References
13
screening approach for the discovery of mechanochromic gold(I) isocyanide complexes with
crystal-to-crystal phase transitions. J Am Chem Soc 138:6252–6260
7. (a) Ito H, Muromoto M, Kurenuma S, Ishizaka S, Kitamura N, Sato H, Seki T (2013)
Mechanical stimulation and solid seeding trigger single-crystal-to-single-crystal molecular
domino transformations. Nat Commun 4:2009. (b) Seki T, Sakurada K, Ito H Controlling
mechano- and seeding-triggered single-crystal-to-single-crystal phase transition: molecular
domino with a disconnection of aurophilic bonds. Angew Chem Int Ed 52:12828–12832. (c)
Seki T, Sakurada K, Muromoto M, Seki S, Ito H (2016) Detailed investigation of the structural, thermal, and electronic properties of gold isocyanide complexes with mechano-triggered
single-crystal-to-single-crystal phase transitions. Chem–Eur J 22:1968–1978
8. (a) Pyykkö P (2004) Theoretical chemistry of gold. Angew Chem Int Ed 43: 4412–4456. (b)
Katz MJ, Sakai K, Leznoff DB (2008) The use of aurophilic and other metal–metal interactions as crystal engineering design elements to increase structural dimensionality. Chem Soc
Rev 37:1884–1895. (c) Schmidbaur H, Schier A A briefing on aurophilicity. Chem Soc Rev
37:1931–1951. (d) Laguna A (2008) Modern supramolecular gold chemistry. Wiley, Weinheim
9. Roundhill DM, Fackler JP Jr (1999) Optoelectronic properties of inorganic compounds.
Springer Science & Business Media, New York, pp 195–226
10. (a) Yoon S-J, Chung JW, Gierschner J, Kim KS, Choi M-G, Kim D, Park SY (2010) Multistimuli
two-color luminescence switching via different slip-stacking of highly fluorescent molecular
sheets. J Am Chem Soc 132:13675–13683. (b) Harada N, Abe Y, Karasawa S, Koga N (2012)
Polymorphic equilibrium responsive thermal and mechanical stimuli in light-emitting crystals
of N-Methylaminonaphthyridine. Org Lett 14:6282–6285. (c) Yagai S, Okamura S, Nakano
Y, Yamauchi M, Kishikawa K, Karatsu T, Kitamura A, Ueno A, Kuzuhara D, Yamada H,
Seki T, Ito H (2014) Design amphiphilic dipolar π-systems for stimuli-responsive luminescent
materials using metastable states. Nat Commun 5:4013. (d) Seki T, Sakurada K, Ito H (2015)
Mismatched changes of the photoluminescence and crystalline structure of a mechanochromic
gold(I) isocyanide complex. Chem Commun 51:13933–13936
11. (a) Li FF, Zhang L, Gong LL, Yan CS, Gao HY, Luo F (2017) Reversible
photo/thermoswitchable dual-color fluorescence through single-crystal-to-single-crystal transformation. Dalton Trans 46:338–341. (b) Lim SH, Olmstead MM, Balch AL (2013) Inorganic
topochemistry. Vapor-induced solid state transformations of luminescent, three-coordinate
gold(I) complexes. Chem Sci 4:311–318. (c) Zeng M-H, Tan Y-X, He Y-P, Yin Z, Chen
Q, Kurmoo M (2013) A porous 4-fold-interpenetrated chiral framework exhibiting vapochromism, Single-crystal-to-single-crystal solvent exchange, gas sorption, and a poisoning
effect. Inorg Chem 52:2353–2360. (d) Huang R-W, Wei Y-S, Dong X-Y, Wu X-H, Du CX, Zang S-Q, Mak TCW (2017) Hypersensitive dual-function luminescence switching of
a silver-chalcogenolate cluster-based metal–organic framework. Nat Chem 9:689–697. (e)
Lim SH, Olmstead MM, Balch AL (2011) Molecular accordion: vapoluminescence and
molecular flexibility in the orange and green luminescent crystals of the dimer, Au2(μ-bis(diphenylphosphino)ethane) 2 Br 2 . J Am Chem Soc 133:10229–10238. (f) Liu G, Liu J, Liu Y,
Tao X (2014) Oriented single-crystal-to-single-crystal phase transition with dramatic changes
in the dimensions of crystals. J Am Chem Soc 136:590–593. (g) Liu J, Liu G, Liu Y, Zheng
X, Han Q, Ye X, Tao X (2016) The role of weak interactions in the mechano-induced singlecrystal-to-single-crystal phase transition of 8 hydroxyquinoline based co-crystals. Chem Asian
J 11:1682–1687. (h) Karothu DP, Weston J, Desta IT, Naumov P (2016) Shape-memory and
self-healing effects in mechanosalient molecular crystals. J Am Chem Soc 138:13298–13306.
(i) Liu GF, Liu J, Ye X, Nie LN, Gu PY, Tao XT, Zhang QC (2017) Self-healing behavior in a thermo-mechanically responsive cocrystal during a reversible phase transition. Angew
Chem Int Ed 56:198–202. (j) Takamizawa S, Miyamoto Y (2014) Superelastic organic crystals.
Angew Chem Int Ed 53:6970–6973. (k) Takasaki Y, Takamizawa S (2015) Reversible crystal
deformation of a single-crystal host of copper(II) 1-naphthoate-pyrazine through crystal phase
transition induced by methanol vapor sorption. Chem Commun 51:5024–5027. (l) Takamizawa
S, Takasaki Y (2015) Superelastic shape recovery of mechanically twinned 3,5-Difluorobenzoic
13
screening approach for the discovery of mechanochromic gold(I) isocyanide complexes with
crystal-to-crystal phase transitions. J Am Chem Soc 138:6252–6260
7. (a) Ito H, Muromoto M, Kurenuma S, Ishizaka S, Kitamura N, Sato H, Seki T (2013)
Mechanical stimulation and solid seeding trigger single-crystal-to-single-crystal molecular
domino transformations. Nat Commun 4:2009. (b) Seki T, Sakurada K, Ito H Controlling
mechano- and seeding-triggered single-crystal-to-single-crystal phase transition: molecular
domino with a disconnection of aurophilic bonds. Angew Chem Int Ed 52:12828–12832. (c)
Seki T, Sakurada K, Muromoto M, Seki S, Ito H (2016) Detailed investigation of the structural, thermal, and electronic properties of gold isocyanide complexes with mechano-triggered
single-crystal-to-single-crystal phase transitions. Chem–Eur J 22:1968–1978
8. (a) Pyykkö P (2004) Theoretical chemistry of gold. Angew Chem Int Ed 43: 4412–4456. (b)
Katz MJ, Sakai K, Leznoff DB (2008) The use of aurophilic and other metal–metal interactions as crystal engineering design elements to increase structural dimensionality. Chem Soc
Rev 37:1884–1895. (c) Schmidbaur H, Schier A A briefing on aurophilicity. Chem Soc Rev
37:1931–1951. (d) Laguna A (2008) Modern supramolecular gold chemistry. Wiley, Weinheim
9. Roundhill DM, Fackler JP Jr (1999) Optoelectronic properties of inorganic compounds.
Springer Science & Business Media, New York, pp 195–226
10. (a) Yoon S-J, Chung JW, Gierschner J, Kim KS, Choi M-G, Kim D, Park SY (2010) Multistimuli
two-color luminescence switching via different slip-stacking of highly fluorescent molecular
sheets. J Am Chem Soc 132:13675–13683. (b) Harada N, Abe Y, Karasawa S, Koga N (2012)
Polymorphic equilibrium responsive thermal and mechanical stimuli in light-emitting crystals
of N-Methylaminonaphthyridine. Org Lett 14:6282–6285. (c) Yagai S, Okamura S, Nakano
Y, Yamauchi M, Kishikawa K, Karatsu T, Kitamura A, Ueno A, Kuzuhara D, Yamada H,
Seki T, Ito H (2014) Design amphiphilic dipolar π-systems for stimuli-responsive luminescent
materials using metastable states. Nat Commun 5:4013. (d) Seki T, Sakurada K, Ito H (2015)
Mismatched changes of the photoluminescence and crystalline structure of a mechanochromic
gold(I) isocyanide complex. Chem Commun 51:13933–13936
11. (a) Li FF, Zhang L, Gong LL, Yan CS, Gao HY, Luo F (2017) Reversible
photo/thermoswitchable dual-color fluorescence through single-crystal-to-single-crystal transformation. Dalton Trans 46:338–341. (b) Lim SH, Olmstead MM, Balch AL (2013) Inorganic
topochemistry. Vapor-induced solid state transformations of luminescent, three-coordinate
gold(I) complexes. Chem Sci 4:311–318. (c) Zeng M-H, Tan Y-X, He Y-P, Yin Z, Chen
Q, Kurmoo M (2013) A porous 4-fold-interpenetrated chiral framework exhibiting vapochromism, Single-crystal-to-single-crystal solvent exchange, gas sorption, and a poisoning
effect. Inorg Chem 52:2353–2360. (d) Huang R-W, Wei Y-S, Dong X-Y, Wu X-H, Du CX, Zang S-Q, Mak TCW (2017) Hypersensitive dual-function luminescence switching of
a silver-chalcogenolate cluster-based metal–organic framework. Nat Chem 9:689–697. (e)
Lim SH, Olmstead MM, Balch AL (2011) Molecular accordion: vapoluminescence and
molecular flexibility in the orange and green luminescent crystals of the dimer, Au2(μ-bis(diphenylphosphino)ethane) 2 Br 2 . J Am Chem Soc 133:10229–10238. (f) Liu G, Liu J, Liu Y,
Tao X (2014) Oriented single-crystal-to-single-crystal phase transition with dramatic changes
in the dimensions of crystals. J Am Chem Soc 136:590–593. (g) Liu J, Liu G, Liu Y, Zheng
X, Han Q, Ye X, Tao X (2016) The role of weak interactions in the mechano-induced singlecrystal-to-single-crystal phase transition of 8 hydroxyquinoline based co-crystals. Chem Asian
J 11:1682–1687. (h) Karothu DP, Weston J, Desta IT, Naumov P (2016) Shape-memory and
self-healing effects in mechanosalient molecular crystals. J Am Chem Soc 138:13298–13306.
(i) Liu GF, Liu J, Ye X, Nie LN, Gu PY, Tao XT, Zhang QC (2017) Self-healing behavior in a thermo-mechanically responsive cocrystal during a reversible phase transition. Angew
Chem Int Ed 56:198–202. (j) Takamizawa S, Miyamoto Y (2014) Superelastic organic crystals.
Angew Chem Int Ed 53:6970–6973. (k) Takasaki Y, Takamizawa S (2015) Reversible crystal
deformation of a single-crystal host of copper(II) 1-naphthoate-pyrazine through crystal phase
transition induced by methanol vapor sorption. Chem Commun 51:5024–5027. (l) Takamizawa
S, Takasaki Y (2015) Superelastic shape recovery of mechanically twinned 3,5-Difluorobenzoic