641
162. Weissermel K, Arpe HJ (1997) Industrial organic chemistry. VCH ver-lagsgesellschaft,
Weinheim
163. Lejkowski ML, Lindner R, Kageyama T, Bdizs G, Plessow PN, Muller IB, Schafer A,
Rominger F, Hofmann P, Futter C, Schunk SA, Limbach M (2012) The first catalytic synthesis of an acrylate from CO 2 and an alkene-A rational approach. Chem Eur J 18:14017–14025
164. Saito S, Nakagawa S, Koizumi T, Hirayama K, Yamamoto YJ (1999) Nickel-mediated regioand chemoselective carboxylation of alkynes in the presence of carbon dioxide. Org Chem
64:3975–3978
165. Takimoto M, Mori M (2001) Cross-coupling reaction of oxo-π-allylnickel complex generated
from 1,3-Diene under an atmosphere of carbon dioxide. J Am Chem Soc 123:2895–2896
166. Takimoto M, Kawamura M, Mori M (2003) Nickel (0)-mediated sequential addition of carbon dioxide and aryl aldehydes into terminal allenes. Org Lett 5:2599–2601
167. Aoki M, Kaneko M, Izumi S, Ukai K, Iwasawa N (2004) Bidentate amidine ligands for
nickel(0)-mediated coupling of carbon dioxide with unsaturated hydrocarbons. Chem
Commun:2568–2569
168. Kuhlmann R, Prüllage A, Künnemann K, Behr A, Vorholt AJ (2017) Process development of
the continuously operated synthesis of N, N-dimethylformamide based on carbon dioxide. J
CO2 Util 22:184–190
169. Olmos A, Asensio G, Pérez PJ (2016) Homogeneous metal-based catalysis in supercritical
carbon dioxide as reaction medium. ACS Catal 6:4265–4280
170. Jessop PG, Hsiao Y, Ikariya T, Noyori R (1996) Homogeneous catalysis in supercritical fluids: hydrogenation of supercritical carbon dioxide to formic acid, alkyl formates, and formamides. J Am Chem Soc 118:344–355
171. Kayaki Y, Shimokawatoko Y, Ikariya T (2007) Synthesis of ruthenium(II) complexes containing hydroxymethylphosphines and their catalytic activities for hydrogenation of supercritical
carbon dioxide. Inorg Chem 46:5791–5797
172. Kröcher O, Köppel RA, Baiker A (1997) Highly active ruthenium complexes with bidentate
phosphine ligands for the solvent-free catalytic synthesis of N,N-dimethylformamide and
methyl formate. Chem Commun:453–454
173. Pokharel UR, Fronczek FR, Maverick AW (2014) Reduction of carbon dioxide to oxalate by
a binuclear copper complex. Nat Commun 5:5883
174. Angamuthu R, Byers P, Lutz M, Spek AL, Bouwman E (2010) Electrocatalytic CO 2 conversion to oxalate by a copper complex. Science 327:313–315
175. Zhou W, Cheng K, Kang J, Zhou C, Subramanian V, Zhang Q, Wang Y (2019) New horizon
in C1 chemistry: breaking the selectivity limitation in transformation of syngas and hydrogenation of CO 2 into hydrocarbon chemicals and fuels. Chem Soc Rev 48:3193–3228
176. Matsuo T, Kawaguchi H (2006) From carbon dioxide to methane: homogeneous reduction of
carbon dioxide with hydrosilanes catalyzed by zirconium-borane complexes. J Am Chem Soc
128:12362–12363
177. Chen J, Falivene L, Caporaso L, Cavallo L, Chen EYX (2016) Selective reduction of CO 2 to
CH 4 by tandem hydrosilylation with mixed Al/B catalysts. J Am Chem Soc 138:5321–5333
Efficient Homogeneous Catalysts for Conversion of CO 2 to Fine Chemicals
162. Weissermel K, Arpe HJ (1997) Industrial organic chemistry. VCH ver-lagsgesellschaft,
Weinheim
163. Lejkowski ML, Lindner R, Kageyama T, Bdizs G, Plessow PN, Muller IB, Schafer A,
Rominger F, Hofmann P, Futter C, Schunk SA, Limbach M (2012) The first catalytic synthesis of an acrylate from CO 2 and an alkene-A rational approach. Chem Eur J 18:14017–14025
164. Saito S, Nakagawa S, Koizumi T, Hirayama K, Yamamoto YJ (1999) Nickel-mediated regioand chemoselective carboxylation of alkynes in the presence of carbon dioxide. Org Chem
64:3975–3978
165. Takimoto M, Mori M (2001) Cross-coupling reaction of oxo-π-allylnickel complex generated
from 1,3-Diene under an atmosphere of carbon dioxide. J Am Chem Soc 123:2895–2896
166. Takimoto M, Kawamura M, Mori M (2003) Nickel (0)-mediated sequential addition of carbon dioxide and aryl aldehydes into terminal allenes. Org Lett 5:2599–2601
167. Aoki M, Kaneko M, Izumi S, Ukai K, Iwasawa N (2004) Bidentate amidine ligands for
nickel(0)-mediated coupling of carbon dioxide with unsaturated hydrocarbons. Chem
Commun:2568–2569
168. Kuhlmann R, Prüllage A, Künnemann K, Behr A, Vorholt AJ (2017) Process development of
the continuously operated synthesis of N, N-dimethylformamide based on carbon dioxide. J
CO2 Util 22:184–190
169. Olmos A, Asensio G, Pérez PJ (2016) Homogeneous metal-based catalysis in supercritical
carbon dioxide as reaction medium. ACS Catal 6:4265–4280
170. Jessop PG, Hsiao Y, Ikariya T, Noyori R (1996) Homogeneous catalysis in supercritical fluids: hydrogenation of supercritical carbon dioxide to formic acid, alkyl formates, and formamides. J Am Chem Soc 118:344–355
171. Kayaki Y, Shimokawatoko Y, Ikariya T (2007) Synthesis of ruthenium(II) complexes containing hydroxymethylphosphines and their catalytic activities for hydrogenation of supercritical
carbon dioxide. Inorg Chem 46:5791–5797
172. Kröcher O, Köppel RA, Baiker A (1997) Highly active ruthenium complexes with bidentate
phosphine ligands for the solvent-free catalytic synthesis of N,N-dimethylformamide and
methyl formate. Chem Commun:453–454
173. Pokharel UR, Fronczek FR, Maverick AW (2014) Reduction of carbon dioxide to oxalate by
a binuclear copper complex. Nat Commun 5:5883
174. Angamuthu R, Byers P, Lutz M, Spek AL, Bouwman E (2010) Electrocatalytic CO 2 conversion to oxalate by a copper complex. Science 327:313–315
175. Zhou W, Cheng K, Kang J, Zhou C, Subramanian V, Zhang Q, Wang Y (2019) New horizon
in C1 chemistry: breaking the selectivity limitation in transformation of syngas and hydrogenation of CO 2 into hydrocarbon chemicals and fuels. Chem Soc Rev 48:3193–3228
176. Matsuo T, Kawaguchi H (2006) From carbon dioxide to methane: homogeneous reduction of
carbon dioxide with hydrosilanes catalyzed by zirconium-borane complexes. J Am Chem Soc
128:12362–12363
177. Chen J, Falivene L, Caporaso L, Cavallo L, Chen EYX (2016) Selective reduction of CO 2 to
CH 4 by tandem hydrosilylation with mixed Al/B catalysts. J Am Chem Soc 138:5321–5333
Efficient Homogeneous Catalysts for Conversion of CO 2 to Fine Chemicals