22. Tanaka H, Ikenosako M, Kato Y, Fujiki M, Inoue Y, Mori T (2018) Symmetry-based rational
design for boosting chiroptical responses. Commun Chem 1:38. https://doi.org/10.1038/
s42004-018-0035-x
23. Mori T, Tanaka T, Higashino T, Yoshida K, Osuka A (2016) Combined experimental and
theoretical investigations on optical activities of Möbius aromatic and Möbius antiaromatic
hexaphyrin phosphorus complexes. J Phys Chem A 120:4241–4248. https://doi.org/10.1021/
acs.jpca.6b03978
24. Kang J, Miyajima D, Itoh Y, Mori T, Tanaka H, Yamauchi M, Inoue Y, Harada S, Aida T
(2014) C5-Symmetric chiral corannulenes: desymmetrization of bowl inversion equilibrium via
“intramolecular” hydrogen-bonding network. J Am Chem Soc 136:10640–10644. https://doi.
org/10.1021/ja505941b
25. Mori T, Ko YH, Kim K, Inoue Y (2006) Circular dichroism of intra- and intermolecular chargetransfer complexes. enhancement of anisotropy factors by dimer formation and by confinement.
J Org Chem 71:3232–3247. https://doi.org/10.1021/jo0602672
26. Mori T, Inoue Y (2005) Circular dichroism of a chiral tethered donor-acceptor system:
enhanced anisotropy factors in charge-transfer transitions by dimer formation and by confinement. Angew Chem Int Ed 44:2582–2585. https://doi.org/10.1002/ange.200462071
27. Kang J, Miyajima D, Mori T, Inoue Y, Itoh Y, Aida T (2015) A rational strategy for the
realization of chain-growth supramolecular polymerization. Science 347:646–651. https://doi.
org/10.1126/science.aaa4249
28. Yamagishi H, Fukino T, Hashizume D, Mori T, Inoue Y, Hikima T, Takata M, Aida T (2015)
metal-organic nanotube with helical and propeller-chiral motifs composed of a C 10 -symmetric
double-decker nanoring. J Am Chem Soc 137:7628–7631. https://doi.org/10.1021/jacs.
5b04386
29. Toyoda M, Imai Y, Mori T (2017) Propeller chirality of boron heptaaryldipyrromethene:
unprecedented supramolecular dimerization and chiroptical properties. J Phys Chem Lett
8:42–48. https://doi.org/10.1021/acs.jpclett.6b02492
30. Goldup SM (2016) Mechanical chirality: a chiral catalyst with a eing to it. Nat Chem
8:404–406. https://doi.org/10.1038/nchem.2509
31. Cakmak Y, Erbas-Cakmak S, Leigh DA (2016) Asymmetric catalysis with a mechanically
point-chiral rotaxane. J Am Chem Soc 138:1749–1751. https://doi.org/10.1021/jacs.6b00303
32. Bordoli RJ, Goldup SM (2014) An efficient approach to mechanically planar chiral rotaxanes.
J Am Chem Soc 136:4817–4820. https://doi.org/10.1021/ja412715m
33. Tachibana Y, Kihara N, Takata T (2004) Asymmetric benzoin condensation catalyzed by chiral
rotaxanes tethering a thiazolium salt moiety via the cooperation of the component: can rotaxane
be an effective reaction field? J Am Chem Soc 126:3438–3439. https://doi.org/10.1021/
ja039461l
34. Vij V, Bhalla V, Kumar M (2016) Hexaarylbenzene: evolution of properties and applications of
multitalented scaffold. Chem Rev 116:9565–9627. https://doi.org/10.1021/acs.chemrev.
6b00144
35. Loxq P, Manoury E, Poli R, Deydier E, Labande A (2016) Synthesis of axially chiral biaryl
compounds by asymmetric catalytic reactions with transition metals. Coord Chem Rev
308:131–190. https://doi.org/10.1016/j.ccr.2015.07.006
36. Kumarasamy E, Ayitou AJ-L, Vallavoju N, Raghunathan R, Iyer A, Clay A, Kandappa SK,
Sivaguru J (2016) Tale of twisted molecules. Atroposelective photoreactions: taming light
induced asymmetric transformations through non-biaryl atropisomers. Acc Chem Res
49:2713–2724. https://doi.org/10.1021/acs.accounts.6b00357
37. Cozzi PG, Emer E, Gualandi A (2011) Atroposelective organocatalysis. Angew Chem Int Ed
50:3847–3849. https://doi.org/10.1002/anie.201008031
38. Durairaj K (1994) Modern concepts and strategies in synthesis of biaryl compounds. Curr Sci
66:833–838
39. Bringmann G, Walter R, Weirich R (1990) Modern strategies for constructing biaryl compounds. Angew Chem 102:1006–1019
172
T. Mori
design for boosting chiroptical responses. Commun Chem 1:38. https://doi.org/10.1038/
s42004-018-0035-x
23. Mori T, Tanaka T, Higashino T, Yoshida K, Osuka A (2016) Combined experimental and
theoretical investigations on optical activities of Möbius aromatic and Möbius antiaromatic
hexaphyrin phosphorus complexes. J Phys Chem A 120:4241–4248. https://doi.org/10.1021/
acs.jpca.6b03978
24. Kang J, Miyajima D, Itoh Y, Mori T, Tanaka H, Yamauchi M, Inoue Y, Harada S, Aida T
(2014) C5-Symmetric chiral corannulenes: desymmetrization of bowl inversion equilibrium via
“intramolecular” hydrogen-bonding network. J Am Chem Soc 136:10640–10644. https://doi.
org/10.1021/ja505941b
25. Mori T, Ko YH, Kim K, Inoue Y (2006) Circular dichroism of intra- and intermolecular chargetransfer complexes. enhancement of anisotropy factors by dimer formation and by confinement.
J Org Chem 71:3232–3247. https://doi.org/10.1021/jo0602672
26. Mori T, Inoue Y (2005) Circular dichroism of a chiral tethered donor-acceptor system:
enhanced anisotropy factors in charge-transfer transitions by dimer formation and by confinement. Angew Chem Int Ed 44:2582–2585. https://doi.org/10.1002/ange.200462071
27. Kang J, Miyajima D, Mori T, Inoue Y, Itoh Y, Aida T (2015) A rational strategy for the
realization of chain-growth supramolecular polymerization. Science 347:646–651. https://doi.
org/10.1126/science.aaa4249
28. Yamagishi H, Fukino T, Hashizume D, Mori T, Inoue Y, Hikima T, Takata M, Aida T (2015)
metal-organic nanotube with helical and propeller-chiral motifs composed of a C 10 -symmetric
double-decker nanoring. J Am Chem Soc 137:7628–7631. https://doi.org/10.1021/jacs.
5b04386
29. Toyoda M, Imai Y, Mori T (2017) Propeller chirality of boron heptaaryldipyrromethene:
unprecedented supramolecular dimerization and chiroptical properties. J Phys Chem Lett
8:42–48. https://doi.org/10.1021/acs.jpclett.6b02492
30. Goldup SM (2016) Mechanical chirality: a chiral catalyst with a eing to it. Nat Chem
8:404–406. https://doi.org/10.1038/nchem.2509
31. Cakmak Y, Erbas-Cakmak S, Leigh DA (2016) Asymmetric catalysis with a mechanically
point-chiral rotaxane. J Am Chem Soc 138:1749–1751. https://doi.org/10.1021/jacs.6b00303
32. Bordoli RJ, Goldup SM (2014) An efficient approach to mechanically planar chiral rotaxanes.
J Am Chem Soc 136:4817–4820. https://doi.org/10.1021/ja412715m
33. Tachibana Y, Kihara N, Takata T (2004) Asymmetric benzoin condensation catalyzed by chiral
rotaxanes tethering a thiazolium salt moiety via the cooperation of the component: can rotaxane
be an effective reaction field? J Am Chem Soc 126:3438–3439. https://doi.org/10.1021/
ja039461l
34. Vij V, Bhalla V, Kumar M (2016) Hexaarylbenzene: evolution of properties and applications of
multitalented scaffold. Chem Rev 116:9565–9627. https://doi.org/10.1021/acs.chemrev.
6b00144
35. Loxq P, Manoury E, Poli R, Deydier E, Labande A (2016) Synthesis of axially chiral biaryl
compounds by asymmetric catalytic reactions with transition metals. Coord Chem Rev
308:131–190. https://doi.org/10.1016/j.ccr.2015.07.006
36. Kumarasamy E, Ayitou AJ-L, Vallavoju N, Raghunathan R, Iyer A, Clay A, Kandappa SK,
Sivaguru J (2016) Tale of twisted molecules. Atroposelective photoreactions: taming light
induced asymmetric transformations through non-biaryl atropisomers. Acc Chem Res
49:2713–2724. https://doi.org/10.1021/acs.accounts.6b00357
37. Cozzi PG, Emer E, Gualandi A (2011) Atroposelective organocatalysis. Angew Chem Int Ed
50:3847–3849. https://doi.org/10.1002/anie.201008031
38. Durairaj K (1994) Modern concepts and strategies in synthesis of biaryl compounds. Curr Sci
66:833–838
39. Bringmann G, Walter R, Weirich R (1990) Modern strategies for constructing biaryl compounds. Angew Chem 102:1006–1019
172
T. Mori