Soil and radish leaf
–
chlordiazepoxide, clonazepam, diazepam,
flurazepam, nordiazepam,
oxazepam, temazepam,
triazolam
1 g soil
1 g wet
weight
plant
Soil: 1 g sand
+2*5 mL MeOH
+1*5 mL acetone
Plant: 1 g sand
+3*5 mL ACN:H
2 O
(70:30, v/v) (15 mL
total)
None (sonication method)
None
SPE clean-up (Oasis
HLB 6 mL 200 mg)
LC-MS/MS
[31]
Radish and ryegrass
– carbamazepine, diclofenac,
fluoxetine, propranolol,
sulfamethazine, triclosan
1 g wet
weight of
plant (leaf
and root)
1 g sand +3*5 mL
ACN:H
2 O (70:30,
v/v)
None (sonication method)
None
SPE clean-up (Oasis
HLB 6 mL 200 mg)
LC-MS/MS
(Thermo
Finnigan
TSQ
Quantum
Discovery
Max)
[133]
Chinese white cabbage,
water spinach, Chinese
radish, corn, and rice
– tetracycline, sulfamethazine,
norfloxacin, erythromycin,
chloramphenicol
1 g weight
crop
30 mL acidified
ACN:acetone (1:1,
v/v, pH
¼ 3)
None
(ultrasonication)
None
SPE clean-up HLB
cartridges
LC-MS/MS
QqQ
[136]
Tomato
– diclofenac, sulfamethoxazole, and
trimethoprim
10 g wet
plant
TMP and DCF:
10 mL MeOH +
NaHCO
3 (pH 6–7)
SMX: 10 mL
MeOH (pH 3–4)
None (sonication method)
None
None
UPLC-MS/
MS QqQ
[44]
Pisum sativum
L. var.
axiphium
– carbamazepine,
atenolol, sulfamethoxazole,
and metabolites
0,1 g dry
weight
1 mL ACN:H
2 O
(1:1, v/v, 0,1%
formic acid)
None (sonication method)
None
None
LC-MS/MS
QqQ
[43]
(continued)
Development of Methods for the Determination of PhACs in Soil/Earthworm/Crop. . .
457