226
41. Valcárcel A et al (2004) Comparative DFT study of the adsorption of 1,3-butadiene, 1-butene
and 2-cis/trans-butenes on the Pt(1 1 1) and Pd(1 1 1) surfaces. Surf Sci 549(2):121–133
42. Valcárcel A et al (2005) Selectivity control for the catalytic 1,3-butadiene hydrogenation
on Pt(111) and Pd(111) surfaces: radical versus closed-shell intermediates. J Phys Chem B
109(29):14175–14182
43. Baetzold RC (1987) Properties of chemisorbed ethylene and butadiene. Langmuir
3(2):189–197
44. Avery NR, Sheppard N (1986) The use of thermal desorption and electron energy loss spectroscopy for the determination of the structures of unsaturated hydrocarbons chemisorbed on
metal single-crystal surfaces. II. Cis- and trans-but-2-ene, but-2-yne and buta-1,3-diene on
Pt(111). Proc R Soc Lond A Math Phys Sci 405(1828):27–39
45. Cassuto A, Tourillon G (1994) The adsorption of butene-1, isobutene, cis-2-butene and
trans-2-butene on Pt(111) at 95 K: NEXAFS and UPS results. Surf Sci 307–309(Part
A):65–69
46. Tsai Y-L, Koel BE (1997) Temperature-programmed desorption investigation of the adsorption and reaction of butene isomers on Pt(111) and ordered Pt−Sn surface alloys. J Phys
Chem B 101(15):2895–2906
47. Tourillon G et al (1996) Buta-1,3-diene and but-1-ene chemisorption on Pt(111), Pd(111),
Pd(110) and Pd50Cu50(111) as studied by UPS, NEXAFS and HREELS in relation to catalysis. J Chem Soc Faraday Trans 92(23):4835–4841
48. Maurice V, Minot C (1989) A theoretical investigation of the adsorption modes of ethene,
1,3-butadiene, 1-butene, and cis- and trans-2-butenes on the unreconstructed (110) surface of
platinum. Langmuir 5(3):734–741
49. Massardier J et al (1988) Platinum single crystals: the effect of surface structure and the influence of K and Na on the activity and the selectivity for 1,3-butadiene hydrogenation. J Catal
112(1):21–33
50. Ouchaib T et al (1989) Competitive hydrogenation of butadiene and butene on palladium and
platinum catalysts. J Catal 119(2):517–520
51. Bertolini JC et al (1996) A comparative study of 1,3-butadiene and 1-butene chemisorbed on
Pt(111), and Pd(111). Surf Sci 349(1):88–96
52. Chen S, Yang B (2020) Theoretical understandings on the unusual selectivity of 1,3-butadiene hydrogenation to butenes over gold catalysts. Catal Today 347:134–141
53. Bent BE et al (1991) Thermal decomposition of alkyl halides on aluminum. 2. The formation
and thermal decomposition of surface metallacycles derived from the dissociative chemisorption of dihaloalkanes. J Am Chem Soc 113(4):1143–1148
54. Chrysostomou D et al (2001) Thermal chemistry of C3 metallacycles on Pt(111) surfaces. J
Phys Chem B 105(25):5968–5978
55. Scoggins TB, White JM (1997) Thermal chemistry of allyl bromide adsorbed on Pt(111). J
Phys Chem B 101(40):7958–7967
56. Cukic T et al (2007) The influence of preparation variables on the performance of Pd/Al2O3
catalyst in the hydrogenation of 1,3-butadiene: building a basis for reproducible catalyst synthesis. Appl Catal A Gen 323:25–37
57. Hugon A et al (2009) Influence of the reactant concentration in selective hydrogenation of
1,3-butadiene over supported gold catalysts under alkene rich conditions: a consideration of
reaction mechanism. Gold Bull 42(4):310–320
58. Kolli NE et al (2013) Bimetallic Au-Pd catalysts for selective hydrogenation of butadiene:
influence of the preparation method on catalytic properties. J Catal 297:79–92
59. Liu C et al (2015) Hydrogenation of 1,3-butadiene over Au and Pt/SiO2-N catalysts at low
temperature. Catal Commun 67:72–77
60. Primet M et al (1990) Influence of the support towards platinum catalysed 1,3-butadiene
hydrogenation. Appl Catal 58(1):241–253
61. Sarkany A et al (1995) Participation of support sites in hydrogenation of 1,3-butadiene over
Pt/Al2O3 catalysts. Appl Catal A Gen 127(1–2):77–92
P. R. Selvakannan et al.
41. Valcárcel A et al (2004) Comparative DFT study of the adsorption of 1,3-butadiene, 1-butene
and 2-cis/trans-butenes on the Pt(1 1 1) and Pd(1 1 1) surfaces. Surf Sci 549(2):121–133
42. Valcárcel A et al (2005) Selectivity control for the catalytic 1,3-butadiene hydrogenation
on Pt(111) and Pd(111) surfaces: radical versus closed-shell intermediates. J Phys Chem B
109(29):14175–14182
43. Baetzold RC (1987) Properties of chemisorbed ethylene and butadiene. Langmuir
3(2):189–197
44. Avery NR, Sheppard N (1986) The use of thermal desorption and electron energy loss spectroscopy for the determination of the structures of unsaturated hydrocarbons chemisorbed on
metal single-crystal surfaces. II. Cis- and trans-but-2-ene, but-2-yne and buta-1,3-diene on
Pt(111). Proc R Soc Lond A Math Phys Sci 405(1828):27–39
45. Cassuto A, Tourillon G (1994) The adsorption of butene-1, isobutene, cis-2-butene and
trans-2-butene on Pt(111) at 95 K: NEXAFS and UPS results. Surf Sci 307–309(Part
A):65–69
46. Tsai Y-L, Koel BE (1997) Temperature-programmed desorption investigation of the adsorption and reaction of butene isomers on Pt(111) and ordered Pt−Sn surface alloys. J Phys
Chem B 101(15):2895–2906
47. Tourillon G et al (1996) Buta-1,3-diene and but-1-ene chemisorption on Pt(111), Pd(111),
Pd(110) and Pd50Cu50(111) as studied by UPS, NEXAFS and HREELS in relation to catalysis. J Chem Soc Faraday Trans 92(23):4835–4841
48. Maurice V, Minot C (1989) A theoretical investigation of the adsorption modes of ethene,
1,3-butadiene, 1-butene, and cis- and trans-2-butenes on the unreconstructed (110) surface of
platinum. Langmuir 5(3):734–741
49. Massardier J et al (1988) Platinum single crystals: the effect of surface structure and the influence of K and Na on the activity and the selectivity for 1,3-butadiene hydrogenation. J Catal
112(1):21–33
50. Ouchaib T et al (1989) Competitive hydrogenation of butadiene and butene on palladium and
platinum catalysts. J Catal 119(2):517–520
51. Bertolini JC et al (1996) A comparative study of 1,3-butadiene and 1-butene chemisorbed on
Pt(111), and Pd(111). Surf Sci 349(1):88–96
52. Chen S, Yang B (2020) Theoretical understandings on the unusual selectivity of 1,3-butadiene hydrogenation to butenes over gold catalysts. Catal Today 347:134–141
53. Bent BE et al (1991) Thermal decomposition of alkyl halides on aluminum. 2. The formation
and thermal decomposition of surface metallacycles derived from the dissociative chemisorption of dihaloalkanes. J Am Chem Soc 113(4):1143–1148
54. Chrysostomou D et al (2001) Thermal chemistry of C3 metallacycles on Pt(111) surfaces. J
Phys Chem B 105(25):5968–5978
55. Scoggins TB, White JM (1997) Thermal chemistry of allyl bromide adsorbed on Pt(111). J
Phys Chem B 101(40):7958–7967
56. Cukic T et al (2007) The influence of preparation variables on the performance of Pd/Al2O3
catalyst in the hydrogenation of 1,3-butadiene: building a basis for reproducible catalyst synthesis. Appl Catal A Gen 323:25–37
57. Hugon A et al (2009) Influence of the reactant concentration in selective hydrogenation of
1,3-butadiene over supported gold catalysts under alkene rich conditions: a consideration of
reaction mechanism. Gold Bull 42(4):310–320
58. Kolli NE et al (2013) Bimetallic Au-Pd catalysts for selective hydrogenation of butadiene:
influence of the preparation method on catalytic properties. J Catal 297:79–92
59. Liu C et al (2015) Hydrogenation of 1,3-butadiene over Au and Pt/SiO2-N catalysts at low
temperature. Catal Commun 67:72–77
60. Primet M et al (1990) Influence of the support towards platinum catalysed 1,3-butadiene
hydrogenation. Appl Catal 58(1):241–253
61. Sarkany A et al (1995) Participation of support sites in hydrogenation of 1,3-butadiene over
Pt/Al2O3 catalysts. Appl Catal A Gen 127(1–2):77–92
P. R. Selvakannan et al.