160
Index
for ligands, 96–102
F
Fission products, 5, 109, 110, 132, 134
G
Gamma rays
irradiation, 137
technetium isotopes, 4
H
Hydrazine, 109, 125–128, 133
Hydrogen evolution, 12, 15, 21, 22, 24, 113,
117, 118, 130, 131, 144
I
Inductively coupled plasma mass spectroscopy (ICP-MS), 143
Interferences
antimony, 147
cadmium, 147
cerium, 146
chlorides, 144–148
copper, 147
hydrogen peroxide, 146
iron, 148
lead, 147
manganese, 147
molybdenum, 151
nitrates, 147
rhenium, 151
ruthenium, 147
uranium, 146, 147, 152
zinc, 146, 147
zirconium, 146, 147
Ion selective membrane, 147
Isotopes
instability, 3, 5
production, 4, 5
properties, 4
K
Kinetic parameters, 35, 36, 55, 58, 63, 128
L
Ligands, organic
(acac) 2 en, 83, 93
bpm, 85, 93
bpy, 73, 75, 84, 89, 93
(brac) 2 en, 83, 93
(buac) 2 en, 83, 93
(bzac) 2 en, 83, 93
CH 3 CN, 77, 90, 93
CF 3 COO, 72, 84, 93
CN-C 6 H 11 , 71, 84, 93
CN-tert-butyl, 71, 84, 93
DBAP, 92, 93
DBCat, 76, 91, 93
dedc, 87, 93
depe, 20, 70, 72, 80, 82, 83, 87, 93
diars, 20, 70, 82, 93
diphos, 82, 93
dioxime:, 75
dmdc, 87, 93
DMP, 81
dmpe, 19, 20, 70, 72–74, 82, 83, 85–87,
93
DMSA, 81
dppb, 70, 82, 86, 87, 93
dppbt(h), 74, 86, 93
dppe, 20, 70, 71, 82–84, 93, 96
en, 92, 93, 98
FcCS 2 , 76, 91, 93
gluconate, 93, 137
HDPE, 79, 80
(H)DPhF, 77, 90, 93
morphbtu, 75, 88, 93
L 1 , 91, 93
H 2 L 1b , 88, 93
L ’ , 91, 93
L ” , 86, 93
L 2 , 76, 91, 93
L 3 , 76, 91, 93
L B
1 , 76, 91, 93
L B
2 , 76, 91, 93
L B
3 , 76, 91, 93
L T , 76, 91, 93
L 3’ , 76, 91, 93
lut, 89, 93
L q , 91, 93
Me 2 bpy, 73, 75, 88, 93
noet:, 74
PEt 2 Ph, 84, 93
PEt 3 , 75, 83, 93
phen, 84, 89, 93
pic, 89, 93
PMe 2 Ph, 70, 77, 84, 90, 93
PMe 3 , 77, 90, 93
pmdc, 87, 93
PnAO, 84, 93
P(OEt) 2 Ph, 78
Index
for ligands, 96–102
F
Fission products, 5, 109, 110, 132, 134
G
Gamma rays
irradiation, 137
technetium isotopes, 4
H
Hydrazine, 109, 125–128, 133
Hydrogen evolution, 12, 15, 21, 22, 24, 113,
117, 118, 130, 131, 144
I
Inductively coupled plasma mass spectroscopy (ICP-MS), 143
Interferences
antimony, 147
cadmium, 147
cerium, 146
chlorides, 144–148
copper, 147
hydrogen peroxide, 146
iron, 148
lead, 147
manganese, 147
molybdenum, 151
nitrates, 147
rhenium, 151
ruthenium, 147
uranium, 146, 147, 152
zinc, 146, 147
zirconium, 146, 147
Ion selective membrane, 147
Isotopes
instability, 3, 5
production, 4, 5
properties, 4
K
Kinetic parameters, 35, 36, 55, 58, 63, 128
L
Ligands, organic
(acac) 2 en, 83, 93
bpm, 85, 93
bpy, 73, 75, 84, 89, 93
(brac) 2 en, 83, 93
(buac) 2 en, 83, 93
(bzac) 2 en, 83, 93
CH 3 CN, 77, 90, 93
CF 3 COO, 72, 84, 93
CN-C 6 H 11 , 71, 84, 93
CN-tert-butyl, 71, 84, 93
DBAP, 92, 93
DBCat, 76, 91, 93
dedc, 87, 93
depe, 20, 70, 72, 80, 82, 83, 87, 93
diars, 20, 70, 82, 93
diphos, 82, 93
dioxime:, 75
dmdc, 87, 93
DMP, 81
dmpe, 19, 20, 70, 72–74, 82, 83, 85–87,
93
DMSA, 81
dppb, 70, 82, 86, 87, 93
dppbt(h), 74, 86, 93
dppe, 20, 70, 71, 82–84, 93, 96
en, 92, 93, 98
FcCS 2 , 76, 91, 93
gluconate, 93, 137
HDPE, 79, 80
(H)DPhF, 77, 90, 93
morphbtu, 75, 88, 93
L 1 , 91, 93
H 2 L 1b , 88, 93
L ’ , 91, 93
L ” , 86, 93
L 2 , 76, 91, 93
L 3 , 76, 91, 93
L B
1 , 76, 91, 93
L B
2 , 76, 91, 93
L B
3 , 76, 91, 93
L T , 76, 91, 93
L 3’ , 76, 91, 93
lut, 89, 93
L q , 91, 93
Me 2 bpy, 73, 75, 88, 93
noet:, 74
PEt 2 Ph, 84, 93
PEt 3 , 75, 83, 93
phen, 84, 89, 93
pic, 89, 93
PMe 2 Ph, 70, 77, 84, 90, 93
PMe 3 , 77, 90, 93
pmdc, 87, 93
PnAO, 84, 93
P(OEt) 2 Ph, 78
