3 FLP Reduction of Carbon Monoxide and Related Reactions
111
92. Neu RC, Otten E, Lough A, Stephan DW (2011) The Synthesis and Exchange Chemistry of
Frustrated Lewis Pair–Nitrous Oxide Complexes. Chem Sci 2:170–176. https://doi.org/10.
1039/C0SC00398K
93. Wass DF, Chapman AM (2013) Frustrated Lewis Pairs Beyond the Main Group: Transition
Metal-Containing Systems. In: Erker G., Stephan D. (eds) Frustrated Lewis Pairs II. Top Curr
Chem 334:261–280. https://doi.org/10.1007/128_2012_395
94. Chapman AM, Haddow MF, Wass DF (2011) Frustrated Lewis Pairs beyond the Main
Group: Synthesis, Reactivity, and Small Molecule Activation with Cationic Zirconocene Phosphinoaryloxide Complexes. J Am Chem Soc 133:18463–18478. https://doi.org/10.1021/ja2
07936p
95. Chapman AM, Haddow MF, Wass DF (2011) Frustrated Lewis Pairs beyond the Main Group:
Cationic Zirconocene-Phosphinoaryloxide Complexes and Their Application in Catalytic
Dehydrogenation of Amine Boranes. J Am Chem Soc 138:8826–8829. https://doi.org/10.
1021/ja201989c
96. Chapman AM, Wass DF (2012) Cationic Ti(IV) and Neutral Ti(III) Titanocene–Phosphinoaryloxide Frustrated Lewis Pairs: Hydrogen Activation and Catalytic Amine-Borane
Dehydrogenation. Dalton Trans 41:9067–9072. https://doi.org/10.1039/C2DT30168G
97. Chapman AM, Haddow MF, Wass DF (2012) Cationic Group 4 Metallocene-(oPhosphanylaryl)oxido Complexes: Synthetic Routes to Transition-Metal Frustrated Lewis
Pairs. Eur J Inorg Chem 1546–1554. https://doi.org/10.1002/ejic.201100968
98. Metters OJ, Forrest SJK, Sparkes HA, Manners I, Wass DF (2016) Small Molecule Activation
by Intermolecular Zr(IV)-Phosphine Frustrated Lewis Pairs. J Am Chem Soc 138:1994–
2003. https://doi.org/10.1021/jacs.5b12536
99. Flynn SR, Metters OJ, Manners I, Wass DF (2016) Zirconium-Catalyzed Imine Hydrogenation
via a Frustrated Lewis Pair Mechanism. Organometallics 35:847–850. https://doi.org/10.1021/
acs.organomet.6b00027
100. Metters OJ, Flynn SR, Dowds CK, Sparkes HA, Manners I, Wass DF (2016) Catalytic Dehydrocoupling of Amine−Boranes using Cationic Zirconium(IV)−Phosphine Frustrated Lewis
Pairs. ACS Catal 6:6601–6611. https://doi.org/10.1021/acscatal.6b02211
101. Hamilton HB, King AM, Sparkes HA, Pridmore NE, Wass DF (2019) Zirconium−Nitrogen
Intermolecular Frustrated Lewis Pairs. Inorg Chem 58:6399–6409. https://doi.org/10.1021/
acs.inorgchem.9b00569
102. Normand AT, Daniliuc CG, Wibbeling B, Kehr G, Le Gendre P, Erker G (2015) Phosphidoand Amidozirconocene Cation-Based Frustrated Lewis Pair Chemistry. J Am Chem Soc
137:10796–10808. https://doi.org/10.1021/jacs.5b06551
103. Normand AT, Richard P, Balan C, Daniliuc CG, Kehr G, Erker G, Le Gendre P (2015) Synthetic
Endeavors towards Titanium Based Frustrated Lewis Pairs with Controlled Electronic and
Steric Properties. Organometallics 34:2000–2011. https://doi.org/10.1021/acs.organomet.5b0
0250
104. Normand AT, Daniliuc CG, Wibbeling B, Kehr G, Le Gendre P, Erker G (2016) Insertion
Reactions of Neutral Phosphidozirconocene Complexes as a Convenient Entry into Frustrated
Lewis Pair Territory. Chem Eur J 22:4285–4293. https://doi.org/10.1002/chem.201504792
105. Jian Z, Daniliuc CG, Kehr G, Erker G (2017) Frustrated Lewis Pair vs Metal-Carbon σBond Insertion Chemistry at an o-Phenylene-Bridged Cp 2 Zr + /PPh 2 System. Organometallics
36:424–434. https://doi.org/10.1021/acs.organomet.6b00828
106. Guram AS, Guo Z, Jordan RF (1993) Zirconium-Mediated Reactions of Carbon Monoxide
and Alkynes. Insertion Chemistry of Cationic Zr(IV) η 2 -Acyl and Alkenyl Complexes. J Am
Chem Soc 115:4902–4903. https://doi.org/10.1021/ja00064a066
107. Guo Z, Swenson DC, Guram AS, Jordan RF (1994) Isolable Zirconium(IV) Carbonyl
Complexes. Synthesis and Characterization of (C 5 R 5 )Zr(η 2 -COCH 3 )(CO) + Species (R =
Me, H). Organometallics 13:766–773. https://doi.org/10.1021/om00015a009
108. Shen H, Jordan RF (2003) Molecular Structure and Vinyl Chloride Insertion of a Cationic
Zirconium(IV) Acyl Carbonyl Complex. 22: 2080–2086. https://doi.org/10.1021/om0210311
111
92. Neu RC, Otten E, Lough A, Stephan DW (2011) The Synthesis and Exchange Chemistry of
Frustrated Lewis Pair–Nitrous Oxide Complexes. Chem Sci 2:170–176. https://doi.org/10.
1039/C0SC00398K
93. Wass DF, Chapman AM (2013) Frustrated Lewis Pairs Beyond the Main Group: Transition
Metal-Containing Systems. In: Erker G., Stephan D. (eds) Frustrated Lewis Pairs II. Top Curr
Chem 334:261–280. https://doi.org/10.1007/128_2012_395
94. Chapman AM, Haddow MF, Wass DF (2011) Frustrated Lewis Pairs beyond the Main
Group: Synthesis, Reactivity, and Small Molecule Activation with Cationic Zirconocene Phosphinoaryloxide Complexes. J Am Chem Soc 133:18463–18478. https://doi.org/10.1021/ja2
07936p
95. Chapman AM, Haddow MF, Wass DF (2011) Frustrated Lewis Pairs beyond the Main Group:
Cationic Zirconocene-Phosphinoaryloxide Complexes and Their Application in Catalytic
Dehydrogenation of Amine Boranes. J Am Chem Soc 138:8826–8829. https://doi.org/10.
1021/ja201989c
96. Chapman AM, Wass DF (2012) Cationic Ti(IV) and Neutral Ti(III) Titanocene–Phosphinoaryloxide Frustrated Lewis Pairs: Hydrogen Activation and Catalytic Amine-Borane
Dehydrogenation. Dalton Trans 41:9067–9072. https://doi.org/10.1039/C2DT30168G
97. Chapman AM, Haddow MF, Wass DF (2012) Cationic Group 4 Metallocene-(oPhosphanylaryl)oxido Complexes: Synthetic Routes to Transition-Metal Frustrated Lewis
Pairs. Eur J Inorg Chem 1546–1554. https://doi.org/10.1002/ejic.201100968
98. Metters OJ, Forrest SJK, Sparkes HA, Manners I, Wass DF (2016) Small Molecule Activation
by Intermolecular Zr(IV)-Phosphine Frustrated Lewis Pairs. J Am Chem Soc 138:1994–
2003. https://doi.org/10.1021/jacs.5b12536
99. Flynn SR, Metters OJ, Manners I, Wass DF (2016) Zirconium-Catalyzed Imine Hydrogenation
via a Frustrated Lewis Pair Mechanism. Organometallics 35:847–850. https://doi.org/10.1021/
acs.organomet.6b00027
100. Metters OJ, Flynn SR, Dowds CK, Sparkes HA, Manners I, Wass DF (2016) Catalytic Dehydrocoupling of Amine−Boranes using Cationic Zirconium(IV)−Phosphine Frustrated Lewis
Pairs. ACS Catal 6:6601–6611. https://doi.org/10.1021/acscatal.6b02211
101. Hamilton HB, King AM, Sparkes HA, Pridmore NE, Wass DF (2019) Zirconium−Nitrogen
Intermolecular Frustrated Lewis Pairs. Inorg Chem 58:6399–6409. https://doi.org/10.1021/
acs.inorgchem.9b00569
102. Normand AT, Daniliuc CG, Wibbeling B, Kehr G, Le Gendre P, Erker G (2015) Phosphidoand Amidozirconocene Cation-Based Frustrated Lewis Pair Chemistry. J Am Chem Soc
137:10796–10808. https://doi.org/10.1021/jacs.5b06551
103. Normand AT, Richard P, Balan C, Daniliuc CG, Kehr G, Erker G, Le Gendre P (2015) Synthetic
Endeavors towards Titanium Based Frustrated Lewis Pairs with Controlled Electronic and
Steric Properties. Organometallics 34:2000–2011. https://doi.org/10.1021/acs.organomet.5b0
0250
104. Normand AT, Daniliuc CG, Wibbeling B, Kehr G, Le Gendre P, Erker G (2016) Insertion
Reactions of Neutral Phosphidozirconocene Complexes as a Convenient Entry into Frustrated
Lewis Pair Territory. Chem Eur J 22:4285–4293. https://doi.org/10.1002/chem.201504792
105. Jian Z, Daniliuc CG, Kehr G, Erker G (2017) Frustrated Lewis Pair vs Metal-Carbon σBond Insertion Chemistry at an o-Phenylene-Bridged Cp 2 Zr + /PPh 2 System. Organometallics
36:424–434. https://doi.org/10.1021/acs.organomet.6b00828
106. Guram AS, Guo Z, Jordan RF (1993) Zirconium-Mediated Reactions of Carbon Monoxide
and Alkynes. Insertion Chemistry of Cationic Zr(IV) η 2 -Acyl and Alkenyl Complexes. J Am
Chem Soc 115:4902–4903. https://doi.org/10.1021/ja00064a066
107. Guo Z, Swenson DC, Guram AS, Jordan RF (1994) Isolable Zirconium(IV) Carbonyl
Complexes. Synthesis and Characterization of (C 5 R 5 )Zr(η 2 -COCH 3 )(CO) + Species (R =
Me, H). Organometallics 13:766–773. https://doi.org/10.1021/om00015a009
108. Shen H, Jordan RF (2003) Molecular Structure and Vinyl Chloride Insertion of a Cationic
Zirconium(IV) Acyl Carbonyl Complex. 22: 2080–2086. https://doi.org/10.1021/om0210311