75. Lin P, Ma S, Wang X, Zhou F (2015) Molecularly engineered dual-crosslinked hydrogel with
ultrahigh mechanical strength, toughness, and good self-recovery. Adv Mater 27:2054–2059
76. Zhong M, Liu X-Y, Shi F-K, Zhang L-Q, Wang X-P, Cheetham AG, Cui H, Xie X-M (2015)
Self-healable, tough and highly stretchable ionic nanocomposite physical hydrogels. Soft
Matter 11:4235–4241
77. Shao C, Chang H, Wang M, Xu F, Yang J (2017) High-strength, tough, and self-healing
nanocomposite physical hydrogels based on the synergistic effects of dynamic hydrogen bond
and dual coordination bonds. ACS Appl Mater Interfaces 9:28305–28318
78. Pan C, Liu L, Chen Q, Zhang Q, Guo G (2017) Tough, stretchable, compressive novel
polymer/graphene oxide nanocomposite hydrogels with excellent self-healing performance.
ACS Appl Mater Interfaces 9:38052–38061
79. Ghoorchian A, Simon JR, Bharti B, Han W, Zhao X, Chilkoti A, López GP (2015) Bioinspired
reversibly cross-linked hydrogels comprising polypeptide micelles exhibit enhanced mechanical properties. Adv Funct Mater 25:3122–3130
80. Chandler D (2005) Interfaces and the driving force of hydrophobic assembly. Nature
437:640–647
81. Sun Y, Liu S, Du G, Gao G, Fu J (2015) Multi-responsive and tough hydrogels based on
triblock copolymer micelles as multifunctional macro-crosslinkers. Chem Commun
51:8512–8515
82. Fu J (2020) Triblock copolymer micelle-crosslinked hydrogels. Adv Polym Sci (in press),
https://doi.org/10.1007/12_2019_55
83. Hao J, Weiss RA (2011) Viscoelastic and mechanical behavior of hydrophobically modified
hydrogels. Macromolecules 44:9390–9398
84. Vogt BD, Weiss RA (2020) Hydrophobically associating hydrogels with microphaseseparated morphologies. Adv Polym Sci (in press)
85. Miquelard-Garnier G, Demoures S, Creton C, Hourdet D (2006) Synthesis and rheological
behavior of new hydrophobically modified hydrogels with tunable properties. Macromolecules 39:8128–8139
86. Hill A, Candau F, Selb J (1993) Properties of hydrophobically associating polyacrylamides:
influence of the method of synthesis. Macromolecules 26:4521–4532
87. Volpert E, Selb J, Francoise C (1998) Associating behaviour of polyacrylamides
hydrophobically modified with dihexylacrylamide. Polymer 39:1025–1033
88. Regalado EJ, Selb J, Candau F (1999) Viscoelastic behavior of semidilute solutions of
multisticker polymer chains. Macromolecules 32:8580–8588
89. Candau F, Selb J (1999) Hydrophobically-modified polyacrylamides prepared by micellar
polymerization. Adv Colloid Interface Sci 79:149–172
90. Gao B, Guo H, Wang J, Zhang Y (2008) Preparation of hydrophobic association polyacrylamide in a new micellar copolymerization system and its hydrophobically associative property. Macromolecules 41:2890–2897
91. Bilici C, Okay O (2013) Shape memory hydrogels via micellar copolymerization of acrylic
acid and n-octadecyl acrylate in aqueous media. Macromolecules 46:3125–3131
92. Candau F, Regalado EJ, Selb J (1998) Scaling behavior of the zero shear viscosity of
hydrophobically modified poly(acrylamide)s. Macromolecules 31:5550–5552
93. Kujawa P, Audibert-Hayet A, Selb J, Candau F (2004) Rheological properties of multisticker
associative polyelectrolytes in semidilute aqueous solutions. J Polym Sci B 42:1640–1655
94. Kujawa P, Audibert-Hayet A, Selb J, Candau F (2006) Effect of ionic strength on the
rheological properties of multisticker associative polyelectrolytes. Macromolecules
39:384–392
95. Abdurrahmanoglu S, Can V, Okay O (2009) Design of high-toughness polyacrylamide
hydrogels by hydrophobic modification. Polymer 50:5449–5455
96. Abdurrahmanoglu S, Cilingir M, Okay O (2011) Dodecyl methacrylate as a crosslinker in the
preparation of tough polyacrylamide hydrogels. Polymer 52:694–699
How to Design Both Mechanically Strong and Self-Healable Hydrogels?
59
ultrahigh mechanical strength, toughness, and good self-recovery. Adv Mater 27:2054–2059
76. Zhong M, Liu X-Y, Shi F-K, Zhang L-Q, Wang X-P, Cheetham AG, Cui H, Xie X-M (2015)
Self-healable, tough and highly stretchable ionic nanocomposite physical hydrogels. Soft
Matter 11:4235–4241
77. Shao C, Chang H, Wang M, Xu F, Yang J (2017) High-strength, tough, and self-healing
nanocomposite physical hydrogels based on the synergistic effects of dynamic hydrogen bond
and dual coordination bonds. ACS Appl Mater Interfaces 9:28305–28318
78. Pan C, Liu L, Chen Q, Zhang Q, Guo G (2017) Tough, stretchable, compressive novel
polymer/graphene oxide nanocomposite hydrogels with excellent self-healing performance.
ACS Appl Mater Interfaces 9:38052–38061
79. Ghoorchian A, Simon JR, Bharti B, Han W, Zhao X, Chilkoti A, López GP (2015) Bioinspired
reversibly cross-linked hydrogels comprising polypeptide micelles exhibit enhanced mechanical properties. Adv Funct Mater 25:3122–3130
80. Chandler D (2005) Interfaces and the driving force of hydrophobic assembly. Nature
437:640–647
81. Sun Y, Liu S, Du G, Gao G, Fu J (2015) Multi-responsive and tough hydrogels based on
triblock copolymer micelles as multifunctional macro-crosslinkers. Chem Commun
51:8512–8515
82. Fu J (2020) Triblock copolymer micelle-crosslinked hydrogels. Adv Polym Sci (in press),
https://doi.org/10.1007/12_2019_55
83. Hao J, Weiss RA (2011) Viscoelastic and mechanical behavior of hydrophobically modified
hydrogels. Macromolecules 44:9390–9398
84. Vogt BD, Weiss RA (2020) Hydrophobically associating hydrogels with microphaseseparated morphologies. Adv Polym Sci (in press)
85. Miquelard-Garnier G, Demoures S, Creton C, Hourdet D (2006) Synthesis and rheological
behavior of new hydrophobically modified hydrogels with tunable properties. Macromolecules 39:8128–8139
86. Hill A, Candau F, Selb J (1993) Properties of hydrophobically associating polyacrylamides:
influence of the method of synthesis. Macromolecules 26:4521–4532
87. Volpert E, Selb J, Francoise C (1998) Associating behaviour of polyacrylamides
hydrophobically modified with dihexylacrylamide. Polymer 39:1025–1033
88. Regalado EJ, Selb J, Candau F (1999) Viscoelastic behavior of semidilute solutions of
multisticker polymer chains. Macromolecules 32:8580–8588
89. Candau F, Selb J (1999) Hydrophobically-modified polyacrylamides prepared by micellar
polymerization. Adv Colloid Interface Sci 79:149–172
90. Gao B, Guo H, Wang J, Zhang Y (2008) Preparation of hydrophobic association polyacrylamide in a new micellar copolymerization system and its hydrophobically associative property. Macromolecules 41:2890–2897
91. Bilici C, Okay O (2013) Shape memory hydrogels via micellar copolymerization of acrylic
acid and n-octadecyl acrylate in aqueous media. Macromolecules 46:3125–3131
92. Candau F, Regalado EJ, Selb J (1998) Scaling behavior of the zero shear viscosity of
hydrophobically modified poly(acrylamide)s. Macromolecules 31:5550–5552
93. Kujawa P, Audibert-Hayet A, Selb J, Candau F (2004) Rheological properties of multisticker
associative polyelectrolytes in semidilute aqueous solutions. J Polym Sci B 42:1640–1655
94. Kujawa P, Audibert-Hayet A, Selb J, Candau F (2006) Effect of ionic strength on the
rheological properties of multisticker associative polyelectrolytes. Macromolecules
39:384–392
95. Abdurrahmanoglu S, Can V, Okay O (2009) Design of high-toughness polyacrylamide
hydrogels by hydrophobic modification. Polymer 50:5449–5455
96. Abdurrahmanoglu S, Cilingir M, Okay O (2011) Dodecyl methacrylate as a crosslinker in the
preparation of tough polyacrylamide hydrogels. Polymer 52:694–699
How to Design Both Mechanically Strong and Self-Healable Hydrogels?
59