10 The Design of Porous Organic Salts with Hierarchical Process
189
Fig. 10.2 Crystal structures of d-POSs. Top view and void space of d-POSs a composed of 2-AS
and TPMA including TCB (d-POS-2a) and b 1-PyS and TPMA including TMB (d-POS-3). In the
top view, template molecules are omitted for clarity. In the sky-blue-colored void space, template
molecules are represented by green balls and sticks. Hydrogen atoms are omitted for clarity except
in the space-filling model of a cluster. Hierarchical interpretation of c d-POS-2a and d d-POS-3.
In the diamondoid networks and interpenetrated structures, triphenylmethyl groups are omitted for
clarity. The independent diamondoid networks are indicated by orange, green, and blue
Fig. 10.3 a Cubic-like hydrogen bonding network in the tetrahedral supramolecular cluster.
b π-π stacking manners between the clusters in d-POS-2a. c Close up view between the clusters in
different diamondoid networks. Red lines represent CH-π intercluster contacts
189
Fig. 10.2 Crystal structures of d-POSs. Top view and void space of d-POSs a composed of 2-AS
and TPMA including TCB (d-POS-2a) and b 1-PyS and TPMA including TMB (d-POS-3). In the
top view, template molecules are omitted for clarity. In the sky-blue-colored void space, template
molecules are represented by green balls and sticks. Hydrogen atoms are omitted for clarity except
in the space-filling model of a cluster. Hierarchical interpretation of c d-POS-2a and d d-POS-3.
In the diamondoid networks and interpenetrated structures, triphenylmethyl groups are omitted for
clarity. The independent diamondoid networks are indicated by orange, green, and blue
Fig. 10.3 a Cubic-like hydrogen bonding network in the tetrahedral supramolecular cluster.
b π-π stacking manners between the clusters in d-POS-2a. c Close up view between the clusters in
different diamondoid networks. Red lines represent CH-π intercluster contacts