178
8 Hetero-Coordinated Interfaces
25. E. Roduner, Size matters: why nanomaterials are different. Chem. Soc. Rev. 35(7), 583–592
(2006)
26. B. Hammer, J.K. Norskov, Why gold is the noblest of all the metals. Nature 376(6537), 238–240
(1995)
27. N. Matensson, R. Nyholm, H. Cale, J. Hedman, B. Johansson, Electron-spectroscopic studies
of the CuxPd1-x alloy system: chemical-shift effects and valence-electron spectra. Phys. Rev.
B 24(4), 1725 (1981)
28. A. Rochefort, M. Abon, P. Delichere, J.C. Bertolini, Alloying effect on the adsorption properties
of Pd50Cu50{111} single crystal surface. Surf. Sci. 294(1–2), 43–52 (1993)
29. T.D. Pope, K. Griffiths, P.R. Norton, Surface and interfacial alloys of Pd with Cu(100): structure,
photoemission and CO chemisorption. Surf. Sci. 306(3), 294–312 (1994)
30. C.J. Barnes, M. Gleeson, S. Sahrakorpi, M. Lindroos, Electronic structure of strained copper
overlayers on Pd(110). Surf. Sci. 447(1–3), 165–179 (2000)
31. S.K. Sengar, B. Mehta, Size and alloying induced changes in lattice constant, core, and
valance band binding energy in Pd-Ag, Pd, and Ag nanoparticles: effect of in-flight sintering
temperature. J. Appl. Phys. 112(1), 014307 (2012)
32. A. Wiltner, C. Linsmeier, Surface alloying of thin beryllium films on tungsten. New J. Phys.
8, 181 (2006)
33. C.Q. Sun, Y. Wang, Y.G. Nie, B.R. Mehta, M. Khanuja, S.M. Shivaprasad, Y. Sun, J.S. Pan,
L.K. Pan, Z. Sun, Interface quantum trap depression and charge polarization in the CuPd and
AgPd bimetallic alloy catalysts. Phys. Chem. Chem. Phys. 12(13), 3131–3135 (2010)
34. Z.S. Ma, Y. Wang, Y.L. Huang, Z.F. Zhou, Y.C. Zhou, W.T. Zheng, C.Q. Sun, XPS quantification
of the hetero-junction interface energy. Appl. Surf. Sci. 265, 71–77 (2013)
35. C.Q. Sun, Oxidation electronics: bond-band-barrier correlation and its applications. Prog. Mater
Sci. 48(6), 521–685 (2003)
36. W.T. Zheng, C.Q. Sun, Electronic process of nitriding: mechanism and applications. Prog.
Solid State Chem. 34(1), 1–20 (2006)
37. G.A. Slack, S.F. Bartram, Thermal expansion of some diamondlike crystals. J. Appl. Phys.
46(1), 89–98 (1975)
38. X.D. Pu, J. Chen, W.Z. Shen, H. Ogawa, Q.X. Guo, Temperature dependence of Raman
scattering in hexagonal indium nitride films. J. Appl. Phys. 98(3), 2006208 (2005)
39. H.B. Du, A. De Sarkar, H.S. Li, Q. Sun, Y. Jia, R.Q. Zhang, Size dependent catalytic effect of
TiO 2 clusters in water dissociation. J. Mol. Catal. A-Chem. 366, 163–170 (2013)
40. C.Q. Sun, Dominance of broken bonds and nonbonding electrons at the nanoscale. Nanoscale
2(10), 1930–1961 (2010)
41. I. Coulthard, T.K. Sham, Charge redistribution in Pd-Ag alloys from a local perspective. Phys.
Rev. Lett. 77(23), 4824–4827 (1996)
42. J.A. Lipton-Duffin, J.M. Macleod, M. Vondracek, K.C. Prince, R. Rosei, F. Rosei, Thermal
evolution of the submonolayer near-surface alloy of ZnPd on Pd(111). Phys. Chem. Chem.
Phys. 16, 4764–4770 (2014)
43. L. Schriver-Mazzuoli, A. Schriver, A. Hallou, IR reflection-absorption spectra of thin water
ice films between 10 and 160 K at low pressure. J. Mol. Struct. 554(2–3), 289–300 (2000)
44. Y. Nie, Y. Wang, Y. Sun, J.S. Pan, B.R. Mehta, M. Khanuja, S.M. Shivaprasad, C.Q. Sun, CuPd
interface charge and energy quantum entrapment: a tight-binding and XPS investigation. Appl.
Surf. Sci. 257(3), 727–730 (2010)
45. C.L. Lee, Y.C. Huang, L.C. Kuo, High catalytic potential of Ag/Pd nanoparticles from selfregulated reduction method on electroless Ni deposition. Electrochem. Commun. 8(6), 1021–
1026 (2006)
46. R.J. Cole, N.J. Brooks, P. Weightman, S.M. Francis, M. Bowker, The physical and electronic
structure of the Cu85Pd15(110) surface; Clues from the study of bulk CuxPd1-x alloys. Surf.
Rev. Lett. 3(5–6), 1763–1772 (1996)
47. Y. Wang, Y.G. Nie, L.K. Pan, Z. Sun, C.Q. Sun, Potential barrier generation at the BeW interface
blocking thermonuclear radiation. Appl. Surf. Sci. 257(8), 3603–3606 (2011)
8 Hetero-Coordinated Interfaces
25. E. Roduner, Size matters: why nanomaterials are different. Chem. Soc. Rev. 35(7), 583–592
(2006)
26. B. Hammer, J.K. Norskov, Why gold is the noblest of all the metals. Nature 376(6537), 238–240
(1995)
27. N. Matensson, R. Nyholm, H. Cale, J. Hedman, B. Johansson, Electron-spectroscopic studies
of the CuxPd1-x alloy system: chemical-shift effects and valence-electron spectra. Phys. Rev.
B 24(4), 1725 (1981)
28. A. Rochefort, M. Abon, P. Delichere, J.C. Bertolini, Alloying effect on the adsorption properties
of Pd50Cu50{111} single crystal surface. Surf. Sci. 294(1–2), 43–52 (1993)
29. T.D. Pope, K. Griffiths, P.R. Norton, Surface and interfacial alloys of Pd with Cu(100): structure,
photoemission and CO chemisorption. Surf. Sci. 306(3), 294–312 (1994)
30. C.J. Barnes, M. Gleeson, S. Sahrakorpi, M. Lindroos, Electronic structure of strained copper
overlayers on Pd(110). Surf. Sci. 447(1–3), 165–179 (2000)
31. S.K. Sengar, B. Mehta, Size and alloying induced changes in lattice constant, core, and
valance band binding energy in Pd-Ag, Pd, and Ag nanoparticles: effect of in-flight sintering
temperature. J. Appl. Phys. 112(1), 014307 (2012)
32. A. Wiltner, C. Linsmeier, Surface alloying of thin beryllium films on tungsten. New J. Phys.
8, 181 (2006)
33. C.Q. Sun, Y. Wang, Y.G. Nie, B.R. Mehta, M. Khanuja, S.M. Shivaprasad, Y. Sun, J.S. Pan,
L.K. Pan, Z. Sun, Interface quantum trap depression and charge polarization in the CuPd and
AgPd bimetallic alloy catalysts. Phys. Chem. Chem. Phys. 12(13), 3131–3135 (2010)
34. Z.S. Ma, Y. Wang, Y.L. Huang, Z.F. Zhou, Y.C. Zhou, W.T. Zheng, C.Q. Sun, XPS quantification
of the hetero-junction interface energy. Appl. Surf. Sci. 265, 71–77 (2013)
35. C.Q. Sun, Oxidation electronics: bond-band-barrier correlation and its applications. Prog. Mater
Sci. 48(6), 521–685 (2003)
36. W.T. Zheng, C.Q. Sun, Electronic process of nitriding: mechanism and applications. Prog.
Solid State Chem. 34(1), 1–20 (2006)
37. G.A. Slack, S.F. Bartram, Thermal expansion of some diamondlike crystals. J. Appl. Phys.
46(1), 89–98 (1975)
38. X.D. Pu, J. Chen, W.Z. Shen, H. Ogawa, Q.X. Guo, Temperature dependence of Raman
scattering in hexagonal indium nitride films. J. Appl. Phys. 98(3), 2006208 (2005)
39. H.B. Du, A. De Sarkar, H.S. Li, Q. Sun, Y. Jia, R.Q. Zhang, Size dependent catalytic effect of
TiO 2 clusters in water dissociation. J. Mol. Catal. A-Chem. 366, 163–170 (2013)
40. C.Q. Sun, Dominance of broken bonds and nonbonding electrons at the nanoscale. Nanoscale
2(10), 1930–1961 (2010)
41. I. Coulthard, T.K. Sham, Charge redistribution in Pd-Ag alloys from a local perspective. Phys.
Rev. Lett. 77(23), 4824–4827 (1996)
42. J.A. Lipton-Duffin, J.M. Macleod, M. Vondracek, K.C. Prince, R. Rosei, F. Rosei, Thermal
evolution of the submonolayer near-surface alloy of ZnPd on Pd(111). Phys. Chem. Chem.
Phys. 16, 4764–4770 (2014)
43. L. Schriver-Mazzuoli, A. Schriver, A. Hallou, IR reflection-absorption spectra of thin water
ice films between 10 and 160 K at low pressure. J. Mol. Struct. 554(2–3), 289–300 (2000)
44. Y. Nie, Y. Wang, Y. Sun, J.S. Pan, B.R. Mehta, M. Khanuja, S.M. Shivaprasad, C.Q. Sun, CuPd
interface charge and energy quantum entrapment: a tight-binding and XPS investigation. Appl.
Surf. Sci. 257(3), 727–730 (2010)
45. C.L. Lee, Y.C. Huang, L.C. Kuo, High catalytic potential of Ag/Pd nanoparticles from selfregulated reduction method on electroless Ni deposition. Electrochem. Commun. 8(6), 1021–
1026 (2006)
46. R.J. Cole, N.J. Brooks, P. Weightman, S.M. Francis, M. Bowker, The physical and electronic
structure of the Cu85Pd15(110) surface; Clues from the study of bulk CuxPd1-x alloys. Surf.
Rev. Lett. 3(5–6), 1763–1772 (1996)
47. Y. Wang, Y.G. Nie, L.K. Pan, Z. Sun, C.Q. Sun, Potential barrier generation at the BeW interface
blocking thermonuclear radiation. Appl. Surf. Sci. 257(8), 3603–3606 (2011)