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Y. Soltani and F.-G. Fontaine
Bn
BenzylBOC
tert-Butyloxycarbonyl
bpy
2,2
-Bipyridine
COD
1,5-Cyclooctadiene
Cy
CyclohexylDMF
Dimethylformamide
DMSO Dimethyl sulfoxide
DTBMP 2,6-Di-tert-butyl-4-methylpyridine
dTBP
2,6-Di-tert-butylpyridine
EAS
Electrophilic aromatic substitution
Et
Ethylexp
Experimental
FDA
Food and Drug Administration
FLP
Frustrated Lewis pair
fur
FurylHOMO Highest occupied molecular orbital
Int
Intermediate
LUMO Lowest unoccupied molecular orbital
m
metaMe
MethylNMR
Nuclear magnetic resonance
NTf 2
−
Bistriflimide anion, [(CF 3 SO 2 ) 2 N]
−
o
Orthop
ParaPAH
Polycyclic aromatic hydrocarbons
Ph
PhenylPMP
1,2,2,6,6-Pentamethylpiperidine
Pip
PiperidyltBu
Tert-ButylTfO
−
Triflate anion, (CF 3 SO 3
− )
THF
Tetrahydrofuran
THT
Tetrahydrothiophene
TIPS
TriisopropylsilylTM
Transition metal
TMP
2,2,6,6-Tetramethylpiperidine
TMS
Trimethylsilyl
Tol
TolylTs
TosylTS
Transition state
tTBP
2,4,6-Tri-tert-butylpyridine