310
121. Bechtoldt A, Tirler C, Raghuvanshi K, Warratz S, Kornhaaß C, Ackermann L (2016)
Ruthenium Oxidase Catalysis for Site-Selective C-H Alkenylations with Ambient O2 as the
Sole Oxidant. Angew. Chem. Int. Ed. 55:264
122. Tan Y, Hartwig JFJ (2010) Palladium-Catalyzed Amination of Aromatic C−H Bonds with
Oxime Esters. Am. Chem. Soc. 132:3676
123. Ng K-H, Chan ASC, Yu W-Y (2010) Pd-Catalyzed Intermolecular ortho-C−H Amidation of
Anilides by N-Nosyloxycarbamate. J. Am. Chem. Soc. 132:12862
124. Rakshit S, Grohmann C, Besset T, Glorius F (2011) Rh(III)-Catalyzed Directed C−H
Olefination Using an Oxidizing Directing Group: Mild, Efficient, and Versatile. J. Am.
Chem. Soc. 133:2350
125. Guimond N, Gouliaras C, Fagnou K (2010) Rhodium(III)-Catalyzed Isoquinolone Synthesis:
The N−O Bond as a Handle for C−N Bond Formation and Catalyst Turnover. J. Am. Chem.
Soc. 132:6908
126. Guimond N, Gorelsky SI, Fagnou K (2011) Rhodium(III)-Catalyzed Heterocycle Synthesis
Using an Internal Oxidant: Improved Reactivity and Mechanistic Studies. J. Am. Chem. Soc.
133:6449
127. Ackermann L, Fenner S (2011) Ruthenium-Catalyzed C–H/N–O Bond Functionalization:
Green Isoquinolone Syntheses in Water. Org. Lett. 13:6548
128. Patureau FW, Glorius F (2011) Oxidizing directing groups enable efficient and innovative
C-H activation reactions. Angew. Chem. Int. Ed. 50:1977
129. Chinnagolla RK, Pimparkar S, Jeganmohan M (2012) Ruthenium-Catalyzed Highly
Regioselective Cyclization of Ketoximes with Alkynes by C–H Bond Activation: A Practical
Route to Synthesize Substituted Isoquinolines. Org. Lett. 14:3032
130. Mo J, Wang L, Cui X (2015) Rhodium(III)-Catalyzed C–H Activation/Alkyne Annulation by
Weak Coordination of Peresters with O–O Bond as an Internal Oxidant. Org. Lett. 17:4960
131. Liu G, Shen Y, Zhou Z, Lu X (2013) Rhodium(III)-catalyzed redox-neutral coupling of
N-phenoxyacetamides and alkynes with tunable selectivity. Angew. Chem. Int. Ed. 52:6033
132. Hyster TK, Ruhl KE, Rovis T (2013) A Coupling of Benzamides and Donor/Acceptor Diazo
Compounds To Form γ-Lactams via Rh(III)-Catalyzed C–H Activation. J. Am. Chem. Soc.
135:5364
133. Huang X, Huang J, Du C, Zhang X, Song F, You J (2013) N‐Oxide as a Traceless Oxidizing
Directing Group: Mild Rhodium(III) –Catalyzed C–H Olefination for the Synthesis of ortho–
Alkenylated Tertiary Anilines. Angew. Chem. Int. Ed. 52:12970
134. Wang H, Grohmann C, Nimphius C, Glorius F (2012) Mild Rh(III)-Catalyzed C–H Activation
and Annulation with Alkyne MIDA Boronates: Short, Efficient Synthesis of Heterocyclic
Boronic Acid Derivatives. J. Am. Chem. Soc. 134:19592
135. Kornhaaß C, Kuper C, Ackermann L (2014) Ferrocenylalkynes for Ruthenium–Catalyzed
Isohypsic C–H/N–O Bond Functionalizations. Adv. Synth. Catal. 356:1619
136. Yang F, Ackermann L (2014) Dehydrative C–H/N–OH Functionalizations in H2O by
Ruthenium(II) Catalysis: Subtle Effect of Carboxylate Ligands and Mechanistic Insight.
J. Org. Chem. 79:12070
137. Yu S, Liu S, Lan Y, Wan B, Li X (2015) Rhodium-Catalyzed C–H Activation of Phenacyl
Ammonium Salts Assisted by an Oxidizing C–N Bond: A Combination of Experimental and
Theoretical Studies. J. Am. Chem. Soc. 137:1623
138. Brasche G, Buchwald SL (2008) C-H functionalization/C-N bond formation: coppercatalyzed synthesis of benzimidazoles from amidines. Angew. Chem. Int. Ed. 47:1932
139. Mei T-S, Wang X, Yu J-Q (2009) Pd(II)-Catalyzed Amination of C−H Bonds Using SingleElectron or Two-electron Oxidants. J. Am. Chem. Soc. 131:10806
140. Stokes BJ, Dong H, Leslie BE, Pumphrey AL, Driver TG (2007) Intramolecular
C−H Amination Reactions: Exploitation of the Rh2(II)-Catalyzed Decomposition of
Azidoacrylates. J. Am. Chem. Soc. 129:7500
141. Chiba S, Hattori G, Narasaka K (2007) Rh(II)-catalyzed Isomerization of 2-Aryl-2H-azirines
to 2,3-Disubstituted Indoles. Chem. Lett. 36:52
D. S. Deshmukh et al.
121. Bechtoldt A, Tirler C, Raghuvanshi K, Warratz S, Kornhaaß C, Ackermann L (2016)
Ruthenium Oxidase Catalysis for Site-Selective C-H Alkenylations with Ambient O2 as the
Sole Oxidant. Angew. Chem. Int. Ed. 55:264
122. Tan Y, Hartwig JFJ (2010) Palladium-Catalyzed Amination of Aromatic C−H Bonds with
Oxime Esters. Am. Chem. Soc. 132:3676
123. Ng K-H, Chan ASC, Yu W-Y (2010) Pd-Catalyzed Intermolecular ortho-C−H Amidation of
Anilides by N-Nosyloxycarbamate. J. Am. Chem. Soc. 132:12862
124. Rakshit S, Grohmann C, Besset T, Glorius F (2011) Rh(III)-Catalyzed Directed C−H
Olefination Using an Oxidizing Directing Group: Mild, Efficient, and Versatile. J. Am.
Chem. Soc. 133:2350
125. Guimond N, Gouliaras C, Fagnou K (2010) Rhodium(III)-Catalyzed Isoquinolone Synthesis:
The N−O Bond as a Handle for C−N Bond Formation and Catalyst Turnover. J. Am. Chem.
Soc. 132:6908
126. Guimond N, Gorelsky SI, Fagnou K (2011) Rhodium(III)-Catalyzed Heterocycle Synthesis
Using an Internal Oxidant: Improved Reactivity and Mechanistic Studies. J. Am. Chem. Soc.
133:6449
127. Ackermann L, Fenner S (2011) Ruthenium-Catalyzed C–H/N–O Bond Functionalization:
Green Isoquinolone Syntheses in Water. Org. Lett. 13:6548
128. Patureau FW, Glorius F (2011) Oxidizing directing groups enable efficient and innovative
C-H activation reactions. Angew. Chem. Int. Ed. 50:1977
129. Chinnagolla RK, Pimparkar S, Jeganmohan M (2012) Ruthenium-Catalyzed Highly
Regioselective Cyclization of Ketoximes with Alkynes by C–H Bond Activation: A Practical
Route to Synthesize Substituted Isoquinolines. Org. Lett. 14:3032
130. Mo J, Wang L, Cui X (2015) Rhodium(III)-Catalyzed C–H Activation/Alkyne Annulation by
Weak Coordination of Peresters with O–O Bond as an Internal Oxidant. Org. Lett. 17:4960
131. Liu G, Shen Y, Zhou Z, Lu X (2013) Rhodium(III)-catalyzed redox-neutral coupling of
N-phenoxyacetamides and alkynes with tunable selectivity. Angew. Chem. Int. Ed. 52:6033
132. Hyster TK, Ruhl KE, Rovis T (2013) A Coupling of Benzamides and Donor/Acceptor Diazo
Compounds To Form γ-Lactams via Rh(III)-Catalyzed C–H Activation. J. Am. Chem. Soc.
135:5364
133. Huang X, Huang J, Du C, Zhang X, Song F, You J (2013) N‐Oxide as a Traceless Oxidizing
Directing Group: Mild Rhodium(III) –Catalyzed C–H Olefination for the Synthesis of ortho–
Alkenylated Tertiary Anilines. Angew. Chem. Int. Ed. 52:12970
134. Wang H, Grohmann C, Nimphius C, Glorius F (2012) Mild Rh(III)-Catalyzed C–H Activation
and Annulation with Alkyne MIDA Boronates: Short, Efficient Synthesis of Heterocyclic
Boronic Acid Derivatives. J. Am. Chem. Soc. 134:19592
135. Kornhaaß C, Kuper C, Ackermann L (2014) Ferrocenylalkynes for Ruthenium–Catalyzed
Isohypsic C–H/N–O Bond Functionalizations. Adv. Synth. Catal. 356:1619
136. Yang F, Ackermann L (2014) Dehydrative C–H/N–OH Functionalizations in H2O by
Ruthenium(II) Catalysis: Subtle Effect of Carboxylate Ligands and Mechanistic Insight.
J. Org. Chem. 79:12070
137. Yu S, Liu S, Lan Y, Wan B, Li X (2015) Rhodium-Catalyzed C–H Activation of Phenacyl
Ammonium Salts Assisted by an Oxidizing C–N Bond: A Combination of Experimental and
Theoretical Studies. J. Am. Chem. Soc. 137:1623
138. Brasche G, Buchwald SL (2008) C-H functionalization/C-N bond formation: coppercatalyzed synthesis of benzimidazoles from amidines. Angew. Chem. Int. Ed. 47:1932
139. Mei T-S, Wang X, Yu J-Q (2009) Pd(II)-Catalyzed Amination of C−H Bonds Using SingleElectron or Two-electron Oxidants. J. Am. Chem. Soc. 131:10806
140. Stokes BJ, Dong H, Leslie BE, Pumphrey AL, Driver TG (2007) Intramolecular
C−H Amination Reactions: Exploitation of the Rh2(II)-Catalyzed Decomposition of
Azidoacrylates. J. Am. Chem. Soc. 129:7500
141. Chiba S, Hattori G, Narasaka K (2007) Rh(II)-catalyzed Isomerization of 2-Aryl-2H-azirines
to 2,3-Disubstituted Indoles. Chem. Lett. 36:52
D. S. Deshmukh et al.