3.4 Cluster Odd–Even Alternation
49
Fig. 3.8 Comparison of the experimental PES spectra of O 2 Au 6
– (a), O 2 Au 8
– (c and d), O 2 Au 12
–
(f), O 2 Au 14
– (h), and O 2 Au 18
– (j) with the computed spectra and the corresponding structures (b),
(e), (g), (i), (k). The experimental spectra of O 2 Au 8
– (c and d) were obtained under two different
experimental conditions. The simulated spectra of the superoxo and peroxo isomers are represented
in brown and blue colours, respectively. Reproduced from Ref. [43]. Copyright 2012 American
Chemical Society
49
Fig. 3.8 Comparison of the experimental PES spectra of O 2 Au 6
– (a), O 2 Au 8
– (c and d), O 2 Au 12
–
(f), O 2 Au 14
– (h), and O 2 Au 18
– (j) with the computed spectra and the corresponding structures (b),
(e), (g), (i), (k). The experimental spectra of O 2 Au 8
– (c and d) were obtained under two different
experimental conditions. The simulated spectra of the superoxo and peroxo isomers are represented
in brown and blue colours, respectively. Reproduced from Ref. [43]. Copyright 2012 American
Chemical Society