162
6 Conversion of Methane to Aromatic Hydrocarbons
85. Goodman BR, Hass KC, Schneider WF, Adams JB (2000) Statistical analysis of Al
distributions and metal ion pairing probabilities in zeolites. Catal Lett 68:85–93
86. Tessonnier JP, Louis B, Walspurger S, Sommer J, Ledoux MJ, Pham-Huu C (2006) Quantitative measurement of the Brönsted acid sites in solid acids: toward a single-site design of
Mo-modified ZSM-5 zeolite. J Phys Chem B 110:10390–10395
87. Solymosi F, Erdöhelyi A, Szöke A (1995) Dehydrogenation of methane on supported
molybdenum oxide. Formation of benzene from methane. Catal Lett 32:43–53
88. Wang D, Lunsford JH, Rosynek MP (1997) Characterization of a Mo/ZSM-5 catalyst for the
conversion of methane to benzene. J Catal 169:347–358
89. Eeckhuysen BM, Wang D, Rosynek MP, Lunsford JH (1998) Conversion of methane to
benzene over transition metal ion ZSM-5 zeolites. II Catalyst characterization by X-ray
photoelectron spectroscopy. J Catal 175:347–351
90. Solymois F, Cserényi J, Szöke A, Bánsági T, Oszkó A (1997) Aromatization of methane over
supported and unsupported Mo-based catalysts. J Catal 165:150–161
91. Jiang H, Wang L, Cui W, Xu Y (1999) Study on the induction period of methane aromatization
over Mo/HZSM-5: partial reduction of Mo species and formation of carbonaceous deposit.
Catal Lett 57:95–102
92. Ma D, Shu Y, Cheng M, Xu Y, Bao X (2000) On the induction period of methane aromatization
over Mo-based catalysts. J Catal 194:105–114
93. Ding W, Li S, Meitzner GD, Iglesia E (2001) Methane conversion to aromatics on Mo/HZSM-5: structure of molybdenum species in working catalysts. J Phys Chem B 105:506–513
94. Li B, Li S, Li N, Chen H, Zhang W, Bao X, Lin B (2006) Structure and acidity of Mo/ZSM5 synthesized by solid state reaction for methane dehydrogenateion and aromatization.
Microporous Mesoporous Mater 88:244–253
95. Liu H, Bao X, Xu Y (2006) Methane dehydroaromatization under nonoxidative conditions
over Mo/HZSM-5 catalysts: identification and preparation of the Mo active species. J Catal
239:441–450
96. Vollmer I, van der Linden B, Ould-Chikh S, Aguilar-Tapia A, Yarulina I, Abou-Hamad E,
Sneider YG, Suarez AIO, Hazemann JL, Kaptteijin F, Gascon G (2018) On the dynamic
nature of Mo sites for methane dehydroaromatization. Chem Sci 9:4801–4807
97. Budde PK, Singh AK, Upadhyayula S (2018) Non-oxidative methane dehydroaromatization
reaction over highly active α-MoC1-x ZSM-5 derived from pretreatment. J Chem Sci (Berlin
Germany) 130:1–6. https://doi.org/10.1007/s12039-018-1432-5
98. Lezcano-González I, Oord R, Rovezzi M, Glatzel P, Botchway SW, Weckhuysen BM, Beale
AM (2016) Molybdenum speciation and its impact on catalytic activity during methane dehydroaromatization in zeolite ZSM-5 as revealed by operand X-ray method. Angew Chem Int
Ed 55:5215–5219
99. Ma D, Shu Y, Bao X, Xu Y (2000) Methane dehydro-aromatization under nonoxidative
conditions over Mo/HZSM-5 catalysts: ESR study of the Mo species on/in the ZSM-5 zeolite.
J Catal 189:314–325
100. Solymois F, Szöke A, Cserényi J (1996) Conversion of methane to benzene over MO 2 C and
Mo 2 C/ZSM-5 catalysts. Catal Lett 39:157–161
101. Liu H, Shen Bao WX, Xu Y (2005) Methane dehydroaromatization over Mo/H-ZSM-5 catalysts: the reactivity of MoC X species formed from Mo X associated and non-associated with
Brönsted acid sites. Appl Catal A: General 295:79–88
102. Zhang JZ, Log MA, Howe RF (1998) Molybdenum ZSM-5 zeolite catalysts fir the conversion
of methane to benzene. Catal Today 44:293–300
103. Liu H, Shen W, Bao X, Xu Y (2006) Identification of Mo active species for methane dehydroaromatization over Mo/HZSM-5 catalyst in the absence of oxygen: 1 H MAS NMR and EPR
investigations. J Mol Catal A Chemical 244:229–236
104. Pierella LB, Wang L, Anunziata OA (1997) Methane direct conversion to aromatic
hydrocarbons at low reaction temperature. React Kinet Catal Lett 60:101–106
105. Sheng H, Schreiner EP, Zheng W, Loba RF (2018) Non-oxidative coupling of methane to
ethylene using Mo 2 C/[B]-ZSM-5. ChemPhysChem 19:504–511
6 Conversion of Methane to Aromatic Hydrocarbons
85. Goodman BR, Hass KC, Schneider WF, Adams JB (2000) Statistical analysis of Al
distributions and metal ion pairing probabilities in zeolites. Catal Lett 68:85–93
86. Tessonnier JP, Louis B, Walspurger S, Sommer J, Ledoux MJ, Pham-Huu C (2006) Quantitative measurement of the Brönsted acid sites in solid acids: toward a single-site design of
Mo-modified ZSM-5 zeolite. J Phys Chem B 110:10390–10395
87. Solymosi F, Erdöhelyi A, Szöke A (1995) Dehydrogenation of methane on supported
molybdenum oxide. Formation of benzene from methane. Catal Lett 32:43–53
88. Wang D, Lunsford JH, Rosynek MP (1997) Characterization of a Mo/ZSM-5 catalyst for the
conversion of methane to benzene. J Catal 169:347–358
89. Eeckhuysen BM, Wang D, Rosynek MP, Lunsford JH (1998) Conversion of methane to
benzene over transition metal ion ZSM-5 zeolites. II Catalyst characterization by X-ray
photoelectron spectroscopy. J Catal 175:347–351
90. Solymois F, Cserényi J, Szöke A, Bánsági T, Oszkó A (1997) Aromatization of methane over
supported and unsupported Mo-based catalysts. J Catal 165:150–161
91. Jiang H, Wang L, Cui W, Xu Y (1999) Study on the induction period of methane aromatization
over Mo/HZSM-5: partial reduction of Mo species and formation of carbonaceous deposit.
Catal Lett 57:95–102
92. Ma D, Shu Y, Cheng M, Xu Y, Bao X (2000) On the induction period of methane aromatization
over Mo-based catalysts. J Catal 194:105–114
93. Ding W, Li S, Meitzner GD, Iglesia E (2001) Methane conversion to aromatics on Mo/HZSM-5: structure of molybdenum species in working catalysts. J Phys Chem B 105:506–513
94. Li B, Li S, Li N, Chen H, Zhang W, Bao X, Lin B (2006) Structure and acidity of Mo/ZSM5 synthesized by solid state reaction for methane dehydrogenateion and aromatization.
Microporous Mesoporous Mater 88:244–253
95. Liu H, Bao X, Xu Y (2006) Methane dehydroaromatization under nonoxidative conditions
over Mo/HZSM-5 catalysts: identification and preparation of the Mo active species. J Catal
239:441–450
96. Vollmer I, van der Linden B, Ould-Chikh S, Aguilar-Tapia A, Yarulina I, Abou-Hamad E,
Sneider YG, Suarez AIO, Hazemann JL, Kaptteijin F, Gascon G (2018) On the dynamic
nature of Mo sites for methane dehydroaromatization. Chem Sci 9:4801–4807
97. Budde PK, Singh AK, Upadhyayula S (2018) Non-oxidative methane dehydroaromatization
reaction over highly active α-MoC1-x ZSM-5 derived from pretreatment. J Chem Sci (Berlin
Germany) 130:1–6. https://doi.org/10.1007/s12039-018-1432-5
98. Lezcano-González I, Oord R, Rovezzi M, Glatzel P, Botchway SW, Weckhuysen BM, Beale
AM (2016) Molybdenum speciation and its impact on catalytic activity during methane dehydroaromatization in zeolite ZSM-5 as revealed by operand X-ray method. Angew Chem Int
Ed 55:5215–5219
99. Ma D, Shu Y, Bao X, Xu Y (2000) Methane dehydro-aromatization under nonoxidative
conditions over Mo/HZSM-5 catalysts: ESR study of the Mo species on/in the ZSM-5 zeolite.
J Catal 189:314–325
100. Solymois F, Szöke A, Cserényi J (1996) Conversion of methane to benzene over MO 2 C and
Mo 2 C/ZSM-5 catalysts. Catal Lett 39:157–161
101. Liu H, Shen Bao WX, Xu Y (2005) Methane dehydroaromatization over Mo/H-ZSM-5 catalysts: the reactivity of MoC X species formed from Mo X associated and non-associated with
Brönsted acid sites. Appl Catal A: General 295:79–88
102. Zhang JZ, Log MA, Howe RF (1998) Molybdenum ZSM-5 zeolite catalysts fir the conversion
of methane to benzene. Catal Today 44:293–300
103. Liu H, Shen W, Bao X, Xu Y (2006) Identification of Mo active species for methane dehydroaromatization over Mo/HZSM-5 catalyst in the absence of oxygen: 1 H MAS NMR and EPR
investigations. J Mol Catal A Chemical 244:229–236
104. Pierella LB, Wang L, Anunziata OA (1997) Methane direct conversion to aromatic
hydrocarbons at low reaction temperature. React Kinet Catal Lett 60:101–106
105. Sheng H, Schreiner EP, Zheng W, Loba RF (2018) Non-oxidative coupling of methane to
ethylene using Mo 2 C/[B]-ZSM-5. ChemPhysChem 19:504–511