Table 15.2
(continued)
Number of
phthalates
detected
Sample treatment method
Sample matrix
Separation and detection
method
Method performance
References
Column: C18
(15 cm
 4.6 mm, 5μm)
3
Solid-phase extraction
River, lake, and
ground water
Gas chromatography–mass
spectrometry;
Column: HP-5MS
(30 m
 0.25 mm, 0.25
μm).
Recovery:89.5–112.3%;
LOD:0.5-1 ng/L;
RSD;4.8–7.5%
Wang et al.
(2019b)
5
Solid-phase microextraction
Tap water, pond
water, and barreled
drinking water
Gas chromatography–mass
spectrometry;
Column: HP-5 MS
(30 m
 0.25 mm, 0.5μm)
Recovery:73.4–103.8%;
LODs:0.0012–0.018μg/L;
RSDs:5.8–9.21%
Song et al. (2016)
7
Stir bar sorptive extraction with liquid desorption
Tap and bottled
mineral water
Gas chromatography–mass
spectrometry;
Column:TRB-5MS
(30 m
 0.25 mm, 0.25
μm)
Recovery:5.1–98.5%;
LODs:3–40μg/L;
RSDs:<14.8%
Serodio and
Nogueira (2006)
4
Head-space solid-phase
microextraction
Drinking water
Gas chromatography-flame
ionization detection;
Column: CP-Sil 8 CB
(30 m
 0.32 mm, 0.25
μm).
Recovery:91–105%;
LODs:0.06–0.08μg/L
RSDs:6.1–7.8%
Amanzadeh et al.
(2016)
5
Magnetic solid-phase extraction
River water, tap
water, and bottled
mineral water
High-performance liquid
chromatography-diode array
detection;
Column: C8
(150mm
 4.6 mm, 5μm)
Recovery:85.6–103.6%;
LOD:0.09–0.24μg/L;
RSD:2.1–5.5%
Liu et al. (2015b)
560
C. Sun et al.