483
Rate expression
Reaction condition
References
R
k K P
CH
H
4
2
71 1 2
2
=
∗
[ ]
α
R
kK P
n
n
n
i
i
C H
H
2 2
2
7 2
1
2
+
=
∏ ∗
[ ]
=
α
R
k K P
CH OH
H O
3
2
61 2 1
2
=
∗
[ ]
α
R
kK P
n
n
n
i
i
C H
OH
H O
2 1
2
6 2
1
2
+
=
∏ ∗
[ ]
=
α
R
k K P
n
n
n
i
i
C H
H
n
2
2
8
2
1
1
=
−
(
)∏ ∗
[ ]
=
β
α
β
α
n
i
n
i
k P
k
n
n
=
∏
−
=
8
8
1
2
C H
α
n
K k P
K k P
k P
K P
K P
k K P
k
=
∗
[ ]
∗
[ ]+
∗
[ ]+
∗
[ ]+
1 3
1 3
6
2
5
7
2
8
2
2
2
2
1
CO
CO
H O
H
H
H
− −
(
)
β
n
∗
[ ] =
+
+
+ +
+








∑
1
1
1
2
1
5
4 5
2
2
2
2
2
2
2
2
K P
K P
P
K P
P
K K P
K P
i
H
C O
H O
H
H O
H
H
= =
=
∏
(
)
2
2
1
N
j
i
j
α α
T,
Co/AC catalyst
Fixed bed reactor
T—220–250 °C
P—2.0–4.0 MPa,
H
2 /
CO-1.0–2.5
Qian et al. [93]
Recent Advancements and Detailed Understanding of Kinetics for Synthesis Gas…