6
ment at Urban Electric Power corporation as of 2020. EMD can theoretically cycle up
to 0.7 electrons per Mn [19] if the MnOOH material can reversibly intercalate H
+
into
EMD’s mixture of pyrolusite and ramsdellite crystals, as shown in Fig. 3. The effect
of depth of zinc discharge in MnO 2 -zinc batteries on the overall cycle life is shown in
Fig. 4. A separate study by [28] cycled EMD Mn-Zn cells at 0.1 electron per Mn and
Fig. 3 A conceptual picture of the Mn rechargeable battery system, which is stable cycling 0.0 to
0.79 electrons per MnO 2 , or can achieves 2.0 electrons per Mn when the Cu-Bi-birnessite system
of Yadav et al. [14, 15] is employed
Fig. 4 Cycle life as a function of zinc depth-of-discharge for shallow-cycled manganese-zinc
batteries. A “S1” cell is a ~ 1 L Mn-Zn cell from Urban Electric Power. The red and gray asterisks
are outlier experiments that failed due to anomalous events
D. E. Turney et al.
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