6 Molecular Magnetism of Metal Complexes and Light-Induced …
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Fig. 6.30 Optical absorption of (SP-Me)[Fe II Fe III (dto) 3 ] in a KBr pellet under a UV light irradiation and b visible-light irradiation at 70 K. UV light irradiation (350 nm with 40 mW cm −2 ) on the
KBr pellet was performed at first. After the saturation of light-induced absorption spectra at around
550–600 nm, visible-light irradiation (white light with 600 mW cm −2 ) on the pellet was performed.
Reprinted with permission from [7(a)]. Copyright 2009 American Chemical Society
Fig. 6.31 a–c Temperature dependence of the magnetization for (SP-Me)[Fe II Fe III (dto) 3 ] before
and after the UV light irradiation (350 nm with 40 mW cm −2 ) for 2 and 4 h at 300 K. d Temperature
dependence of the magnetization after the UV light irradiation for 5 h at 70 K. e Schematic representation of the photo-induced phase conversion from the phase (A) to the phase (B). T = 75 K
denotes the CTPT. Reprinted with permission from [7(a)]. Copyright 2009 American Chemical
Society
297
Fig. 6.30 Optical absorption of (SP-Me)[Fe II Fe III (dto) 3 ] in a KBr pellet under a UV light irradiation and b visible-light irradiation at 70 K. UV light irradiation (350 nm with 40 mW cm −2 ) on the
KBr pellet was performed at first. After the saturation of light-induced absorption spectra at around
550–600 nm, visible-light irradiation (white light with 600 mW cm −2 ) on the pellet was performed.
Reprinted with permission from [7(a)]. Copyright 2009 American Chemical Society
Fig. 6.31 a–c Temperature dependence of the magnetization for (SP-Me)[Fe II Fe III (dto) 3 ] before
and after the UV light irradiation (350 nm with 40 mW cm −2 ) for 2 and 4 h at 300 K. d Temperature
dependence of the magnetization after the UV light irradiation for 5 h at 70 K. e Schematic representation of the photo-induced phase conversion from the phase (A) to the phase (B). T = 75 K
denotes the CTPT. Reprinted with permission from [7(a)]. Copyright 2009 American Chemical
Society