50
T. Onishi
2.5.3 AC Impedance Measurement of Hydride Ion Conduction
In general, experimental data, which is obtained by AC impedance measurement,
is analysed under assuming that electric resistance is constant in bulk part. It is
noted that it is generally divided into three contributions: bulk, grain boundary and
electrode interface. However, covalency of hydrogen is changeable during hydride
ion conduction. It implies that electric resistance in solid part also varies. Hence,
this effect must be taken into account. Otherwise, incorrect activation energy will
be given as same as proton conduction [8].
Acknowledgements This work was partially supported by the Research Council of Norway
through its Centres of Excellence scheme, project number 262695.
References
1. Y. Inaguma, J. Ceram. Soc. Jpn. 114, 1103–1110 (2006)
2. M. Yoshino, A. Kozawa, R.J. Brodd, Lithium-Ion Batteries (Springer Nature, 2009), Introduction
3. T. Onishi, Quantum Computational Chemistry (Springer Nature, Singapore, 2018), Chapter 13
4. T. Norby, M. Widerøe, R. Glöcknera, Y. Larringa, Dalton Trans: 3012–3018 (2012)
5. T. Norby, Perovskite Oxide for Solid Oxide Fuel Cell (Springer Nature, Singapore, 2009),
Chapter 11
6. T. Ishihara, Perovskite Oxide for Solid Oxide Fuel Cell (Springer Nature, Singapore, 2009),
Chapter 4
7. T. Onishi, Quantum Computational Chemistry (Springer Nature, Singapore, 2018), Chapter 14
8. T. Onishi, Adv. Quantum Chem. 70, 31–67 (2015)
9. T. Norby, Y. Larring, Solid State Ionics 136–137, 139–148 (2000)
10. S. Steinsvik, Y. Larring, T. Norby, Solid State Ionics 143, 103–116 (2001)
11. M. Widerøe, W. Münch, Y. Larring, T. Norby, Solid State Ionics 154–155, 669–677 (2002)
12. Y. Kobayashi, O.J. Hernandez, T. Sakaguchi, T. Yajima, T. Roisnel, Y. Tsujimoto, M. Morita,
Y. Noda, Y. Mogami, A. Kitada, M. Ohkura, S. Hosokawa, Z. Li, K. Hayashi, Y. Kusano, J.
Kim, N. Tsuji, A. Fujiwara, Y. Matsushita, K. Yoshimura, K. Takegoshi, M. Inoue, M. Takano,
H. Kageyama, Nat. Mater. 11, 507–511 (2012)
13. T. Yajima, F. Takeiri, K. Aidzu, H. Akamatsu, K. Fujita, W. Yoshimune, M. Ohkura, S. Lei,
V. Gopalan, K. Tanaka, C.M. Brown, M.A. Green, T. Yamamoto, Y. Kobayashi, H. Hiroshi
Kageyama, Nat. Chem. 7, 1017–1023 (2015)
14. T. Onishi, in AIP Conference Proceedings 2040: 020002, 2018
15. K. Yvon, B. Bertheville, J. Alloys Compd. 425, 101–108 (2006)
16. K. Klaveness, O. Swang, H. Fjellvåg, Europhys. Lett. 76, 285–290 (2006)
17. A. Bouamrane, C. Brauer, J.P. Soulié, J.M. Létoffeé, J.P. Bastide, Thermochim. Acta 326, 37–
41 (1999)
18. A. Bouamrane, J.P. Laval, J.P. Soulie, J.P. Bastide, Mater. Res. Bull. 35, 545–549 (2000)
19. A.A. Granovsky, Firefly version 8, http://classic.chem.msu.su/gran/firefly/index.html
20. M.W. Schmidt, K.K. Baldridge, J.A. Boatz, S.T. Elbert, M.S. Gordon, J.H. Jensen, S. Koseki,
N. Matsunaga, K.A. Nguyen, S. Su, T.L. Windus, M. Dupuis, J.A. Montgomery, J. Comput.
Chem. 14, 1347–1363 (1993)
21. U. Varetto,; Swiss National Supercomputing Centre. Manno, Switzerland
22. T. Onishi, Adv. Quantum Chem. 64, 31–81 (2012)
T. Onishi
2.5.3 AC Impedance Measurement of Hydride Ion Conduction
In general, experimental data, which is obtained by AC impedance measurement,
is analysed under assuming that electric resistance is constant in bulk part. It is
noted that it is generally divided into three contributions: bulk, grain boundary and
electrode interface. However, covalency of hydrogen is changeable during hydride
ion conduction. It implies that electric resistance in solid part also varies. Hence,
this effect must be taken into account. Otherwise, incorrect activation energy will
be given as same as proton conduction [8].
Acknowledgements This work was partially supported by the Research Council of Norway
through its Centres of Excellence scheme, project number 262695.
References
1. Y. Inaguma, J. Ceram. Soc. Jpn. 114, 1103–1110 (2006)
2. M. Yoshino, A. Kozawa, R.J. Brodd, Lithium-Ion Batteries (Springer Nature, 2009), Introduction
3. T. Onishi, Quantum Computational Chemistry (Springer Nature, Singapore, 2018), Chapter 13
4. T. Norby, M. Widerøe, R. Glöcknera, Y. Larringa, Dalton Trans: 3012–3018 (2012)
5. T. Norby, Perovskite Oxide for Solid Oxide Fuel Cell (Springer Nature, Singapore, 2009),
Chapter 11
6. T. Ishihara, Perovskite Oxide for Solid Oxide Fuel Cell (Springer Nature, Singapore, 2009),
Chapter 4
7. T. Onishi, Quantum Computational Chemistry (Springer Nature, Singapore, 2018), Chapter 14
8. T. Onishi, Adv. Quantum Chem. 70, 31–67 (2015)
9. T. Norby, Y. Larring, Solid State Ionics 136–137, 139–148 (2000)
10. S. Steinsvik, Y. Larring, T. Norby, Solid State Ionics 143, 103–116 (2001)
11. M. Widerøe, W. Münch, Y. Larring, T. Norby, Solid State Ionics 154–155, 669–677 (2002)
12. Y. Kobayashi, O.J. Hernandez, T. Sakaguchi, T. Yajima, T. Roisnel, Y. Tsujimoto, M. Morita,
Y. Noda, Y. Mogami, A. Kitada, M. Ohkura, S. Hosokawa, Z. Li, K. Hayashi, Y. Kusano, J.
Kim, N. Tsuji, A. Fujiwara, Y. Matsushita, K. Yoshimura, K. Takegoshi, M. Inoue, M. Takano,
H. Kageyama, Nat. Mater. 11, 507–511 (2012)
13. T. Yajima, F. Takeiri, K. Aidzu, H. Akamatsu, K. Fujita, W. Yoshimune, M. Ohkura, S. Lei,
V. Gopalan, K. Tanaka, C.M. Brown, M.A. Green, T. Yamamoto, Y. Kobayashi, H. Hiroshi
Kageyama, Nat. Chem. 7, 1017–1023 (2015)
14. T. Onishi, in AIP Conference Proceedings 2040: 020002, 2018
15. K. Yvon, B. Bertheville, J. Alloys Compd. 425, 101–108 (2006)
16. K. Klaveness, O. Swang, H. Fjellvåg, Europhys. Lett. 76, 285–290 (2006)
17. A. Bouamrane, C. Brauer, J.P. Soulié, J.M. Létoffeé, J.P. Bastide, Thermochim. Acta 326, 37–
41 (1999)
18. A. Bouamrane, J.P. Laval, J.P. Soulie, J.P. Bastide, Mater. Res. Bull. 35, 545–549 (2000)
19. A.A. Granovsky, Firefly version 8, http://classic.chem.msu.su/gran/firefly/index.html
20. M.W. Schmidt, K.K. Baldridge, J.A. Boatz, S.T. Elbert, M.S. Gordon, J.H. Jensen, S. Koseki,
N. Matsunaga, K.A. Nguyen, S. Su, T.L. Windus, M. Dupuis, J.A. Montgomery, J. Comput.
Chem. 14, 1347–1363 (1993)
21. U. Varetto,
22. T. Onishi, Adv. Quantum Chem. 64, 31–81 (2012)