5 Commercial Aspects of Biomass Deconstruction with Ionic Liquids
119
4. Dale BE, Anderson JE, Brown RC, Csonka S, Dale VH, Herwick G, Jackson RD, Jordan N,
Kaffka S, Kline KL, Lynd LR (2014) Take a closer look: biofuels can support environmental, economic and social goals. Environ Sci Technol 48:7200–7203. https://doi.org/10.1021/
es5025433
5. Isikgor FH, Becer CR (2015) Lignocellulosic biomass: a sustainable platform for the production of bio-based chemicals and polymers. Polym Chem 6:4497–4559. https://doi.org/10.
1039/C5PY00263J
6. Mosier N, Wyman C, Dale B, Elander R, Lee YY, Holtzapple M, Ladisch M (2005) Features
of promising technologies for pretreatment of lignocellulosic biomass. Bioresour Technol
96:673–686. https://doi.org/10.1016/j.biortech.2004.06.025
7. Agbor VB, Cicek N, Sparling R, Berlin A, Levin DB (2011) Biomass pretreatment: fundamentals toward application. Biotechnol Adv 29:675–685. https://doi.org/10.1016/j.biotechadv.
2011.05.005
8. Kumar AK, Sharma S (2017) Recent updates on different methods of pretreatment of lignocellulosic feedstocks: a review. Bioresour Bioprocess 4:7. https://doi.org/10.1186/s40643017-0137-9
9. Alvira P, Tomás-Pejó E, Ballesteros M, Negro MJ (2010) Pretreatment technologies for an
efficient bioethanol production process based on enzymatic hydrolysis: a review. Bioresour
Technol 101:4851–4861. https://doi.org/10.1016/j.biortech.2009.11.093
10. Albers SC, Berklund AM, Graff GD (2016) The rise and fall of innovation in biofuels. Nat
Biotechnol 34:814–821. https://doi.org/10.1038/nbt.3644
11. Oliveira FM, Pinheiro IO, Souto-Maior AM, Martin C, Gonçalves AR, Rocha GJ (2013)
Industrial-scale steam explosion pretreatment of sugarcane straw for enzymatic hydrolysis of
cellulose for production of second generation ethanol and value-added products. Bioresour
Technol 130:168–173. https://doi.org/10.1016/j.biortech.2012.12.030
12. Bals B, Rogers C, Jin M, Balan V, Dale B (2010) Evaluation of ammonia fibre expansion
(AFEX) pretreatment for enzymatic hydrolysis of switchgrass harvested in different seasons
and locations. Biotechnol Biofuels 3:1. https://doi.org/10.1186/1754-6834-3-1
13. Saha BC, Iten LB, Cotta MA, Wu YV (2005) Dilute acid pretreatment, enzymatic saccharification and fermentation of wheat straw to ethanol. Process Biochem 40:3693–3700. https://
doi.org/10.1016/j.procbio.2005.04.006
14. Zhuang X, Wang W, Yu Q, Qi W, Wang Q, Tan X, Zhou G, Yuan Z (2016) Liquid hot water pretreatment of lignocellulosic biomass for bioethanol production accompanying with high valuable products. Bioresour Technol 199:68–75. https://doi.org/10.1016/j.biortech.2015.08.051
15. Zhao X, Cheng K, Liu D (2009) Organosolv pretreatment of lignocellulosic biomass for enzymatic hydrolysis. Appl Microbiol Biotechnol 82:815–827. https://doi.org/10.1007/s00253009-1883-1
16. Fort DA, Remsing RC, Swatloski RP, Moyna P, Moyna G, Rogers RD (2007) Can ionic
liquids dissolve wood? Processing and analysis of lignocellulosic materials with 1-n-butyl-3methylimidazolium chloride. Green Chem 9:63–69. https://doi.org/10.1039/B607614A
17. An Y-X, Zong M-H, Wu H, Li N (2015) Pretreatment of lignocellulosic biomass with renewable cholinium ionic liquids: Biomass fractionation, enzymatic digestion and ionic liquid
reuse. Bioresour Technol 192:165–171. https://doi.org/10.1016/j.biortech.2015.05.064
18. Hu S, Zhang Z, Zhou Y, Han B, Fan H, Li W, Song J, Xie Y (2008) Conversion of fructose to
5-hydroxymethylfurfural using ionic liquids prepared from renewable materials. Green Chem
10:1280–1283. https://doi.org/10.1039/b810392e
19. Rogers RD, Seddon KR (2003) Ionic liquids–solvents of the future? Science 302:792–793.
https://doi.org/10.1126/science.1090313
20. Plechkova NV, Seddon KR (2008) Applications of ionic liquids in the chemical industry.
Chem Soc Rev 37:123–150. https://doi.org/10.1039/B006677J
21. García-Verdugo E, Altava B, Burguete MI, Lozano P, Luis SV (2015) Ionic liquids and
continuous flow processes: a good marriage to design sustainable processes. Green Chem
17:2693–2713. https://doi.org/10.1039/C4GC02388A
119
4. Dale BE, Anderson JE, Brown RC, Csonka S, Dale VH, Herwick G, Jackson RD, Jordan N,
Kaffka S, Kline KL, Lynd LR (2014) Take a closer look: biofuels can support environmental, economic and social goals. Environ Sci Technol 48:7200–7203. https://doi.org/10.1021/
es5025433
5. Isikgor FH, Becer CR (2015) Lignocellulosic biomass: a sustainable platform for the production of bio-based chemicals and polymers. Polym Chem 6:4497–4559. https://doi.org/10.
1039/C5PY00263J
6. Mosier N, Wyman C, Dale B, Elander R, Lee YY, Holtzapple M, Ladisch M (2005) Features
of promising technologies for pretreatment of lignocellulosic biomass. Bioresour Technol
96:673–686. https://doi.org/10.1016/j.biortech.2004.06.025
7. Agbor VB, Cicek N, Sparling R, Berlin A, Levin DB (2011) Biomass pretreatment: fundamentals toward application. Biotechnol Adv 29:675–685. https://doi.org/10.1016/j.biotechadv.
2011.05.005
8. Kumar AK, Sharma S (2017) Recent updates on different methods of pretreatment of lignocellulosic feedstocks: a review. Bioresour Bioprocess 4:7. https://doi.org/10.1186/s40643017-0137-9
9. Alvira P, Tomás-Pejó E, Ballesteros M, Negro MJ (2010) Pretreatment technologies for an
efficient bioethanol production process based on enzymatic hydrolysis: a review. Bioresour
Technol 101:4851–4861. https://doi.org/10.1016/j.biortech.2009.11.093
10. Albers SC, Berklund AM, Graff GD (2016) The rise and fall of innovation in biofuels. Nat
Biotechnol 34:814–821. https://doi.org/10.1038/nbt.3644
11. Oliveira FM, Pinheiro IO, Souto-Maior AM, Martin C, Gonçalves AR, Rocha GJ (2013)
Industrial-scale steam explosion pretreatment of sugarcane straw for enzymatic hydrolysis of
cellulose for production of second generation ethanol and value-added products. Bioresour
Technol 130:168–173. https://doi.org/10.1016/j.biortech.2012.12.030
12. Bals B, Rogers C, Jin M, Balan V, Dale B (2010) Evaluation of ammonia fibre expansion
(AFEX) pretreatment for enzymatic hydrolysis of switchgrass harvested in different seasons
and locations. Biotechnol Biofuels 3:1. https://doi.org/10.1186/1754-6834-3-1
13. Saha BC, Iten LB, Cotta MA, Wu YV (2005) Dilute acid pretreatment, enzymatic saccharification and fermentation of wheat straw to ethanol. Process Biochem 40:3693–3700. https://
doi.org/10.1016/j.procbio.2005.04.006
14. Zhuang X, Wang W, Yu Q, Qi W, Wang Q, Tan X, Zhou G, Yuan Z (2016) Liquid hot water pretreatment of lignocellulosic biomass for bioethanol production accompanying with high valuable products. Bioresour Technol 199:68–75. https://doi.org/10.1016/j.biortech.2015.08.051
15. Zhao X, Cheng K, Liu D (2009) Organosolv pretreatment of lignocellulosic biomass for enzymatic hydrolysis. Appl Microbiol Biotechnol 82:815–827. https://doi.org/10.1007/s00253009-1883-1
16. Fort DA, Remsing RC, Swatloski RP, Moyna P, Moyna G, Rogers RD (2007) Can ionic
liquids dissolve wood? Processing and analysis of lignocellulosic materials with 1-n-butyl-3methylimidazolium chloride. Green Chem 9:63–69. https://doi.org/10.1039/B607614A
17. An Y-X, Zong M-H, Wu H, Li N (2015) Pretreatment of lignocellulosic biomass with renewable cholinium ionic liquids: Biomass fractionation, enzymatic digestion and ionic liquid
reuse. Bioresour Technol 192:165–171. https://doi.org/10.1016/j.biortech.2015.05.064
18. Hu S, Zhang Z, Zhou Y, Han B, Fan H, Li W, Song J, Xie Y (2008) Conversion of fructose to
5-hydroxymethylfurfural using ionic liquids prepared from renewable materials. Green Chem
10:1280–1283. https://doi.org/10.1039/b810392e
19. Rogers RD, Seddon KR (2003) Ionic liquids–solvents of the future? Science 302:792–793.
https://doi.org/10.1126/science.1090313
20. Plechkova NV, Seddon KR (2008) Applications of ionic liquids in the chemical industry.
Chem Soc Rev 37:123–150. https://doi.org/10.1039/B006677J
21. García-Verdugo E, Altava B, Burguete MI, Lozano P, Luis SV (2015) Ionic liquids and
continuous flow processes: a good marriage to design sustainable processes. Green Chem
17:2693–2713. https://doi.org/10.1039/C4GC02388A
