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Its Conversion to a Complex Containing a Tetramethylfulvene Ligand. Organometallics
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111. Jian Z, Kehr G, Daniliuc CG, Wibbeling B, Wiegand T, Siedow M, Eckert H, Bursch M,
Grimme S, Erker G (2017) CO-Reduction Chemistry: Reaction of a CO-Derived Formylhydridoborate with Carbon Monoxide, with Carbon Dioxide, and with Dihydrogen. J Am Chem
Soc 139:6474–6483. https://doi.org/10.1021/jacs.7b02548
112. Dobrovetsky R, Stephan DW (2013) Stoichiometric Metal-Free Reduction of CO in Syn-Gas.
J Am Chem Soc 135:4974–4977. https://doi.org/10.1021/ja401492s
113. Berkefeld A, Piers WE, Parvez M, Castro L, Maron L, Eisenstein O (2012) Carbon Monoxide
Activation via O-Bound CO Using Decamethylscandocinium − Hydridoborate Ion Pairs. J
Am Chem Soc 134:10843–10851. https://doi.org/10.1021/ja300591v
114. Jian Z, Daniliuc CG, Kehr G, Erker G (2018) Zirconocene mediated acetylboron chemistry.
Chem Commun 54:5724–5727. https://doi.org/10.1039/C8CC02680G
115. Hoffman BM, Eames TB (1969) Free-Radical Molecular Complexes. J Am Chem Soc
91:5168–5170. https://doi.org/10.1021/ja01046a044
116. Eames TB, Hoffman BM (1971) Free-Radical Molecular Complexes. II. The Boron Halides
and Aluminum Chloride. J Am Chem Soc 93:3141–3146. https://doi.org/10.1021/ja0074
2a007
117. Scepaniak JJ, Wright AM, Lewis RA, Wu G, Hayton TW (2012) Tuning the Reactivity of
TEMPO by Coordination to a Lewis Acid: Isolation and Reactivity of MCl 3 (η 1 -TEMPO) (M
= Fe, Al). J Am Chem Soc 134:19350–19353. https://doi.org/10.1021/ja309499h
118. Nguyen T-AD, Wright AM, Page JS, Wu G, Hayton TW (2014) Oxidation of Alcohols and
Activated Alkanes with Lewis Acid Activated TEMPO. Inorg Chem 53:11377–11387. https://
doi.org/10.1021/ic5018888
119. Liu Y-L, Kehr G, Daniliuc CG, Erker G (2017) Utilizing the TEMPO Radical in Zirconocene
Cation and Hydrido Zirconocene Chemistry. Organometallics 36:3407–3414. https://doi.org/
10.1021/acs.organomet.7b00558
T. Wang et al.
109. Wolczanski PT, Bercaw JE (1980) On the Mechanisms of Carbon Monoxide Reduction with
Zirconium Hydrides. Acc Chem Res 13:121–127. https://doi.org/10.1021/ar50148a004
110. Miller FD, Sanner RD (1988) Activation of Benzene Carbon-Hydrogen Bonds via Photolysis or Thermolysis of (η 5 -C 5 Me 5 ) 2 Zr(alkyl)H. Isolation of (η 5 -C 5 Me 5 ) 2 Zr(C 6 H 5 )H and
Its Conversion to a Complex Containing a Tetramethylfulvene Ligand. Organometallics
7:818–825. https://doi.org/10.1021/om00094a005
111. Jian Z, Kehr G, Daniliuc CG, Wibbeling B, Wiegand T, Siedow M, Eckert H, Bursch M,
Grimme S, Erker G (2017) CO-Reduction Chemistry: Reaction of a CO-Derived Formylhydridoborate with Carbon Monoxide, with Carbon Dioxide, and with Dihydrogen. J Am Chem
Soc 139:6474–6483. https://doi.org/10.1021/jacs.7b02548
112. Dobrovetsky R, Stephan DW (2013) Stoichiometric Metal-Free Reduction of CO in Syn-Gas.
J Am Chem Soc 135:4974–4977. https://doi.org/10.1021/ja401492s
113. Berkefeld A, Piers WE, Parvez M, Castro L, Maron L, Eisenstein O (2012) Carbon Monoxide
Activation via O-Bound CO Using Decamethylscandocinium − Hydridoborate Ion Pairs. J
Am Chem Soc 134:10843–10851. https://doi.org/10.1021/ja300591v
114. Jian Z, Daniliuc CG, Kehr G, Erker G (2018) Zirconocene mediated acetylboron chemistry.
Chem Commun 54:5724–5727. https://doi.org/10.1039/C8CC02680G
115. Hoffman BM, Eames TB (1969) Free-Radical Molecular Complexes. J Am Chem Soc
91:5168–5170. https://doi.org/10.1021/ja01046a044
116. Eames TB, Hoffman BM (1971) Free-Radical Molecular Complexes. II. The Boron Halides
and Aluminum Chloride. J Am Chem Soc 93:3141–3146. https://doi.org/10.1021/ja0074
2a007
117. Scepaniak JJ, Wright AM, Lewis RA, Wu G, Hayton TW (2012) Tuning the Reactivity of
TEMPO by Coordination to a Lewis Acid: Isolation and Reactivity of MCl 3 (η 1 -TEMPO) (M
= Fe, Al). J Am Chem Soc 134:19350–19353. https://doi.org/10.1021/ja309499h
118. Nguyen T-AD, Wright AM, Page JS, Wu G, Hayton TW (2014) Oxidation of Alcohols and
Activated Alkanes with Lewis Acid Activated TEMPO. Inorg Chem 53:11377–11387. https://
doi.org/10.1021/ic5018888
119. Liu Y-L, Kehr G, Daniliuc CG, Erker G (2017) Utilizing the TEMPO Radical in Zirconocene
Cation and Hydrido Zirconocene Chemistry. Organometallics 36:3407–3414. https://doi.org/
10.1021/acs.organomet.7b00558