Fenton oxidation of organic pollutants. The incorporation of iron into clays through
pillaring and impregnation improved the catalytic properties of clay. Volcanic soils
formed due to volcanic action dominated by amorphous aluminium silicates and/or
Al organic matters are also found effective heterogeneous Fenton catalyst. These
catalysts were highly stable and exhibited less leaching and higher reuse potentials.
Considering the catalytic properties and lower cost of soils, more research should be
focused to improve the catalytic performance and post-recovery of catalysts.
Research should also focus on increasing the surface area of the catalyst.
References
Amritha AS, Manu B (2018) Degradation of nitroaromatic compounds: a novel approach using iron
from laterite soil. Appl Water Sci 8:1–4. https://doi.org/10.1007/s13201-018-0778-7
Aravena S, Pizarro C, Rubio MA, Cavalcante LCD, Garg VK, Pereira MC, Fabris JD (2010)
Magnetic minerals from volcanic Ultisols as heterogeneous Fenton catalysts. Hyperfine Interact
195:35–41. https://doi.org/10.1007/s10751-009-0098-2
Ayodele OB (2013) Effect of phosphoric acid treatment on kaolinite supported ferrioxalate catalyst
for the degradation of amoxicillin in batch photo-Fenton process. Appl Clay Sci 72:74–83.
https://doi.org/10.1016/j.clay.2013.01.004
Ayodele OB, Hameed BH (2013) Development of kaolinite supported ferric oxalate heterogeneous
catalyst for degradation of 4-nitrophenol in photo-Fenton process. Appl Clay Sci
83–84:171–181. https://doi.org/10.1016/j.clay.2013.08.019
Ayodele OB, Lim JK, Hameed BH (2012) Pillared montmorillonite supported ferric oxalate as
heterogeneous photo-Fenton catalyst for degradation of amoxicillin. Appl Catal A Gen
413–414:301–309. https://doi.org/10.1016/j.apcata.2011.11.023
Baiju A, Gandhimathi R, Ramesh ST, Nidheesh PV (2018) Combined heterogeneous electroFenton and biological process for the treatment of stabilized landfill leachate. J Environ
Manag 210:328–337. https://doi.org/10.1016/j.jenvman.2018.01.019
Bansal P, Verma A (2017) Synergistic effect of dual process (photocatalysis and photo-Fenton) for
the degradation of cephalexin using TiO2 immobilized novel clay beads with waste fly
ash/foundry sand. J Photochem Photobiol A Chem 342:131–142. https://doi.org/10.1016/j.
jphotochem.2017.04.010
Barabaszová KČ, Valášková M (2013) Characterization of vermiculite particles after different
milling techniques. Powder Technol 239:277–283. https://doi.org/10.1016/j.powtec.2013.01.
053
Barreca S, Colmenares JJV, Pace A, Orecchio S, Pulgarin C (2014) Neutral solar photo-Fenton
degradation of 4-nitrophenol on iron-enriched hybrid montmorillonite-alginate beads
(Fe-MABs). J Photochem Photobiol A Chem 282:33–40. https://doi.org/10.1016/j.
jphotochem.2014.02.008
Bel Hadjltaief H, Da Costa P, Beaunier P, Gálvez ME, Ben Zina M (2014) Fe-clay-plate as a
heterogeneous catalyst in photo-Fenton oxidation of phenol as probe molecule for water
treatment. Appl Clay Sci 91–92:46–54. https://doi.org/10.1016/j.clay.2014.01.020
Brillas E, Sirés I, Oturan MA (2009) Electro-Fenton process and related electrochemical technologies based on Fenton’s reaction chemistry. Chem Rev 109:6570–6631. https://doi.org/10.
1021/cr900136g
Cetinkaya S, Morcali H, Akarsu S, Ziba C, Dolaz M (2018) Comparison of classic Fenton with
ultrasound Fenton processes on industrial textile wastewater. Sustain Environ Res J
28:165–170. https://doi.org/10.1016/j.serj.2018.02.001
532
A. V. Karim et al.
pillaring and impregnation improved the catalytic properties of clay. Volcanic soils
formed due to volcanic action dominated by amorphous aluminium silicates and/or
Al organic matters are also found effective heterogeneous Fenton catalyst. These
catalysts were highly stable and exhibited less leaching and higher reuse potentials.
Considering the catalytic properties and lower cost of soils, more research should be
focused to improve the catalytic performance and post-recovery of catalysts.
Research should also focus on increasing the surface area of the catalyst.
References
Amritha AS, Manu B (2018) Degradation of nitroaromatic compounds: a novel approach using iron
from laterite soil. Appl Water Sci 8:1–4. https://doi.org/10.1007/s13201-018-0778-7
Aravena S, Pizarro C, Rubio MA, Cavalcante LCD, Garg VK, Pereira MC, Fabris JD (2010)
Magnetic minerals from volcanic Ultisols as heterogeneous Fenton catalysts. Hyperfine Interact
195:35–41. https://doi.org/10.1007/s10751-009-0098-2
Ayodele OB (2013) Effect of phosphoric acid treatment on kaolinite supported ferrioxalate catalyst
for the degradation of amoxicillin in batch photo-Fenton process. Appl Clay Sci 72:74–83.
https://doi.org/10.1016/j.clay.2013.01.004
Ayodele OB, Hameed BH (2013) Development of kaolinite supported ferric oxalate heterogeneous
catalyst for degradation of 4-nitrophenol in photo-Fenton process. Appl Clay Sci
83–84:171–181. https://doi.org/10.1016/j.clay.2013.08.019
Ayodele OB, Lim JK, Hameed BH (2012) Pillared montmorillonite supported ferric oxalate as
heterogeneous photo-Fenton catalyst for degradation of amoxicillin. Appl Catal A Gen
413–414:301–309. https://doi.org/10.1016/j.apcata.2011.11.023
Baiju A, Gandhimathi R, Ramesh ST, Nidheesh PV (2018) Combined heterogeneous electroFenton and biological process for the treatment of stabilized landfill leachate. J Environ
Manag 210:328–337. https://doi.org/10.1016/j.jenvman.2018.01.019
Bansal P, Verma A (2017) Synergistic effect of dual process (photocatalysis and photo-Fenton) for
the degradation of cephalexin using TiO2 immobilized novel clay beads with waste fly
ash/foundry sand. J Photochem Photobiol A Chem 342:131–142. https://doi.org/10.1016/j.
jphotochem.2017.04.010
Barabaszová KČ, Valášková M (2013) Characterization of vermiculite particles after different
milling techniques. Powder Technol 239:277–283. https://doi.org/10.1016/j.powtec.2013.01.
053
Barreca S, Colmenares JJV, Pace A, Orecchio S, Pulgarin C (2014) Neutral solar photo-Fenton
degradation of 4-nitrophenol on iron-enriched hybrid montmorillonite-alginate beads
(Fe-MABs). J Photochem Photobiol A Chem 282:33–40. https://doi.org/10.1016/j.
jphotochem.2014.02.008
Bel Hadjltaief H, Da Costa P, Beaunier P, Gálvez ME, Ben Zina M (2014) Fe-clay-plate as a
heterogeneous catalyst in photo-Fenton oxidation of phenol as probe molecule for water
treatment. Appl Clay Sci 91–92:46–54. https://doi.org/10.1016/j.clay.2014.01.020
Brillas E, Sirés I, Oturan MA (2009) Electro-Fenton process and related electrochemical technologies based on Fenton’s reaction chemistry. Chem Rev 109:6570–6631. https://doi.org/10.
1021/cr900136g
Cetinkaya S, Morcali H, Akarsu S, Ziba C, Dolaz M (2018) Comparison of classic Fenton with
ultrasound Fenton processes on industrial textile wastewater. Sustain Environ Res J
28:165–170. https://doi.org/10.1016/j.serj.2018.02.001
532
A. V. Karim et al.