Index
161
PPh 3 , 88, 93
PR 2 S, 93
py, 75, 88, 89, 93
9S3, 66, 93
(sal) 2 en, 83, 93
SC 6 H 4 -p-Cl, 74, 86, 93
SC 6 H 4 -p-OCH 3 , 74, 86, 87, 93
SC 6 H 4 -p-t-Bu, 86, 93
SC 6 H 5 , 74, 86, 93
SCH 2 C 6 H 4 -p-OCH 3 , 74, 86, 93
SCH 2 C 6 H 5 , 74, 86, 93
SCP, 87, 93
(S 2 CPh)(S 3 CPh) 2 , 91, 93
SES, 87, 93
S-n-C 3 H 7 , 86, 93
t-butyl 3 terpy, 88, 93
TCTA, 77, 90, 93
tdt, 86, 93
terpy, 84, 88, 89, 93
tmeda, 75, 88, 93
tmf 2 enH 2 , 75, 93
tmpp, 75, 88, 93
tn, 81, 92, 93
TpXPC, 88, 93
Ligands, inorganic
Re(CO) 5 X, 62
TcBr 26 , 45–47
TcCl 26 , 35, 45–47, 49, 50, 61, 62, 137
TcI 26 , 60
[Tc x X y ] n- , 48, 49
TcNBr -
4 , 47
TcNCl -
4 , 47
[Tc(NCS) 6 ] 3- , 61, 62
[Tc(NH 3 ) 4 (NO)H 2 O] 2+ , 50
[Tc(NH 3 ) 4 (NO)F] +
[Tc(NO)(NCS) 5 ] 2+ , 62
TcOBr -
4 , 47
TcOCl -
4 , 47, 50
TcO(CN) 25 , 60
Tc(OH) p (CO 3 )
4-p-2q
q
, 59
[Tc 6 Q 8 (CN) 6 ] 4- , 61–62
[Tc 6 S 8 X 6 ] 4- , 61–62
Liquid chromatography, 145
Liquid scintillation counting (LSC), 143
M
Manganese
electrochemistry, 11, 12, 16, 17
ionic forms, 16, 17, 27
oxides, 12, 16
Mercury electrode, 18, 21, 36, 52, 79–81,
127, 145, 150, 151
Metallic technetium
conductivity, 5
dissolution, 112, 120–123, 135
electrodeposition, 114–117, 119
hydrogen evolution, 15, 113, 117, 118
physicochemical properties, 5, 6
Microelectrodes, 71, 148
Molten salts
conductance of Re(IV), 136
diagrams of Tc, 134
Molybdenum
electrochemistry, 11–13
ionic forms, 11–13, 27
isotopes, 3, 4
N
Neptunium
interaction with technetium, 128–130
Neutron activation Analysis (NAA), 143
Nitric acids
decomposition, 124, 125
redox potentials, 124, 125
Nuclear fuel, 109–112, 130, 137
O
Oxides
Tc 2 O 7 , 22, 135
Tc 2 O 5 , 22
TcO 3 , 22, 36
TcO 2 , see Tc(IV)
P
Palladium, 110, 131
Pitzer parameters, 31–33
Plutonium, 5, 111, 112, 127, 134
Polymeric forms (or species), 11, 13, 14, 38,
42–44, 63, 120, 124, 129, 130, 137
Polyoxometalates, 133
Protonation
TcO -
4 , 53
TcO 24 , 53
R
Resonance ionization mass spectrometry,
143
Rhenium
electrochemistry, 16, 17, 19–22, 24–26,
39, 61, 62, 81, 115, 119, 130
E h -ph diagram, 14
161
PPh 3 , 88, 93
PR 2 S, 93
py, 75, 88, 89, 93
9S3, 66, 93
(sal) 2 en, 83, 93
SC 6 H 4 -p-Cl, 74, 86, 93
SC 6 H 4 -p-OCH 3 , 74, 86, 87, 93
SC 6 H 4 -p-t-Bu, 86, 93
SC 6 H 5 , 74, 86, 93
SCH 2 C 6 H 4 -p-OCH 3 , 74, 86, 93
SCH 2 C 6 H 5 , 74, 86, 93
SCP, 87, 93
(S 2 CPh)(S 3 CPh) 2 , 91, 93
SES, 87, 93
S-n-C 3 H 7 , 86, 93
t-butyl 3 terpy, 88, 93
TCTA, 77, 90, 93
tdt, 86, 93
terpy, 84, 88, 89, 93
tmeda, 75, 88, 93
tmf 2 enH 2 , 75, 93
tmpp, 75, 88, 93
tn, 81, 92, 93
TpXPC, 88, 93
Ligands, inorganic
Re(CO) 5 X, 62
TcBr 26 , 45–47
TcCl 26 , 35, 45–47, 49, 50, 61, 62, 137
TcI 26 , 60
[Tc x X y ] n- , 48, 49
TcNBr -
4 , 47
TcNCl -
4 , 47
[Tc(NCS) 6 ] 3- , 61, 62
[Tc(NH 3 ) 4 (NO)H 2 O] 2+ , 50
[Tc(NH 3 ) 4 (NO)F] +
[Tc(NO)(NCS) 5 ] 2+ , 62
TcOBr -
4 , 47
TcOCl -
4 , 47, 50
TcO(CN) 25 , 60
Tc(OH) p (CO 3 )
4-p-2q
q
, 59
[Tc 6 Q 8 (CN) 6 ] 4- , 61–62
[Tc 6 S 8 X 6 ] 4- , 61–62
Liquid chromatography, 145
Liquid scintillation counting (LSC), 143
M
Manganese
electrochemistry, 11, 12, 16, 17
ionic forms, 16, 17, 27
oxides, 12, 16
Mercury electrode, 18, 21, 36, 52, 79–81,
127, 145, 150, 151
Metallic technetium
conductivity, 5
dissolution, 112, 120–123, 135
electrodeposition, 114–117, 119
hydrogen evolution, 15, 113, 117, 118
physicochemical properties, 5, 6
Microelectrodes, 71, 148
Molten salts
conductance of Re(IV), 136
diagrams of Tc, 134
Molybdenum
electrochemistry, 11–13
ionic forms, 11–13, 27
isotopes, 3, 4
N
Neptunium
interaction with technetium, 128–130
Neutron activation Analysis (NAA), 143
Nitric acids
decomposition, 124, 125
redox potentials, 124, 125
Nuclear fuel, 109–112, 130, 137
O
Oxides
Tc 2 O 7 , 22, 135
Tc 2 O 5 , 22
TcO 3 , 22, 36
TcO 2 , see Tc(IV)
P
Palladium, 110, 131
Pitzer parameters, 31–33
Plutonium, 5, 111, 112, 127, 134
Polymeric forms (or species), 11, 13, 14, 38,
42–44, 63, 120, 124, 129, 130, 137
Polyoxometalates, 133
Protonation
TcO -
4 , 53
TcO 24 , 53
R
Resonance ionization mass spectrometry,
143
Rhenium
electrochemistry, 16, 17, 19–22, 24–26,
39, 61, 62, 81, 115, 119, 130
E h -ph diagram, 14