Index
323
electromotive force .....52, 105, 208, 213
electroneutrality .........10, 12, 25, 35, 42,
100, 116, 142, 156, 248, 254, 271
energy density ...................................285
enthalpy
– of migration ........107, 128, 135, 160
equivalent electric circuit ............60, 181
extrinsic
– defect ..................8, 23, 45, 152, 156
– domain ..........................67, 135, 253
– vacancy ...............................107, 131
F
factor
correlation – .....................................95
geometric – 59, 75, 103, 126, 192, 267
Fick’s law ............92, 172, 179, 190, 303
flux
electrochemical semipermeability – ....
53, 102, 158
specific – ..........................................90
fraction
insertion – ......................................251
fractional surface coverage .......177, 199
free-volume model ....................118, 159
Frenkel disorder .........9, 16, 31, 97, 104,
212, 213, 243
frequency response analyzer .............180
fuel cell ..............210, 211, 236, 287, 290
G
glass........................... 105, 111, 131, 144
– former ................................. 111, 144
– modifier .............................. 111, 144
glass transition temperature ..............118
H
Hebb-Wagner method ...................58, 63
Hittorf method .....................................54
hopping .............................................163
activated-hopping model .................93
– distance .........................94, 104, 128
– frequency ......................................93
– probability ...........................118, 159
hydrocarbon ..............................238, 293
I
impedance
complex – ..........47, 51, 60, 73, 74, 91
– diagram .......................177, 181, 191
– spectroscopy .................................47
inductance .....................47, 51, 181, 192
insertion .......................................41, 138
– material .......................211, 217, 250
interface ..........55, 62, 84, 100, 113, 147,
157, 179, 206, 222, 233, 259, 279, 280
intrinsic vacancy .........................45, 141
iron monoxide ...............................20, 33
isoelectric point .........................223, 261
K
Knudsen diffusion .............207, 228, 275
Kröger-Vink notation ........8, 15, 24, 226
L
Langmuir equation ............................186
lanthanum cobaltite .....................64, 180
lanthanum manganite ........................211
least squares fit ...................60, 161, 181,
194, 217, 249
liquid junction ...................................214
M
method
four-electrode – ..........................59, 71
Hebb-Wagner – ..........................58, 63
Hittorf – ...........................................54
Tubandt – ...................................54, 90
migration .............................54, 104, 192
electric – ..........................................92
enthalpy of – ..........107, 128, 135, 160
ionic – ..............................................86
mobility .............................................104
electric – ..................93, 151, 248, 270
electrochemical – .............91, 134, 220
hole – .............................................217
ionic – ........................................83, 95
323
electromotive force .....52, 105, 208, 213
electroneutrality .........10, 12, 25, 35, 42,
100, 116, 142, 156, 248, 254, 271
energy density ...................................285
enthalpy
– of migration ........107, 128, 135, 160
equivalent electric circuit ............60, 181
extrinsic
– defect ..................8, 23, 45, 152, 156
– domain ..........................67, 135, 253
– vacancy ...............................107, 131
F
factor
correlation – .....................................95
geometric – 59, 75, 103, 126, 192, 267
Fick’s law ............92, 172, 179, 190, 303
flux
electrochemical semipermeability – ....
53, 102, 158
specific – ..........................................90
fraction
insertion – ......................................251
fractional surface coverage .......177, 199
free-volume model ....................118, 159
Frenkel disorder .........9, 16, 31, 97, 104,
212, 213, 243
frequency response analyzer .............180
fuel cell ..............210, 211, 236, 287, 290
G
glass........................... 105, 111, 131, 144
– former ................................. 111, 144
– modifier .............................. 111, 144
glass transition temperature ..............118
H
Hebb-Wagner method ...................58, 63
Hittorf method .....................................54
hopping .............................................163
activated-hopping model .................93
– distance .........................94, 104, 128
– frequency ......................................93
– probability ...........................118, 159
hydrocarbon ..............................238, 293
I
impedance
complex – ..........47, 51, 60, 73, 74, 91
– diagram .......................177, 181, 191
– spectroscopy .................................47
inductance .....................47, 51, 181, 192
insertion .......................................41, 138
– material .......................211, 217, 250
interface ..........55, 62, 84, 100, 113, 147,
157, 179, 206, 222, 233, 259, 279, 280
intrinsic vacancy .........................45, 141
iron monoxide ...............................20, 33
isoelectric point .........................223, 261
K
Knudsen diffusion .............207, 228, 275
Kröger-Vink notation ........8, 15, 24, 226
L
Langmuir equation ............................186
lanthanum cobaltite .....................64, 180
lanthanum manganite ........................211
least squares fit ...................60, 161, 181,
194, 217, 249
liquid junction ...................................214
M
method
four-electrode – ..........................59, 71
Hebb-Wagner – ..........................58, 63
Hittorf – ...........................................54
Tubandt – ...................................54, 90
migration .............................54, 104, 192
electric – ..........................................92
enthalpy of – ..........107, 128, 135, 160
ionic – ..............................................86
mobility .............................................104
electric – ..................93, 151, 248, 270
electrochemical – .............91, 134, 220
hole – .............................................217
ionic – ........................................83, 95