104
4 Technetium Coordinated by Organic Ligands …
of cis-dicarbonyltetrakis(diethylphenylphosphonite)technetium(I) perchlorate. Inorg Chim Acta
13:47–59
Bolzati C, Uccelli L, Duatti A (1997) Synthesis and characterization of nitrido Tc(V)
and Re(V) complexes with ferrocenedithiocarboxylate{FcCS 2 =[Fe(C 5 H 4 CS 2 )(C 5 H 5 )] - }. Inorg
Chem 36:3582–3585
Bond AM, Colton R, Mcdonald E (1978) Chemical and electrochemical studies of tricarbonyl
derivatives of manganese and rhenium. Inorg Chem 17(10):2842–2847
Breikss AI, Nicholson T, Jones AG et al (1990) Synthesis and characterization of technetium (III)
and technetium (II) complexes with mixed phosphine-, chloride-, and nitrogen-donor ligands.
X-ray crystal structure of TcCl 3 (PPh 3 )(bpy). Inorg Chem 29:640–645
Bryan JC, Cotton FA, Daniels LM (1995) Metal—metal multiply-bonded complexes of technetium.
2. Preparation and characterization of the fully solvated ditechnetium cation [Tc 2 (CH 3 CN) 10 ] 4+ .
Inorg Chem 34:1875–1883
Bursten BP (1982) Ligand additivity: applications to the electrochemistry and photoelectron
spectroscopy of d6 octahedral complexes. J Am Chem Soc 104(5):1299–1304
Chatterjee S, Del Negro AS, Smith FN et al (2013) Photophysics and luminescence spectroelectrochemistry of [Tc(dmpe) 3 ] +/2+ (dmpe = 1,2-bis(dimethylphosphino)ethane). J Phys Chem A
117:12749–12758
Clarke MJ, Kastner ME, Podbielski LA (1988) Low-symmetry, mixed-valent, μ-oxo technetium
complexes with pyridine and halide ligands. J Am Chem Soc 110:1818–1827
Cotton FA, Haefner SC, Sattelberger AP (1996a) Metal-metal multiply-bonded complexes of technetium. 3. Preparation and characterization of phosphine complexes of technetium possessing a
metal-metal bond order of 3.5. Inorg Chem 35:1831–1838
Cotton FA, Haefner SC, Sattelberger AP (1996b) Metal-metal multiply bonded complexes
of technetium. 5. Tris and tetrakis(formamidinato) complexes of ditechnetium. Inorg Chem
35:7350–7357
Cotton FA, Haefner SC, Sattelberger AP (1997) Metal-metal multiply-bonded complexes of technetium. 6. A μ, η 1 , η 2 -CH 3 CN complex prepared via reductive cleavage of the electron-rich
Tc≡Tc triple bond in decakis-acetonitrile ditechnetium tetrafluoroborate. Inorg Chim Acta
266:55–63
Cyr JE, Linder KE, Nowotnik DP (1993) Electrochemistry of boron-capped 99 Tc-dioxime
complexes. Inorg Chim Acta 206(1):97–104
De Gregori I, Lobos S (1989) Electrochemical and chemical reduction of TcO 4
- in dithiols in
alkaline aqueous media. Appl Radiat Lsot 40(5):385–391
deLearie LA, Haltiwanger RC, Pierpont CG (1989) Technetium complexes of 3,5-ditert-butylcatechol. Direct synthesis of tris (3,5-di-tert-butylcatecholato)technetium(VI) and
Bis(3,5-di-tert-butylcatecholato)- (di-teri-butylamidophenolato)technetium(VI) from ammonium pertechnetate. J Am Chem Soc 111:4324–4328
Dilworth R, Hutson AJ, Morton S et al (1992) The preparation and electrochemistry of technetium and rhenium complexes of 2-(diphenylphosphino)benzenethiol. The crystal and molecular
structures of [Re(2-Ph 2 PC 6 H 4 S) 3 ] and [Tc(2-Ph 2 PC 6 H 4 S) 3 ]. Polyhedron 11(17):2151–2155
Einrem RF, Braband H, Fox T (2016) Synthesis and molecular structure of 99 Tc corroles. Chem
Eur J 22:18747–18751
Hunter G, Kilcullen N (1989) Complexes of technetium, rhenium, and rhodium with sexidentate
Schiff-base ligands. J Chem Soc Dalton Trans 2115–2119
Hurst RW, Heineman WR, Deutsch E (1981) Technetium electrochemistry. 1. Spectroelectrochemical studies of halogen, diars, and diphos complexes of technetium in nonaqueous media. Inorg
Chem 20(10):3298–3303
Huy NH (2009) Complexes of rhenium and technetium with chelating thiourea ligands. PhD
dissertation, Institute of Chemistry and Biochemistry, Freie Universität Berlin, Berlin
Ichimura A, Heineman WR, Vanderheyden J-L et al (1984) Technetium electrochemistry. 2. Electrochemical and spectroelectrochemical studies of the bis(tertiary phosphine) (D) complexes
trans-[Tc III D 2 X 2 ] + (X = Cl, Br) and [Tc I D 3 ] + . Inorg Chem 23:1272–1278
4 Technetium Coordinated by Organic Ligands …
of cis-dicarbonyltetrakis(diethylphenylphosphonite)technetium(I) perchlorate. Inorg Chim Acta
13:47–59
Bolzati C, Uccelli L, Duatti A (1997) Synthesis and characterization of nitrido Tc(V)
and Re(V) complexes with ferrocenedithiocarboxylate{FcCS 2 =[Fe(C 5 H 4 CS 2 )(C 5 H 5 )] - }. Inorg
Chem 36:3582–3585
Bond AM, Colton R, Mcdonald E (1978) Chemical and electrochemical studies of tricarbonyl
derivatives of manganese and rhenium. Inorg Chem 17(10):2842–2847
Breikss AI, Nicholson T, Jones AG et al (1990) Synthesis and characterization of technetium (III)
and technetium (II) complexes with mixed phosphine-, chloride-, and nitrogen-donor ligands.
X-ray crystal structure of TcCl 3 (PPh 3 )(bpy). Inorg Chem 29:640–645
Bryan JC, Cotton FA, Daniels LM (1995) Metal—metal multiply-bonded complexes of technetium.
2. Preparation and characterization of the fully solvated ditechnetium cation [Tc 2 (CH 3 CN) 10 ] 4+ .
Inorg Chem 34:1875–1883
Bursten BP (1982) Ligand additivity: applications to the electrochemistry and photoelectron
spectroscopy of d6 octahedral complexes. J Am Chem Soc 104(5):1299–1304
Chatterjee S, Del Negro AS, Smith FN et al (2013) Photophysics and luminescence spectroelectrochemistry of [Tc(dmpe) 3 ] +/2+ (dmpe = 1,2-bis(dimethylphosphino)ethane). J Phys Chem A
117:12749–12758
Clarke MJ, Kastner ME, Podbielski LA (1988) Low-symmetry, mixed-valent, μ-oxo technetium
complexes with pyridine and halide ligands. J Am Chem Soc 110:1818–1827
Cotton FA, Haefner SC, Sattelberger AP (1996a) Metal-metal multiply-bonded complexes of technetium. 3. Preparation and characterization of phosphine complexes of technetium possessing a
metal-metal bond order of 3.5. Inorg Chem 35:1831–1838
Cotton FA, Haefner SC, Sattelberger AP (1996b) Metal-metal multiply bonded complexes
of technetium. 5. Tris and tetrakis(formamidinato) complexes of ditechnetium. Inorg Chem
35:7350–7357
Cotton FA, Haefner SC, Sattelberger AP (1997) Metal-metal multiply-bonded complexes of technetium. 6. A μ, η 1 , η 2 -CH 3 CN complex prepared via reductive cleavage of the electron-rich
Tc≡Tc triple bond in decakis-acetonitrile ditechnetium tetrafluoroborate. Inorg Chim Acta
266:55–63
Cyr JE, Linder KE, Nowotnik DP (1993) Electrochemistry of boron-capped 99 Tc-dioxime
complexes. Inorg Chim Acta 206(1):97–104
De Gregori I, Lobos S (1989) Electrochemical and chemical reduction of TcO 4
- in dithiols in
alkaline aqueous media. Appl Radiat Lsot 40(5):385–391
deLearie LA, Haltiwanger RC, Pierpont CG (1989) Technetium complexes of 3,5-ditert-butylcatechol. Direct synthesis of tris (3,5-di-tert-butylcatecholato)technetium(VI) and
Bis(3,5-di-tert-butylcatecholato)- (di-teri-butylamidophenolato)technetium(VI) from ammonium pertechnetate. J Am Chem Soc 111:4324–4328
Dilworth R, Hutson AJ, Morton S et al (1992) The preparation and electrochemistry of technetium and rhenium complexes of 2-(diphenylphosphino)benzenethiol. The crystal and molecular
structures of [Re(2-Ph 2 PC 6 H 4 S) 3 ] and [Tc(2-Ph 2 PC 6 H 4 S) 3 ]. Polyhedron 11(17):2151–2155
Einrem RF, Braband H, Fox T (2016) Synthesis and molecular structure of 99 Tc corroles. Chem
Eur J 22:18747–18751
Hunter G, Kilcullen N (1989) Complexes of technetium, rhenium, and rhodium with sexidentate
Schiff-base ligands. J Chem Soc Dalton Trans 2115–2119
Hurst RW, Heineman WR, Deutsch E (1981) Technetium electrochemistry. 1. Spectroelectrochemical studies of halogen, diars, and diphos complexes of technetium in nonaqueous media. Inorg
Chem 20(10):3298–3303
Huy NH (2009) Complexes of rhenium and technetium with chelating thiourea ligands. PhD
dissertation, Institute of Chemistry and Biochemistry, Freie Universität Berlin, Berlin
Ichimura A, Heineman WR, Vanderheyden J-L et al (1984) Technetium electrochemistry. 2. Electrochemical and spectroelectrochemical studies of the bis(tertiary phosphine) (D) complexes
trans-[Tc III D 2 X 2 ] + (X = Cl, Br) and [Tc I D 3 ] + . Inorg Chem 23:1272–1278
