311
142. Too PC, Noji T, Lim YJ, Li X, Chiba S (2011) Rhodium(III)-Catalyzed Synthesis of Pyridines
from α,β-Unsaturated Ketoximes and Internal Alkynes. Synlett 19:2789
143. Zhang X, Qi Z, Li X (2014) Rhodium(III) –Catalyzed C–C and C–O Coupling of Quinoline
N‐Oxides with Alkynes: Combination of C–H Activation with O–Atom Transfer. Angew.
Chem. Int. Ed. 126:10970
144. Wang C, Huang Y (2013) Traceless Directing Strategy: Efficient Synthesis of N-Alkyl
Indoles via Redox-Neutral C–H Activation. Org. Lett. 15:5294
145. Muralirajan K, Haridharan R, Prakash S, Cheng C-H (2015) Rhodium(III) –Catalyzed in
situ Oxidizing Directing Group–Assisted C–H Bond Activation and Olefination: A Route
to 2‐Vinylanilines. Adv. Syn. Cat. 357:761
146. Deshmukh DS, Yadav PA, Bhanage BM (2019) Cp*Co(iii)-catalyzed annulation of azines by
C–H/N–N bond activation for the synthesis of isoquinolines. Org. Biomol. Chem. 17:3489
147. Zhang Q-R, Huang J-R, Zhang W, Dong L (2014) Highly Functionalized Pyridines Synthesis
from N-Sulfonyl Ketimines and Alkynes Using the N–S Bond as an Internal Oxidant. Org.
Lett. 16:1684
148. Kaishap PP, Sarma B, Gogoi S (2016) The amide C–N bond of isatins as the directing group
and the internal oxidant in Ru-catalyzed C–H activation and annulation reactions: access to
8-amido isocoumarins. Chem. Commun. 52:9809
149. Wu Z, Song H, Cui X, Pi C, Du W, Wu Y (2013) Sulfonylation of Quinoline N-Oxides with
Aryl Sulfonyl Chlorides via Copper-Catalyzed C–H Bonds Activation. Org. Lett. 15:1270
150. Ureshino T, Yoshida T, Kuninobu Y, Takai K (2010) Rhodium-Catalyzed Synthesis of
Silafluorene Derivatives via Cleavage of Silicon−Hydrogen and Carbon−Hydrogen Bonds.
J. Am. Chem. Soc. 132:14324
151. Kuninobu Y, Yamauchi K, Tamura N, Seiki T, Takai K (2013) Rhodium‐Catalyzed
Asymmetric Synthesis of Spirosilabifluorene Derivatives. Angew. Chem. Int. Ed. 52:1520
152. Zhou Z, Liu G, Chen Y, Lu X (2015) Rhodium(III)‐Catalyzed Redox‐Neutral C–H Annulation
of Arylnitrones and Alkynes for the Synthesis of Indole Derivatives. Adv. Synth. Catal.
357:2944
153. Li B, Pierre H, Dixneuf (2013) sp2 C–H bond activation in water and catalytic cross-coupling
reactions. Chem Soc Rev 42:5744
154. Yang J, Fu T, Long Y, Zhou X (2017) Bifunctional Ion Pair Catalysts from Chiral α‐Amino
Acids. Chin J Org Chem 37:1111
155. Gandeepan P, Kaplaneris N, Santoro S, Vaccaro L, Ackermann L (2019) Biomass-Derived
Solvents for Sustainable Transition Metal-Catalyzed C–H Activation. ACS Sustainable Chem
Eng 7:8023
156. Lipshutz BH, Gallou F, Handa S (2016) Evolution of Solvents in Organic Chemistry. ACS
Sustainable Chem Eng. 4: 5838
157. Sheldon R (2005) Green solvents for sustainable organic synthesis: state of the art. Green
Chem. 7:267
158. Nie R, Lai R, Lv S, Xu Y, Guo L, Wang Q, Wu Y (2019) Water-mediated C–H activation
of arenes with secure carbene precursors: the reaction and its application. Chem Commun
55:11418
159. Herrerías CI, Yao X, Li Z, Li C-J (2007) Reactions of C−H Bonds in Water. Chem Rev
107:2546
160. Ma W, Mei R, Tenti G, Ackermann L (2014) Ruthenium(II)‐Catalyzed Oxidative C–H
Alkenylations of Sulfonic Acids, Sulfonyl Chlorides and Sulfonamides. Chem Eur J 20:15248
161. Upadhyay N, Thorat V H, Sato R, Annamalai P, Chuang S-C, Cheng C-H (2017) Synthesis
of isoquinolones via Rh-catalyzed C–H activation of substituted benzamides using air as the
sole oxidant in water. Green Chem 19:3219
162. Gong H, Zeng H, Zhou F, Li C (2015) Rhodium(I)-catalyzed regiospecific dimerization of
aromatic acids: two direct C-H bond activations in water. Angew Chem Int Ed 54:5718
163. Hu X, Yang X, Dai X‐J, Li C‐J (2017) Palladium‐Catalyzed Direct β‐C−H Arylation of
Ketones with Arylboronic Acids in Water. Adv Syn Catal 359:2402
Insights into Sustainable C–H Bond Activation
142. Too PC, Noji T, Lim YJ, Li X, Chiba S (2011) Rhodium(III)-Catalyzed Synthesis of Pyridines
from α,β-Unsaturated Ketoximes and Internal Alkynes. Synlett 19:2789
143. Zhang X, Qi Z, Li X (2014) Rhodium(III) –Catalyzed C–C and C–O Coupling of Quinoline
N‐Oxides with Alkynes: Combination of C–H Activation with O–Atom Transfer. Angew.
Chem. Int. Ed. 126:10970
144. Wang C, Huang Y (2013) Traceless Directing Strategy: Efficient Synthesis of N-Alkyl
Indoles via Redox-Neutral C–H Activation. Org. Lett. 15:5294
145. Muralirajan K, Haridharan R, Prakash S, Cheng C-H (2015) Rhodium(III) –Catalyzed in
situ Oxidizing Directing Group–Assisted C–H Bond Activation and Olefination: A Route
to 2‐Vinylanilines. Adv. Syn. Cat. 357:761
146. Deshmukh DS, Yadav PA, Bhanage BM (2019) Cp*Co(iii)-catalyzed annulation of azines by
C–H/N–N bond activation for the synthesis of isoquinolines. Org. Biomol. Chem. 17:3489
147. Zhang Q-R, Huang J-R, Zhang W, Dong L (2014) Highly Functionalized Pyridines Synthesis
from N-Sulfonyl Ketimines and Alkynes Using the N–S Bond as an Internal Oxidant. Org.
Lett. 16:1684
148. Kaishap PP, Sarma B, Gogoi S (2016) The amide C–N bond of isatins as the directing group
and the internal oxidant in Ru-catalyzed C–H activation and annulation reactions: access to
8-amido isocoumarins. Chem. Commun. 52:9809
149. Wu Z, Song H, Cui X, Pi C, Du W, Wu Y (2013) Sulfonylation of Quinoline N-Oxides with
Aryl Sulfonyl Chlorides via Copper-Catalyzed C–H Bonds Activation. Org. Lett. 15:1270
150. Ureshino T, Yoshida T, Kuninobu Y, Takai K (2010) Rhodium-Catalyzed Synthesis of
Silafluorene Derivatives via Cleavage of Silicon−Hydrogen and Carbon−Hydrogen Bonds.
J. Am. Chem. Soc. 132:14324
151. Kuninobu Y, Yamauchi K, Tamura N, Seiki T, Takai K (2013) Rhodium‐Catalyzed
Asymmetric Synthesis of Spirosilabifluorene Derivatives. Angew. Chem. Int. Ed. 52:1520
152. Zhou Z, Liu G, Chen Y, Lu X (2015) Rhodium(III)‐Catalyzed Redox‐Neutral C–H Annulation
of Arylnitrones and Alkynes for the Synthesis of Indole Derivatives. Adv. Synth. Catal.
357:2944
153. Li B, Pierre H, Dixneuf (2013) sp2 C–H bond activation in water and catalytic cross-coupling
reactions. Chem Soc Rev 42:5744
154. Yang J, Fu T, Long Y, Zhou X (2017) Bifunctional Ion Pair Catalysts from Chiral α‐Amino
Acids. Chin J Org Chem 37:1111
155. Gandeepan P, Kaplaneris N, Santoro S, Vaccaro L, Ackermann L (2019) Biomass-Derived
Solvents for Sustainable Transition Metal-Catalyzed C–H Activation. ACS Sustainable Chem
Eng 7:8023
156. Lipshutz BH, Gallou F, Handa S (2016) Evolution of Solvents in Organic Chemistry. ACS
Sustainable Chem Eng. 4: 5838
157. Sheldon R (2005) Green solvents for sustainable organic synthesis: state of the art. Green
Chem. 7:267
158. Nie R, Lai R, Lv S, Xu Y, Guo L, Wang Q, Wu Y (2019) Water-mediated C–H activation
of arenes with secure carbene precursors: the reaction and its application. Chem Commun
55:11418
159. Herrerías CI, Yao X, Li Z, Li C-J (2007) Reactions of C−H Bonds in Water. Chem Rev
107:2546
160. Ma W, Mei R, Tenti G, Ackermann L (2014) Ruthenium(II)‐Catalyzed Oxidative C–H
Alkenylations of Sulfonic Acids, Sulfonyl Chlorides and Sulfonamides. Chem Eur J 20:15248
161. Upadhyay N, Thorat V H, Sato R, Annamalai P, Chuang S-C, Cheng C-H (2017) Synthesis
of isoquinolones via Rh-catalyzed C–H activation of substituted benzamides using air as the
sole oxidant in water. Green Chem 19:3219
162. Gong H, Zeng H, Zhou F, Li C (2015) Rhodium(I)-catalyzed regiospecific dimerization of
aromatic acids: two direct C-H bond activations in water. Angew Chem Int Ed 54:5718
163. Hu X, Yang X, Dai X‐J, Li C‐J (2017) Palladium‐Catalyzed Direct β‐C−H Arylation of
Ketones with Arylboronic Acids in Water. Adv Syn Catal 359:2402
Insights into Sustainable C–H Bond Activation