, 2nd edn. Wiley-VCH,
Weinheim, Germany
27. Primo A, Garcia H (2014) Zeolites as Catalysts in Oil Refining. Chem Soc Rev 43:7548–7561.
https://doi.org/10.1039/C3CS60394F
28. Ma Y, Zhang S, Chang C-R, Huang Z-Q, Ho JC, Qu Y (2018) Semi-Solid and Solid Frustrated
Lewis Pair Catalysts. Chem Soc Rev 47:5541–5553. https://doi.org/10.1039/C7CS00691H
29. Szeto KC, Sahyoun W, Merle N, Castelbou JL, Popoff N, Lefebvre F, Raynaud J, Godard
C, Claver C, Delevoye L, Gauvin RM, Taoufik M (2016) Development of Silica-Supported
Frustrated Lewis Pairs: Highly Active Transition Metal-Free Catalysts for the Z-Selective
Reduction of Alkynes. Catal Sci Technol 6:882–889. https://doi.org/10.1039/C5CY01372K
30. Pelletier J, Espinas J, Vu N, Norsic S, Baudouin A, Delevoye L, Trébosc J, Roux EL,
Santini C, Basset J-M, Gauvin RM, Taoufik M (2011) A Well-Defined Silica-Supported
Aluminium Alkyl Through an Unprecedented, Consecutive Two-Step Protonolysis–Alkyl
Transfer Mechanism. Chem Commun 47:2979–2981. https://doi.org/10.1039/C0CC04986G
31. Johnstone TC, Wee GNJH, Stephan DW (2018) Accessing Frustrated Lewis Pair Chemistry
from a Spectroscopically Stable and Classical Lewis Acid-Base Adduct. Angew Chem Int Ed
57:5881–5884. https://doi.org/10.1002/anie.201802385
32. Chernichenko K, Madarász Á, Pápai I, Nieger M, Leskelä M, Repo T (2013) A FrustratedLewis-Pair Approach to Catalytic Reduction of Alkynes to cis-Alkenes. Nat Chem 5:718–723.
https://doi.org/10.1038/nchem.1693
33. Trunk M, Teichert JF, Thomas A (2017) Room-Temperature Activation of Hydrogen by
Semi-Immobilized Frustrated Lewis Pairs in Microporous Polymer Networks. J Am Chem
Soc 139:3615–3618. https://doi.org/10.1021/jacs.6b13147
34. Schmidt J, Werner M, Thomas A (2009) Conjugated Microporous Polymer Networks
via Yamamoto Polymerization. Macromolecules 42:4426–4429. https://doi.org/10.1021/ma9
005473
35. Willms A, Schumacher H, Tabassum T, Qi L, Scott SL, Hausoul PJC, Rose M (2018) Solid
Molecular Frustrated Lewis Pairs in a Polyamine Organic Framework for the Catalytic MetalFree Hydrogenation of Alkenes. ChemCatChem 10:1835–1843. https://doi.org/10.1002/cctc.
201701783
36. Inés B, Palomas D, Holle S, Steinberg S, Nicasio JA, Alcarazo M (2012) Metal-Free Hydrogenation of Electron-Poor Allenes and Alkenes. Angew Chem Int Ed 51:12367–12369. https://
doi.org/10.1002/anie.201205348
37. Mahdi T, Stephan DW (2014) Enabling Catalytic Ketone Hydrogenation by Frustrated Lewis
Pairs. J Am Chem Soc 136:15809–15812. https://doi.org/10.1021/ja508829x
38. Scott DJ, Fuchter MJ, Ashley AE (2014) Nonmetal Catalyzed Hydrogenation of Carbonyl
Compounds. J Am Chem Soc 136:15813–15816. https://doi.org/10.1021/ja5088979
39. Mahdi T, Stephan DW (2015) Facile Protocol for Catalytic Frustrated Lewis Pair Hydrogenation and Reductive Deoxygenation of Ketones and Aldehydes. Angew Chem Int Ed
54:8511–8514. https://doi.org/10.1002/anie.201503087