224
Acknowledgements The authors acknowledge the RMIT-CSIRO collaborative research on
hydrogenation of olefins. They also acknowledge Dr. Manh Hoang (CSIRO) and Dr. Sarvesh
Kumar Soni (RMIT) for their suggestions and technical discussion.
References
1. Alves JA et al (2012) Kinetic study of the selective catalytic hydrogenation of 1,3-butadiene
in a mixture of n-butenes. J Ind Eng Chem 18(4):1353–1365
2. Pérez D et al (2015) Study of the selective hydrogenation of 1,3-butadiene in three types of
industrial reactors. Fuel 149:34–45
3. Méndez FJ et al (2017) Selective hydrogenation of 1,3-butadiene in the presence of 1-butene
under liquid phase conditions using structured catalysts. Catal Today 289:151–161
4. Liu D et al (2018) Theoretical investigation of selective hydrogenation of 1,3-butadiene on Pt
doping Cu nanoparticles. Appl Surf Sci 456:59–68
5. Aguilar-Tapia A et al (2016) Selective hydrogenation of 1,3-butadiene over bimetallic Au-Ni/
TiO2 catalysts prepared by deposition-precipitation with urea. J Catal 344:515–523
6. Lozano L et al (2013) Influence of toluene on the catalytic activity of NiPdCe catalyst for
selective hydrogenation of 1,3-butadiene. Fuel 110:76–82
7. Ardiaca NO et al (2001) Experimental procedure for kinetic studies on egg-shell catalysts.
The case of liquid-phase hydrogenation of 1,3-butadiene and n-butenes on commercial Pd
catalysts. Catal Today 64(3–4):205–215
8. Boitiaux JP et al (1987) Hydrogenation of unsaturated hydrocarbons in liquid phase on palladium, platinum and rhodium catalysts. III. Quantitative selectivity ranking of platinum,
palladium and rhodium in the hydrogenation of 1-butene, 1,3-butadiene and 1-butyne using a
single reaction scheme. Appl Catal 35(2):193–209
9. Boitiaux JP et al (1987) Liquid phase hydrogenation of unsaturated hydrocarbons on
palladium, platinum and rhodium catalysts. Part I: kinetic study of 1-butene, 1,3-butadiene
and 1-butyne hydrogenation on platinum. Appl Catal 32:145–168
10. Boitiaux JP et al (1987) Liquid phase hydrogenation of unsaturated hydrocarbons on palladium, platinum and rhodium catalysts. Part II: kinetic study of 1-butene, 1,3-butadiene and
1-butyne hydrogenation on rhodium; comparison with platinum and palladium. Appl Catal
32:169–183
11. Gaube J, Klein HF (2014) Kinetics and mechanism of butene isomerization/hydrogenation
and of 1,3-butadiene hydrogenation on palladium. Appl Catal A Gen 470:361–368
12. Goetz J et al (1996) Kinetic aspects of selectivity and stereoselectivity for the hydrogenation
of buta-1,3-diene over a palladium catalyst. Ind Eng Chem Res 35(3):703–711
13. Goetz J et al (1996) Kinetics of buta-1,3-diene hydrogenation over palladium catalysts. Chem
Eng Sci 51(11):2879–2884
14. Goetz J et al (1997) Kinetics of buta-1,3-diene hydrogenation over 0.5% Pd/γ-Al2O3 catalyst.
Chem Eng Technol 20(2):138–143
15. Goetz J et al (1996) Low-loaded Pd/α-Al2O3 catalysts: influence of metal particle morphology on hydrogenation of buta-1,3-diene and hydrogenation and isomerization of but-1-ene. J
Catal 164(2):369–377
16. Horiuti I, Polanyi M (1934) Exchange reactions of hydrogen on metallic catalysts. Trans
Faraday Soc 30:1164–1172
17. Santiso EE et al (2008) Isomerization kinetics of small hydrocarbons in confinement.
Adsorption 14(2–3):181–188
18. Bates AJ et al (1970) The hydrogenation of akladienes. Part IV. The reaction of buta-1,3diene with deuterium catalysed by rhodium, palladium, and platinum. J Chem Soc AInorgan
Phys Theor:2435–2441
P. R. Selvakannan et al.
Acknowledgements The authors acknowledge the RMIT-CSIRO collaborative research on
hydrogenation of olefins. They also acknowledge Dr. Manh Hoang (CSIRO) and Dr. Sarvesh
Kumar Soni (RMIT) for their suggestions and technical discussion.
References
1. Alves JA et al (2012) Kinetic study of the selective catalytic hydrogenation of 1,3-butadiene
in a mixture of n-butenes. J Ind Eng Chem 18(4):1353–1365
2. Pérez D et al (2015) Study of the selective hydrogenation of 1,3-butadiene in three types of
industrial reactors. Fuel 149:34–45
3. Méndez FJ et al (2017) Selective hydrogenation of 1,3-butadiene in the presence of 1-butene
under liquid phase conditions using structured catalysts. Catal Today 289:151–161
4. Liu D et al (2018) Theoretical investigation of selective hydrogenation of 1,3-butadiene on Pt
doping Cu nanoparticles. Appl Surf Sci 456:59–68
5. Aguilar-Tapia A et al (2016) Selective hydrogenation of 1,3-butadiene over bimetallic Au-Ni/
TiO2 catalysts prepared by deposition-precipitation with urea. J Catal 344:515–523
6. Lozano L et al (2013) Influence of toluene on the catalytic activity of NiPdCe catalyst for
selective hydrogenation of 1,3-butadiene. Fuel 110:76–82
7. Ardiaca NO et al (2001) Experimental procedure for kinetic studies on egg-shell catalysts.
The case of liquid-phase hydrogenation of 1,3-butadiene and n-butenes on commercial Pd
catalysts. Catal Today 64(3–4):205–215
8. Boitiaux JP et al (1987) Hydrogenation of unsaturated hydrocarbons in liquid phase on palladium, platinum and rhodium catalysts. III. Quantitative selectivity ranking of platinum,
palladium and rhodium in the hydrogenation of 1-butene, 1,3-butadiene and 1-butyne using a
single reaction scheme. Appl Catal 35(2):193–209
9. Boitiaux JP et al (1987) Liquid phase hydrogenation of unsaturated hydrocarbons on
palladium, platinum and rhodium catalysts. Part I: kinetic study of 1-butene, 1,3-butadiene
and 1-butyne hydrogenation on platinum. Appl Catal 32:145–168
10. Boitiaux JP et al (1987) Liquid phase hydrogenation of unsaturated hydrocarbons on palladium, platinum and rhodium catalysts. Part II: kinetic study of 1-butene, 1,3-butadiene and
1-butyne hydrogenation on rhodium; comparison with platinum and palladium. Appl Catal
32:169–183
11. Gaube J, Klein HF (2014) Kinetics and mechanism of butene isomerization/hydrogenation
and of 1,3-butadiene hydrogenation on palladium. Appl Catal A Gen 470:361–368
12. Goetz J et al (1996) Kinetic aspects of selectivity and stereoselectivity for the hydrogenation
of buta-1,3-diene over a palladium catalyst. Ind Eng Chem Res 35(3):703–711
13. Goetz J et al (1996) Kinetics of buta-1,3-diene hydrogenation over palladium catalysts. Chem
Eng Sci 51(11):2879–2884
14. Goetz J et al (1997) Kinetics of buta-1,3-diene hydrogenation over 0.5% Pd/γ-Al2O3 catalyst.
Chem Eng Technol 20(2):138–143
15. Goetz J et al (1996) Low-loaded Pd/α-Al2O3 catalysts: influence of metal particle morphology on hydrogenation of buta-1,3-diene and hydrogenation and isomerization of but-1-ene. J
Catal 164(2):369–377
16. Horiuti I, Polanyi M (1934) Exchange reactions of hydrogen on metallic catalysts. Trans
Faraday Soc 30:1164–1172
17. Santiso EE et al (2008) Isomerization kinetics of small hydrocarbons in confinement.
Adsorption 14(2–3):181–188
18. Bates AJ et al (1970) The hydrogenation of akladienes. Part IV. The reaction of buta-1,3diene with deuterium catalysed by rhodium, palladium, and platinum. J Chem Soc AInorgan
Phys Theor:2435–2441
P. R. Selvakannan et al.