8 Electronic Properties of Transition Metal-Benzene Sandwich Clusters
347
74. R. Clérac, H. Miyasaka, M. Yamashita, C. Coulon, Evidence for single-chain magnet behavior
in a Mn III -Ni II chain designed with high spin magnetic units: A route to high temperature
metastable magnets. J. Am. Chem. Soc. 124, 12837–12844 (2002)
75. W.-X. Zhang, R. Ishikawa, B. Breedlove, M. Yamashita, Single-chain magnets: Beyond the
Glauber model. RSC Adv. 3, 3772–3798 (2013)
76. R.H. Baughman, A.A. Zakhidov, W.A. de Heer, Carbon nanotubes—The route toward
applications. Science 297, 787–792 (2002)
77. M.H. Jo, J.E. Grose, K. Baheti, M.M. Deshmukh, J.J. Sokol, E.M. Rumberger, D.N.
Hendrickson, J.R. Long, H. Park, D.C. Ralph, Signatures of molecular magnetism in singlemolecule transport spectroscopy. Nano Lett. 6, 2014–2020 (2006)
78. L. Bogani, W. Wernsdorfer, Molecular spintronics using single-molecule magnets. Nat. Mater.
7, 179–186 (2008)
79. L. Ma, A.H.C. Hart, S. Ozden, R. Vajtaia, P.M. Ajayan, Spiers memorial lecture advances of
carbon nanomaterials. Faraday Discuss. 173, 9–46 (2014)
80. S.N. Khanna, P. Jena, Assembling crystals from clusters. Phys. Rev. Lett. 69, 1664–1667
(1993)
81. S.A. Claridge, A.W. Castleman Jr., S.N. Khanna, C.B. Murray, A. Sen, P.S. Weiss, Clusterassembled materials. ACS Nano 3, 244–255 (2009)
82. P. Gambardella, S. Rusponi, M. Veronese, S.S. Dhesi, C. Grazioli, A. Dallmeyer, I. Cabria, R.
Zeller, P.H. Dederichs, K. Kern, C. Carbone, H. Brune, Giant magnetic anisotropy of single
cobalt atoms and nanoparticles. Science 300, 1130–1133 (2003)
83. R. Pandey, B.K. Rao, P. Jena, J.M. Newsam, Unique magnetic signature of transition metal
atoms supported on benzene. Chem. Phys. Lett. 321, 142–150 (2000)
84. R. Pandey, B.K. Rao, P. Jena, M.A. Blanco, Electronic structure and properties of transition
metal-benzene complexes. J. Am. Chem. Soc. 123, 3799–3808 (2001)
85. C. Elschenbroich, E. Schmidt, R. Gondrum, B. Metz, O. Burghaus, W. Massa, S.
Wocadlo, Metal π complexes of benzene derivatives. Germanium in the periphery of
Bis(benzene)vanadium and Bis(benzene)chromium. Synthesis and structure of new heterametallocyclophanes. Organometallics 16, 4589–4596 (1997)
86. J.M. Frost, K.L.M. Harriman, M. Murugesu, The rise of 3-d single-ion magnets in molecular
magnetism: Towards materials from molecules? Chem. Sci. 7, 2470–2491 (2016)
87. W. Gerlach, O. Stern, Das magnetische Moment des Silberatoms. Z. Phys. A 9, 353–355
(1922)
88. K. Miyajima, A. Nakajima, S. Yabushita, M.B. Knickelbein, K. Kaya, Ferromagnetism in
one-dimensional vanadium-benzene sandwich clusters. J. Am. Chem. Soc. 126, 13202–13203
(2004)
89. K. Miyajima, M.B. Knickelbein, A. Nakajima, Stern-Gerlach studies of organometallic
sandwich clusters. Eur. Phys. J. D. 34, 177–182 (2005)
90. K. Miyajima, S. Yabushita, M.B. Knickelbein, A. Nakajima, Stern-Gerlach experiments of
one-dimensional metal-benzene sandwich clusters: M n (C 6 H 6 ) m (M = Al, Sc, Ti, and V). J.
Am. Chem. Soc. 129, 8473–8480 (2007)
91. M.B. Knickelbein, Magnetic moments of bare and benzene-capped cobalt clusters. J. Chem.
Phys. 125, 044308-1–044308-7 (2006)
92. A.K. Kandalam, B.K. Rao, P. Jena, R. Pandey, Geometry and electronic structure of V n (Bz) m
complexes. J. Chem. Phys. 120, 10414–10422 (2004)
93. J. Wang, P.H. Acioli, J. Jellinek, Structure and magnetism of V n Bz n+1 sandwich clusters. J.
Am. Chem. Soc. 127, 2812–2813 (2005)
94. X. Zhang, J. Wang, Structural, electronic, and magnetic properties of Co n (benzene) m
complexes. J. Phys. Chem. A 112, 296–304 (2008)
95. M.M. Rahman, H. Kasai, E.S. Dy, Theoretical investigation of electric and magnetic
properties of benzene–vanadium sandwich complex chain. Jpn. J. Appl. Phys. 44, 7954–7956
(2005)
96. H. Xiang, J. Yang, J.G. Hou, Q. Zhu, One-dimensional transition metal−benzene sandwich
polymers: Possible ideal conductors for spin transport. J. Am. Chem. Soc. 128, 2310–2314
(2006)
347
74. R. Clérac, H. Miyasaka, M. Yamashita, C. Coulon, Evidence for single-chain magnet behavior
in a Mn III -Ni II chain designed with high spin magnetic units: A route to high temperature
metastable magnets. J. Am. Chem. Soc. 124, 12837–12844 (2002)
75. W.-X. Zhang, R. Ishikawa, B. Breedlove, M. Yamashita, Single-chain magnets: Beyond the
Glauber model. RSC Adv. 3, 3772–3798 (2013)
76. R.H. Baughman, A.A. Zakhidov, W.A. de Heer, Carbon nanotubes—The route toward
applications. Science 297, 787–792 (2002)
77. M.H. Jo, J.E. Grose, K. Baheti, M.M. Deshmukh, J.J. Sokol, E.M. Rumberger, D.N.
Hendrickson, J.R. Long, H. Park, D.C. Ralph, Signatures of molecular magnetism in singlemolecule transport spectroscopy. Nano Lett. 6, 2014–2020 (2006)
78. L. Bogani, W. Wernsdorfer, Molecular spintronics using single-molecule magnets. Nat. Mater.
7, 179–186 (2008)
79. L. Ma, A.H.C. Hart, S. Ozden, R. Vajtaia, P.M. Ajayan, Spiers memorial lecture advances of
carbon nanomaterials. Faraday Discuss. 173, 9–46 (2014)
80. S.N. Khanna, P. Jena, Assembling crystals from clusters. Phys. Rev. Lett. 69, 1664–1667
(1993)
81. S.A. Claridge, A.W. Castleman Jr., S.N. Khanna, C.B. Murray, A. Sen, P.S. Weiss, Clusterassembled materials. ACS Nano 3, 244–255 (2009)
82. P. Gambardella, S. Rusponi, M. Veronese, S.S. Dhesi, C. Grazioli, A. Dallmeyer, I. Cabria, R.
Zeller, P.H. Dederichs, K. Kern, C. Carbone, H. Brune, Giant magnetic anisotropy of single
cobalt atoms and nanoparticles. Science 300, 1130–1133 (2003)
83. R. Pandey, B.K. Rao, P. Jena, J.M. Newsam, Unique magnetic signature of transition metal
atoms supported on benzene. Chem. Phys. Lett. 321, 142–150 (2000)
84. R. Pandey, B.K. Rao, P. Jena, M.A. Blanco, Electronic structure and properties of transition
metal-benzene complexes. J. Am. Chem. Soc. 123, 3799–3808 (2001)
85. C. Elschenbroich, E. Schmidt, R. Gondrum, B. Metz, O. Burghaus, W. Massa, S.
Wocadlo, Metal π complexes of benzene derivatives. Germanium in the periphery of
Bis(benzene)vanadium and Bis(benzene)chromium. Synthesis and structure of new heterametallocyclophanes. Organometallics 16, 4589–4596 (1997)
86. J.M. Frost, K.L.M. Harriman, M. Murugesu, The rise of 3-d single-ion magnets in molecular
magnetism: Towards materials from molecules? Chem. Sci. 7, 2470–2491 (2016)
87. W. Gerlach, O. Stern, Das magnetische Moment des Silberatoms. Z. Phys. A 9, 353–355
(1922)
88. K. Miyajima, A. Nakajima, S. Yabushita, M.B. Knickelbein, K. Kaya, Ferromagnetism in
one-dimensional vanadium-benzene sandwich clusters. J. Am. Chem. Soc. 126, 13202–13203
(2004)
89. K. Miyajima, M.B. Knickelbein, A. Nakajima, Stern-Gerlach studies of organometallic
sandwich clusters. Eur. Phys. J. D. 34, 177–182 (2005)
90. K. Miyajima, S. Yabushita, M.B. Knickelbein, A. Nakajima, Stern-Gerlach experiments of
one-dimensional metal-benzene sandwich clusters: M n (C 6 H 6 ) m (M = Al, Sc, Ti, and V). J.
Am. Chem. Soc. 129, 8473–8480 (2007)
91. M.B. Knickelbein, Magnetic moments of bare and benzene-capped cobalt clusters. J. Chem.
Phys. 125, 044308-1–044308-7 (2006)
92. A.K. Kandalam, B.K. Rao, P. Jena, R. Pandey, Geometry and electronic structure of V n (Bz) m
complexes. J. Chem. Phys. 120, 10414–10422 (2004)
93. J. Wang, P.H. Acioli, J. Jellinek, Structure and magnetism of V n Bz n+1 sandwich clusters. J.
Am. Chem. Soc. 127, 2812–2813 (2005)
94. X. Zhang, J. Wang, Structural, electronic, and magnetic properties of Co n (benzene) m
complexes. J. Phys. Chem. A 112, 296–304 (2008)
95. M.M. Rahman, H. Kasai, E.S. Dy, Theoretical investigation of electric and magnetic
properties of benzene–vanadium sandwich complex chain. Jpn. J. Appl. Phys. 44, 7954–7956
(2005)
96. H. Xiang, J. Yang, J.G. Hou, Q. Zhu, One-dimensional transition metal−benzene sandwich
polymers: Possible ideal conductors for spin transport. J. Am. Chem. Soc. 128, 2310–2314
(2006)