4.2 Aqueous Solutions
93
(acac)
2 en: N,N’-ethylenebis(acetylacetone iminate); ACN: acetonitrile; (brac)
2 en: N,N’-ethylenebis(3-bromoacetoacetone iminate); (buac)
2 en: N,N’ethylenebis(tert-butyl acetoacetone iminate); (bzac)
2 en: N,N’-ethylenebis(benzoylacetone iminate); bpm: 2,2
-bipyrimidine; bpy: 2,2
-bipyridine; CTAB:
hexadecyltrimethylammonium bromide; Cy: cysteine; DBAP: di-tert-butylamidophenolate; DBCat: bis(3,5-di-tert-butylcatecholate); DCM: dichloromethane;
dedc: diethyldithiocarbamate; depe: 1,2-bis(diethylphosphino)ethane; diars: o-phenylenebis(dimethylarsine); diphos: 1,2-bis(diphenylphosphino)ethane;
DMAc: N,N-dimethylacetamide; dmdc: dimethyldithiocarbamate; DMF: dimethylformamide; dmpe: 1,2-bis(dimethylphosphino)ethane; (H)DPhF:
diphenylformamidine; dppb: bis(1,2-diphenylphosphino)benzene; dppbt(h): 2-(diphenylphosphino)benzenethiol; 2-(dppe: l,2-bis(diphenylphosphino)ethane;
en: etylenediamine; Et: ethyl; FcCS
2 : [Fe I
(C
5 H
5 )(C
5 H
4 CS
2 )] −
; FcCS
2 •: [Fe II
(C
5 H
5 )(C
5 H
4 CS
2 )]; morphbtu: N,N-dialkyl-N’-benzoylthioureas; L 1
: 2(dipheny1phosphino)- benzoic; (H2L 1b
): N’-(2-Hydroxyphenyl)benzamidine; L’
= 1 -(8
-quinolyliminomethyl)-2-naphtholate, L”: SCH
2 CH
2 SCH
2 CH
2 S;
L 2
: 3-(dipheny1phosphino)propionic; L 3
: (dipheny1phosphino)acetic; L
B
1
: monoanion of N-phenylsalicylideneamine; L
B
2
: monoanion of N quinolin8-ol; L
B
3
: monoanion of 5-nitroquinolin-8-ol; L
T : dianion of N-(2-oxidophenyl)salicylideneamine; L 3
: tris[2-(2
-hydroxybenzylideneethyl)]amine;
lut: 3,5-lutidine; L
q : N,N
-2-hydroxypropane-1,3-bis(salicylideneimine); (Me
2 bpy): 4,4
-dimethyl-2,2
-bipyridine; PC: propylene carbonate; Ph: phenyl;
phen: 1,10-phenantroline; pic: 4-picoline; pmdc: methylenedithiocarbamate; (PnAO): derivative of propyleneamine oxime; PR
2 S: phosphinothiolate
with R
= aryl, alkyl; py: pyridine; (9S3): 1,4,7-trithiacyclononane; (sal)
2 en: N,N’-ethylenebis(salicylideneaminate); (SCP): zwitter ionic ligand
−
SCH
2 P +
(CH
3 )(CH
2 )
2 P(S)(CH
3 )
2 ; (S
2 CPh)(S
3 CPh)
2 : bis(perthiobenzoato)(dithiobenzoato); SDS: sodium dodecyl sulfate; SES: tridentate dithiolato
fagment of type –S(CH2)2E(CH2)S- where E
= O (1), S(2), NMe(3); (SR): where R can be selected alkyl or areneo- thiolato; TBAH:
tetrabutylammonium hydroxide; (t-butyl
3 terpy): 4,4
,4
’-tris(tert-butyl)terpyridine; TCTA: l,4,7-triazacyclononane-A,A’,A"-triacetate; (TEA)P/Cl/Br:
tetraethylammonium perchlorate/chloride/bromide; tdt: toluene-3,4-dithiolate; terpy: 2,2
:6
,2
’-terpyridine; tmeda: etramethylethylenediamine; (tmf
2 enH
2 ):
4,4
-[(1E,1
E)[ethane-1,2-diylbis(azanylylidene)]bis(methanylylidene)]bis(2,2,5,5-tetramethyl-2,5-dihydrofuran-3-ol); tmpp: tris(3-methoxypropyl)phosphine;
tn: 1,3-diaminepropane; TpXPC: mesotris(para-X-phenyl)corrole where X
= CF
3 , H, Me, and OMe
93
(acac)
2 en: N,N’-ethylenebis(acetylacetone iminate); ACN: acetonitrile; (brac)
2 en: N,N’-ethylenebis(3-bromoacetoacetone iminate); (buac)
2 en: N,N’ethylenebis(tert-butyl acetoacetone iminate); (bzac)
2 en: N,N’-ethylenebis(benzoylacetone iminate); bpm: 2,2
-bipyrimidine; bpy: 2,2
-bipyridine; CTAB:
hexadecyltrimethylammonium bromide; Cy: cysteine; DBAP: di-tert-butylamidophenolate; DBCat: bis(3,5-di-tert-butylcatecholate); DCM: dichloromethane;
dedc: diethyldithiocarbamate; depe: 1,2-bis(diethylphosphino)ethane; diars: o-phenylenebis(dimethylarsine); diphos: 1,2-bis(diphenylphosphino)ethane;
DMAc: N,N-dimethylacetamide; dmdc: dimethyldithiocarbamate; DMF: dimethylformamide; dmpe: 1,2-bis(dimethylphosphino)ethane; (H)DPhF:
diphenylformamidine; dppb: bis(1,2-diphenylphosphino)benzene; dppbt(h): 2-(diphenylphosphino)benzenethiol; 2-(dppe: l,2-bis(diphenylphosphino)ethane;
en: etylenediamine; Et: ethyl; FcCS
2 : [Fe I
(C
5 H
5 )(C
5 H
4 CS
2 )] −
; FcCS
2 •: [Fe II
(C
5 H
5 )(C
5 H
4 CS
2 )]; morphbtu: N,N-dialkyl-N’-benzoylthioureas; L 1
: 2(dipheny1phosphino)- benzoic; (H2L 1b
): N’-(2-Hydroxyphenyl)benzamidine; L’
= 1 -(8
-quinolyliminomethyl)-2-naphtholate, L”: SCH
2 CH
2 SCH
2 CH
2 S;
L 2
: 3-(dipheny1phosphino)propionic; L 3
: (dipheny1phosphino)acetic; L
B
1
: monoanion of N-phenylsalicylideneamine; L
B
2
: monoanion of N quinolin8-ol; L
B
3
: monoanion of 5-nitroquinolin-8-ol; L
T : dianion of N-(2-oxidophenyl)salicylideneamine; L 3
: tris[2-(2
-hydroxybenzylideneethyl)]amine;
lut: 3,5-lutidine; L
q : N,N
-2-hydroxypropane-1,3-bis(salicylideneimine); (Me
2 bpy): 4,4
-dimethyl-2,2
-bipyridine; PC: propylene carbonate; Ph: phenyl;
phen: 1,10-phenantroline; pic: 4-picoline; pmdc: methylenedithiocarbamate; (PnAO): derivative of propyleneamine oxime; PR
2 S: phosphinothiolate
with R
= aryl, alkyl; py: pyridine; (9S3): 1,4,7-trithiacyclononane; (sal)
2 en: N,N’-ethylenebis(salicylideneaminate); (SCP): zwitter ionic ligand
−
SCH
2 P +
(CH
3 )(CH
2 )
2 P(S)(CH
3 )
2 ; (S
2 CPh)(S
3 CPh)
2 : bis(perthiobenzoato)(dithiobenzoato); SDS: sodium dodecyl sulfate; SES: tridentate dithiolato
fagment of type –S(CH2)2E(CH2)S- where E
= O (1), S(2), NMe(3); (SR): where R can be selected alkyl or areneo- thiolato; TBAH:
tetrabutylammonium hydroxide; (t-butyl
3 terpy): 4,4
,4
’-tris(tert-butyl)terpyridine; TCTA: l,4,7-triazacyclononane-A,A’,A"-triacetate; (TEA)P/Cl/Br:
tetraethylammonium perchlorate/chloride/bromide; tdt: toluene-3,4-dithiolate; terpy: 2,2
:6
,2
’-terpyridine; tmeda: etramethylethylenediamine; (tmf
2 enH
2 ):
4,4
-[(1E,1
E)[ethane-1,2-diylbis(azanylylidene)]bis(methanylylidene)]bis(2,2,5,5-tetramethyl-2,5-dihydrofuran-3-ol); tmpp: tris(3-methoxypropyl)phosphine;
tn: 1,3-diaminepropane; TpXPC: mesotris(para-X-phenyl)corrole where X
= CF
3 , H, Me, and OMe