322
crystal
perfect – .......................................7, 33
real – ..................................................7
current
diffusion-limited – ................178, 207,
228, 274, 275
electric – ..........................83, 209, 268
exchange – .....................175, 185, 198
current density .....92, 158, 172, 189, 289
exchange – .............................173, 199
D
decentering ..........................................74
– angle .......................................61, 76
– parameter ......................................60
defect
extrinsic – ..............8, 23, 45, 152, 156
intrinsic – .....................................8, 22
point – ..........................9, 27, 115, 154
structure – ..........................15, 24, 255
desorption ............53, 102, 172, 178, 198
diagram
Brouwer – .... 11, 35, 97, 112, 150, 255
impedance – ...................177, 181, 191
Nyquist – .........................................49
dielectric constant ...................52, 62, 76
diffusion .....................93, 107, 113, 176,
179, 216, 290
chemical – ........................................92
– coefficient ............92, 107, 108, 114,
134, 152, 182, 275
element of – ...................................193
Knudsen – ......................207, 228, 275
– limited current ...................178, 207,
228, 274, 275
oxygen – ........................................150
– regime .................................175, 276
self – ......................................107, 137
semi-infinite – ................................176
dilatocoulometry ...........................65, 83
dipole .............................................47, 73
disorder
electronic – ................................9, 256
Frenkel – .........................9, 16, 31, 97,
104, 212, 213, 243
anionic – .......................................10
cationic – ......................................10
intrinsic – .....................................9, 26
Schottky – ..9, 10, 16, 25, 95, 184, 194
domain
electrolytic – ................14, 45, 97, 255
extrinsic – ........................67, 135, 253
ionicity – ............................13, 46, 255
doping .................................18, 195, 255
– level ......................................98, 135
– reaction .....10, 16, 25, 131, 156, 243
E
effective charge ...............................8, 15
efficiency
coulombic – ...................................210
thermodynamic – ...................237, 291
electrochemical
– cell ..........62, 65, 180, 191, 243, 274
– chain ...... 52, 77, 100, 105, 111, 114,
147, 206, 212, 214, 220, 223, 225,
231, 236, 244, 256, 262, 285, 287
– coloration ............................ 111, 146
– generator .....................................208
– kinetics ........................................171
– pump ...................................182, 194
– semipermeability ....53, 56, 102, 131
electrode ..............................................59
blocking – ......................57, 62, 77, 81
counter – ..........................................58
negative – .......................209, 268, 290
oxygen – ........................180, 192, 268
– polarization .................................172
positive – ...............................209, 290
– potential ......................144, 171, 185
– reaction .52, 180, 192, 231, 239, 282
reference – 62, 77, 113, 171, 185, 223,
233, 258, 282
– thermodynamics .........................171
working – .....................58, 62, 77, 176
electrolysis ......................55, 66, 83, 208
electrolyte
solid – .....46, 102, 158, 171, 206, 212,
222, 234, 274, 283, 287
weak – (model) ..............................115
Solid-State Electrochemistry
crystal
perfect – .......................................7, 33
real – ..................................................7
current
diffusion-limited – ................178, 207,
228, 274, 275
electric – ..........................83, 209, 268
exchange – .....................175, 185, 198
current density .....92, 158, 172, 189, 289
exchange – .............................173, 199
D
decentering ..........................................74
– angle .......................................61, 76
– parameter ......................................60
defect
extrinsic – ..............8, 23, 45, 152, 156
intrinsic – .....................................8, 22
point – ..........................9, 27, 115, 154
structure – ..........................15, 24, 255
desorption ............53, 102, 172, 178, 198
diagram
Brouwer – .... 11, 35, 97, 112, 150, 255
impedance – ...................177, 181, 191
Nyquist – .........................................49
dielectric constant ...................52, 62, 76
diffusion .....................93, 107, 113, 176,
179, 216, 290
chemical – ........................................92
– coefficient ............92, 107, 108, 114,
134, 152, 182, 275
element of – ...................................193
Knudsen – ......................207, 228, 275
– limited current ...................178, 207,
228, 274, 275
oxygen – ........................................150
– regime .................................175, 276
self – ......................................107, 137
semi-infinite – ................................176
dilatocoulometry ...........................65, 83
dipole .............................................47, 73
disorder
electronic – ................................9, 256
Frenkel – .........................9, 16, 31, 97,
104, 212, 213, 243
anionic – .......................................10
cationic – ......................................10
intrinsic – .....................................9, 26
Schottky – ..9, 10, 16, 25, 95, 184, 194
domain
electrolytic – ................14, 45, 97, 255
extrinsic – ........................67, 135, 253
ionicity – ............................13, 46, 255
doping .................................18, 195, 255
– level ......................................98, 135
– reaction .....10, 16, 25, 131, 156, 243
E
effective charge ...............................8, 15
efficiency
coulombic – ...................................210
thermodynamic – ...................237, 291
electrochemical
– cell ..........62, 65, 180, 191, 243, 274
– chain ...... 52, 77, 100, 105, 111, 114,
147, 206, 212, 214, 220, 223, 225,
231, 236, 244, 256, 262, 285, 287
– coloration ............................ 111, 146
– generator .....................................208
– kinetics ........................................171
– pump ...................................182, 194
– semipermeability ....53, 56, 102, 131
electrode ..............................................59
blocking – ......................57, 62, 77, 81
counter – ..........................................58
negative – .......................209, 268, 290
oxygen – ........................180, 192, 268
– polarization .................................172
positive – ...............................209, 290
– potential ......................144, 171, 185
– reaction .52, 180, 192, 231, 239, 282
reference – 62, 77, 113, 171, 185, 223,
233, 258, 282
– thermodynamics .........................171
working – .....................58, 62, 77, 176
electrolysis ......................55, 66, 83, 208
electrolyte
solid – .....46, 102, 158, 171, 206, 212,
222, 234, 274, 283, 287
weak – (model) ..............................115
Solid-State Electrochemistry