78
2 Biphenyl Moiety for a Solvent Responsive Aryl Gold(I) …
Fig. 2.45 Frontier molecular orbitals and corresponding energy levels obtained by TD-DFT calculations of the tetramers derived from the single-crystal structures of 3/CHCl 3 , 3/CH 2 Cl 2 , and
3/acetone (B3LYP/SDD)
References
1. Yan X, Wang F, Zheng B, Huang F (2012) Stimuli-responsive supramolecular polymeric
materials. Chem Soc Rev 41:6042–6065
2. (a) Shimizu M, Hiyama T (2010) Organic fluorophores exhibiting highly efficient photoluminescence in the solid state. Chem Asi J 5:1516–1531. (b) Gierschner J, Park SY (2013)
Luminescent distyrylbenzenes: tailoring molecular structure and crystalline morphology. J
Mater Chem C 1:5818–5832. (c) Varughese S (2014) Non-covalent routes to tune the optical properties of molecular materials. J Mater Chem C 2:3499–3516. (d) Yan D, Evans DG
(2014) Molecular crystalline materials with tunable luminescent properties: from polymorphs
to multi-component solids. Mater Horiz 1:46–57
3. (a) Wadas TJ, Wang QM, Kim YJ, Flaschenreim C, Blanton TN, Eisenberg R (2004) Vapochromism and its structural basis in a luminescent Pt(II) terpyridine–nicotinamide complex. J
Am Chem Soc 126:16841–16849. (b) Grove LJ, Rennekamp JM, Jude H, Connick WB (2004)
A new class of platinum(II) vapochromic salts. J Am Chem Soc 126:1594–1595. (d) Malwitz
MA, Lim SH, White–Morris RL, Pham DM, Olmstead MM, Balch AL (2012) Crystallization
and interconversions of vapor-sensitive, luminescent polymorphs of [(C 6 H 11 NC) 2 AuI](AsF 6 )
and [(C 6 H 11 NC) 2 AuI](PF 6 ). J Am Chem Soc 134:10885–10893. (f) Koshevoy IO, Chang
YC, Karttunen AJ, Haukka M, Pakkanen T, Chou PT (2012) Modulation of metallophilic
bonds: solvent-induced isomerization and luminescence vapochromism of a polymorphic Au–
Cu cluster. J Am Chem Soc 134:6564–6567. (g) Kobayashi A, Komatsu K, Ohara H, Kamada W,
2 Biphenyl Moiety for a Solvent Responsive Aryl Gold(I) …
Fig. 2.45 Frontier molecular orbitals and corresponding energy levels obtained by TD-DFT calculations of the tetramers derived from the single-crystal structures of 3/CHCl 3 , 3/CH 2 Cl 2 , and
3/acetone (B3LYP/SDD)
References
1. Yan X, Wang F, Zheng B, Huang F (2012) Stimuli-responsive supramolecular polymeric
materials. Chem Soc Rev 41:6042–6065
2. (a) Shimizu M, Hiyama T (2010) Organic fluorophores exhibiting highly efficient photoluminescence in the solid state. Chem Asi J 5:1516–1531. (b) Gierschner J, Park SY (2013)
Luminescent distyrylbenzenes: tailoring molecular structure and crystalline morphology. J
Mater Chem C 1:5818–5832. (c) Varughese S (2014) Non-covalent routes to tune the optical properties of molecular materials. J Mater Chem C 2:3499–3516. (d) Yan D, Evans DG
(2014) Molecular crystalline materials with tunable luminescent properties: from polymorphs
to multi-component solids. Mater Horiz 1:46–57
3. (a) Wadas TJ, Wang QM, Kim YJ, Flaschenreim C, Blanton TN, Eisenberg R (2004) Vapochromism and its structural basis in a luminescent Pt(II) terpyridine–nicotinamide complex. J
Am Chem Soc 126:16841–16849. (b) Grove LJ, Rennekamp JM, Jude H, Connick WB (2004)
A new class of platinum(II) vapochromic salts. J Am Chem Soc 126:1594–1595. (d) Malwitz
MA, Lim SH, White–Morris RL, Pham DM, Olmstead MM, Balch AL (2012) Crystallization
and interconversions of vapor-sensitive, luminescent polymorphs of [(C 6 H 11 NC) 2 AuI](AsF 6 )
and [(C 6 H 11 NC) 2 AuI](PF 6 ). J Am Chem Soc 134:10885–10893. (f) Koshevoy IO, Chang
YC, Karttunen AJ, Haukka M, Pakkanen T, Chou PT (2012) Modulation of metallophilic
bonds: solvent-induced isomerization and luminescence vapochromism of a polymorphic Au–
Cu cluster. J Am Chem Soc 134:6564–6567. (g) Kobayashi A, Komatsu K, Ohara H, Kamada W,