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N. Kojima and A. Okazawa
Fig. 6.35 Magnetization versus magnetic field (MH) curves at 1.77, 2.10, and 2.64 K for a single
crystal (volume: 0.066 ± 0.008 mm 3 ) of [Mn 12 ] ac . The magnetic field was applied along the
magnetization axis, which aligns with the longest crystal dimension. Reprinted by permission from
Springer Nature: [58], Copyright 1996
Fig. 6.36 a Magnetic hysteresis curve and b–d double-well potentials with energy levels for a spin
state of S for a single-molecule magnet having easy-axis magnetic anisotropy (D < 0). The levels
of positive m S states are localized in the right well and the negative ones in the left well. Applied
dc fields (H) are b zero, c 0 < H < −D/gμ B , and d −D/gμ B . The QTM occurs when energy levels
between the two wells come to the same level
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