578
M. Morimoto and M. Irie
17. Betzig E, Patterson GH, Sougrat R, Lindwasser OW, Olenych S, Bonifacino JS, Davidson MW,
Lippincott-Schwartz J, Hess HF (2006) Imaging intracellular fluorescent proteins at nanometer
resolution. Science 313:1642–1645
18. Rust MJ, Bates M, Zhuang X (2006) Sub-diffraction-limit imaging by stochastic optical
reconstruction microscopy (STORM). Nat Meth 3:793–796
19. Raymo FM (2013) Photoactivatable synthetic fluorophores. Phys Chem Chem Phys 15:14840–
14850
20. Lord SJ, Conley NR, Lee HD, Samuel R, Liu N, Twieg RJ, Moerner WE (2008) A photoactivatable push–pull fluorophore for single-molecule imaging in live cells. J Am Chem Soc
130:9204–9205
21. Fölling J, Belov V, Kunetsky R, Medda R, Schönle A, Egner A, Eggeling C, Bossi M, Hell SW
(2007) Photochromic rhodamines provide nanoscopy with optical sectioning. Angew Chem
Int Ed 46:6266–6270
22. Lee MK, Rai P, Williams J, Twieg RJ, Moerner WE (2014) Small-molecule labeling of live cell
surfaces for three-dimensional super-resolution microscopy. J Am Chem Soc 136:14003–14006
23. Kobayashi T, Urano Y, Kamiya M, Ueno T, Kojima H, Nagano T (2007) Highly activatable
and rapidly releasable caged fluorescein derivatives. J Am Chem Soc 129:6696–6697
24. Kobayashi T, Komatsu T, Kamiya M, Campos C, González-Gaitán M, Terai T, Hanaoka K,
Nagano T, Urano Y (2012) Highly activatable and environment-insensitive optical highlighters
for selective spatiotemporal imaging of target proteins. J Am Chem Soc 134:11153–11160
25. Deniz E, Tomasulo M, Cusido J, Yildiz I, Petriella M, Bossi ML, Sortino S, Raymo FM (2012)
Photoactivatable fluorophores for super-resolution imaging based on oxazine auxochromes. J
Phys Chem C 116:6058–6068
26. Thapaliya ER, Captain B, Raymo FM (2014) Photoactivatable anthracenes. J Org Chem
79:3973–3981
27. Irie M, Morimoto M (2018) Photoswitchable turn-on mode fluorescent diarylethenes: strategies
for controlling the switching response. Bull Chem Soc Jpn 91:237–250
28. Morimoto M, Irie M (2017) Turn-on mode fluorescent diarylethenes. In: Yokoyama Y, Nakatani
K (eds) Photon-working switches. Springer, Tokyo
29. Jeong Y-C, Yang SI, Ahn K-H, Kim E (2005) Highly fluorescent photochromic diarylethene
in the closed-ring form. Chem Commun 2503–2505
30. Jeong Y-C, Yang SI, Kim E, Ahn K-H (2006) Development of highly fluorescent photochromic
material with high fatigue resistance. Tetrahedron 62:5855–5861
31. Jeong Y-C, Park DG, Lee IS, Yang SI, Ahn K-H (2009) Highly fluorescent photochromic
diarylethene with an excellent fatigue property. J Mater Chem 19:97–103
32. Sumi T, Takagi Y, Yagi A, Morimoto M, Irie M (2014) Photoirradiation wavelength dependence
of cycloreversion quantum yields of diarylethenes. Chem Commun 50:3928–3930
33. Uno K, Niikura H, Morimoto M, Ishibashi Y, Miyasaka H, Irie M (2011) In situ preparation
of highly fluorescent dyes upon photoirradiation. J Am Chem Soc 133:13558–13564
34. Takagi Y, Kunishi T, Katayama T, Ishibashi Y, Miyasaka H, Morimoto M, Irie M (2012) Photoswitchable fluorescent diarylethene derivatives with short alkyl chain substituents. Photochem
Photobiol Sci 11:1661–1665
35. Irie M, Eriguchi T, Takada T, Uchida K (1997) Photochromism of diarylethenes having
thiophene oligomers as the aryl groups. Tetrahedron 53:12263–12271
36. Dedecker P, Hotta J, Flors C, Sliwa M, Uji-i H, Roeffaers MBJ, Ando R, Mizuno H, Miyawaki
A, Hofkens J (2007) Subdiffraction imaging through the selective donut-mode depletion of
thermally stable photoswitchable fluorophores: Numerical analysis and application to the
fluorescent protein Dronpa. J Am Chem Soc 129:16132–16141
37. Takagi Y, Morimoto M, Kashihara R, Fujinami S, Ito S, Miayasaka H (2017) Irie M Turnon mode fluorescent diarylethenes: control of the cycloreversion quantum yield. Tetrahedron
73:4918–4924
38. Morimoto M, Sumi T, Irie M (2017) Photoswitchable fluorescent diarylethene derivatives with
thiophene 1,1-dioxide groups: effect of alkyl substituents at the reactive carbons. Materials
10:1021
M. Morimoto and M. Irie
17. Betzig E, Patterson GH, Sougrat R, Lindwasser OW, Olenych S, Bonifacino JS, Davidson MW,
Lippincott-Schwartz J, Hess HF (2006) Imaging intracellular fluorescent proteins at nanometer
resolution. Science 313:1642–1645
18. Rust MJ, Bates M, Zhuang X (2006) Sub-diffraction-limit imaging by stochastic optical
reconstruction microscopy (STORM). Nat Meth 3:793–796
19. Raymo FM (2013) Photoactivatable synthetic fluorophores. Phys Chem Chem Phys 15:14840–
14850
20. Lord SJ, Conley NR, Lee HD, Samuel R, Liu N, Twieg RJ, Moerner WE (2008) A photoactivatable push–pull fluorophore for single-molecule imaging in live cells. J Am Chem Soc
130:9204–9205
21. Fölling J, Belov V, Kunetsky R, Medda R, Schönle A, Egner A, Eggeling C, Bossi M, Hell SW
(2007) Photochromic rhodamines provide nanoscopy with optical sectioning. Angew Chem
Int Ed 46:6266–6270
22. Lee MK, Rai P, Williams J, Twieg RJ, Moerner WE (2014) Small-molecule labeling of live cell
surfaces for three-dimensional super-resolution microscopy. J Am Chem Soc 136:14003–14006
23. Kobayashi T, Urano Y, Kamiya M, Ueno T, Kojima H, Nagano T (2007) Highly activatable
and rapidly releasable caged fluorescein derivatives. J Am Chem Soc 129:6696–6697
24. Kobayashi T, Komatsu T, Kamiya M, Campos C, González-Gaitán M, Terai T, Hanaoka K,
Nagano T, Urano Y (2012) Highly activatable and environment-insensitive optical highlighters
for selective spatiotemporal imaging of target proteins. J Am Chem Soc 134:11153–11160
25. Deniz E, Tomasulo M, Cusido J, Yildiz I, Petriella M, Bossi ML, Sortino S, Raymo FM (2012)
Photoactivatable fluorophores for super-resolution imaging based on oxazine auxochromes. J
Phys Chem C 116:6058–6068
26. Thapaliya ER, Captain B, Raymo FM (2014) Photoactivatable anthracenes. J Org Chem
79:3973–3981
27. Irie M, Morimoto M (2018) Photoswitchable turn-on mode fluorescent diarylethenes: strategies
for controlling the switching response. Bull Chem Soc Jpn 91:237–250
28. Morimoto M, Irie M (2017) Turn-on mode fluorescent diarylethenes. In: Yokoyama Y, Nakatani
K (eds) Photon-working switches. Springer, Tokyo
29. Jeong Y-C, Yang SI, Ahn K-H, Kim E (2005) Highly fluorescent photochromic diarylethene
in the closed-ring form. Chem Commun 2503–2505
30. Jeong Y-C, Yang SI, Kim E, Ahn K-H (2006) Development of highly fluorescent photochromic
material with high fatigue resistance. Tetrahedron 62:5855–5861
31. Jeong Y-C, Park DG, Lee IS, Yang SI, Ahn K-H (2009) Highly fluorescent photochromic
diarylethene with an excellent fatigue property. J Mater Chem 19:97–103
32. Sumi T, Takagi Y, Yagi A, Morimoto M, Irie M (2014) Photoirradiation wavelength dependence
of cycloreversion quantum yields of diarylethenes. Chem Commun 50:3928–3930
33. Uno K, Niikura H, Morimoto M, Ishibashi Y, Miyasaka H, Irie M (2011) In situ preparation
of highly fluorescent dyes upon photoirradiation. J Am Chem Soc 133:13558–13564
34. Takagi Y, Kunishi T, Katayama T, Ishibashi Y, Miyasaka H, Morimoto M, Irie M (2012) Photoswitchable fluorescent diarylethene derivatives with short alkyl chain substituents. Photochem
Photobiol Sci 11:1661–1665
35. Irie M, Eriguchi T, Takada T, Uchida K (1997) Photochromism of diarylethenes having
thiophene oligomers as the aryl groups. Tetrahedron 53:12263–12271
36. Dedecker P, Hotta J, Flors C, Sliwa M, Uji-i H, Roeffaers MBJ, Ando R, Mizuno H, Miyawaki
A, Hofkens J (2007) Subdiffraction imaging through the selective donut-mode depletion of
thermally stable photoswitchable fluorophores: Numerical analysis and application to the
fluorescent protein Dronpa. J Am Chem Soc 129:16132–16141
37. Takagi Y, Morimoto M, Kashihara R, Fujinami S, Ito S, Miayasaka H (2017) Irie M Turnon mode fluorescent diarylethenes: control of the cycloreversion quantum yield. Tetrahedron
73:4918–4924
38. Morimoto M, Sumi T, Irie M (2017) Photoswitchable fluorescent diarylethene derivatives with
thiophene 1,1-dioxide groups: effect of alkyl substituents at the reactive carbons. Materials
10:1021