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107. Freyhardt CC, Tsapatsis M, Lobo RF, Balkus KJ, Davis ME Jr (1996) A high-silica zeolite
with a 14-tetrahedral-atom pore opening. Nature 381:295–298
108. Davis ME, Saldarriaga C, Montes C, Garces J, Crowder C (1988) A molecular sieve with
eighteen-membered rings. Nature 331:698–699
109. Strohmaier KG, Vaughan DEW (2003) Structure of the first silicate molecular sieve with
18-ring pore openings, ECR-34. J Am Chem Soc 125:16035–16039
110. Verboekend D, Pérez-Ramírez J (2011) Design of hierarchical zeolite catalysts by desilication. Catal Sci Technol 1(6):879–890
111. Verboekend D, Thomas K, Milina M, Mitchell S, Pérez-Ramírez J, Gilson JP (2011) Towards
more efficient monodimensional zeolite catalysts: N-alkane hydro-isomerisation on hierarchical ZSM-22. Catal Sci Technol 1(8):1331–1335
112. Chen LH, Li XY, Rooke JC, Zhang YH, Yang XY, Tang Y et al (2012) Hierarchically
structured zeolites: synthesis, mass transport properties and applications. J Mater Chem
22(34):17381–17403
113. de Jong KP, Zecevic J, Friedrich H, de Jongh PE, Bulut M, van Donk S, Kenmogne R, Finiels
A, Hulea V, Fajula F (2010) Zeolite Y crystals with trimodal porosity as ideal hydrocracking
catalysts. Angew Chem 122(52):10272–10276
114. de Jong KP, Zecevic J, Friedrich H, de Jongh PE, Bulut M, van Donk S, Kenmogne R, Finiels
A, Hulea V, Fajula F (2010) Zeolite Y crystals with trimodal porosity as ideal hydrocracking
catalysts. Angew Chem Int Ed 49(52):10074–10078
115. Rosalie Starling (2015) Hydrocarbon engineering energy global. https://www.energyglobal.com
116. Van Broekhoven EH, Mas Cabre FR, Bogaard P, Klaver G, Vonhof M (1999) Process for
alkylating hydrocarbons. US Patent 5986158
117. Buchold H, Dropsch H, Eberhardt J (2002) Proceedings of the world petroleum congress
2002, Rio de Janeiro
118. Shuang H, Lian-hai L (2006) Highly regioselective hydrogenation of biphenyl to phenylcyclohexane. In: The proceedings of the 3rd international conference on functional molecules
119. Chang CD, Cheng JC, Helton TE, Steckel MA, Stevenson SA (2000) Hydroalkylation of
aromatic hydrocarbons. US Patent 6037513
120. Chen T, Cheng JC, Helton TE, Buchanan JS (2011) Process for the production cyclohexylbenzene. US Patent 7910779
121. Chen T, Cheng JC, Benitez FM, Helton TE, Stanat JE (2012) Process for the production
cyclohexylbenzene. US Patent 8106243
122. Cheng J. C, Chen T, Ghosh P (2012) Process for production cyclohexylbenzene, US
Patent 8178728
123. Jun Q, Komura K, Kubota Y, Sugi Y (2007) Synthesis of cyclohexylbenzene by hydroalkylation of benzene over Pd/Hβ binary catalyst. Chin J Catal 28:246–250
124. Chen TJ, Benitez FM, Cheng JC, Stanat JE, Buchanan JS (2011) Process for the production
of cyclohexylbenzene. US Patent 7906685
125. Corson BB, Ipatieff VN (1937) Influence of cyclohexene concentration in the alkylation of benzene by cyclohexene. Dealkylation of cyclohexylbenzenes. J Am Chem Soc
59(4):645–647
126. Slaugh LH (1968) Hydrogenation of benzene to phenylcyclohexane with supported alkali
metal catalysts. Tetrahedron 24:4523–4533
127. Fahy J, Trimm DL, Cookson DJ (2001) Four component catalysis for the hydroalkylation of
benzene to cyclohexyl benzene. Appl Catal A Gen 11:259–268
128. Kumar SAK, John M, Pai SM, Ghosh S, Newalkar BL, Pant KK (2017) Selective hydroalkylation of benzene over palladium supported Y-zeolite: effect of metal acid balance. J Mol Catal
442:27–38
129. Becker CL, Nair H, Lattner JR, Kuechler KH (2016) Process for producing cyclohexylbenzene. US Patent 9458067B2
130. Truffault R (1934) Bull Soc Chim 1:391
S. M. Pai et al.
107. Freyhardt CC, Tsapatsis M, Lobo RF, Balkus KJ, Davis ME Jr (1996) A high-silica zeolite
with a 14-tetrahedral-atom pore opening. Nature 381:295–298
108. Davis ME, Saldarriaga C, Montes C, Garces J, Crowder C (1988) A molecular sieve with
eighteen-membered rings. Nature 331:698–699
109. Strohmaier KG, Vaughan DEW (2003) Structure of the first silicate molecular sieve with
18-ring pore openings, ECR-34. J Am Chem Soc 125:16035–16039
110. Verboekend D, Pérez-Ramírez J (2011) Design of hierarchical zeolite catalysts by desilication. Catal Sci Technol 1(6):879–890
111. Verboekend D, Thomas K, Milina M, Mitchell S, Pérez-Ramírez J, Gilson JP (2011) Towards
more efficient monodimensional zeolite catalysts: N-alkane hydro-isomerisation on hierarchical ZSM-22. Catal Sci Technol 1(8):1331–1335
112. Chen LH, Li XY, Rooke JC, Zhang YH, Yang XY, Tang Y et al (2012) Hierarchically
structured zeolites: synthesis, mass transport properties and applications. J Mater Chem
22(34):17381–17403
113. de Jong KP, Zecevic J, Friedrich H, de Jongh PE, Bulut M, van Donk S, Kenmogne R, Finiels
A, Hulea V, Fajula F (2010) Zeolite Y crystals with trimodal porosity as ideal hydrocracking
catalysts. Angew Chem 122(52):10272–10276
114. de Jong KP, Zecevic J, Friedrich H, de Jongh PE, Bulut M, van Donk S, Kenmogne R, Finiels
A, Hulea V, Fajula F (2010) Zeolite Y crystals with trimodal porosity as ideal hydrocracking
catalysts. Angew Chem Int Ed 49(52):10074–10078
115. Rosalie Starling (2015) Hydrocarbon engineering energy global. https://www.energyglobal.com
116. Van Broekhoven EH, Mas Cabre FR, Bogaard P, Klaver G, Vonhof M (1999) Process for
alkylating hydrocarbons. US Patent 5986158
117. Buchold H, Dropsch H, Eberhardt J (2002) Proceedings of the world petroleum congress
2002, Rio de Janeiro
118. Shuang H, Lian-hai L (2006) Highly regioselective hydrogenation of biphenyl to phenylcyclohexane. In: The proceedings of the 3rd international conference on functional molecules
119. Chang CD, Cheng JC, Helton TE, Steckel MA, Stevenson SA (2000) Hydroalkylation of
aromatic hydrocarbons. US Patent 6037513
120. Chen T, Cheng JC, Helton TE, Buchanan JS (2011) Process for the production cyclohexylbenzene. US Patent 7910779
121. Chen T, Cheng JC, Benitez FM, Helton TE, Stanat JE (2012) Process for the production
cyclohexylbenzene. US Patent 8106243
122. Cheng J. C, Chen T, Ghosh P (2012) Process for production cyclohexylbenzene, US
Patent 8178728
123. Jun Q, Komura K, Kubota Y, Sugi Y (2007) Synthesis of cyclohexylbenzene by hydroalkylation of benzene over Pd/Hβ binary catalyst. Chin J Catal 28:246–250
124. Chen TJ, Benitez FM, Cheng JC, Stanat JE, Buchanan JS (2011) Process for the production
of cyclohexylbenzene. US Patent 7906685
125. Corson BB, Ipatieff VN (1937) Influence of cyclohexene concentration in the alkylation of benzene by cyclohexene. Dealkylation of cyclohexylbenzenes. J Am Chem Soc
59(4):645–647
126. Slaugh LH (1968) Hydrogenation of benzene to phenylcyclohexane with supported alkali
metal catalysts. Tetrahedron 24:4523–4533
127. Fahy J, Trimm DL, Cookson DJ (2001) Four component catalysis for the hydroalkylation of
benzene to cyclohexyl benzene. Appl Catal A Gen 11:259–268
128. Kumar SAK, John M, Pai SM, Ghosh S, Newalkar BL, Pant KK (2017) Selective hydroalkylation of benzene over palladium supported Y-zeolite: effect of metal acid balance. J Mol Catal
442:27–38
129. Becker CL, Nair H, Lattner JR, Kuechler KH (2016) Process for producing cyclohexylbenzene. US Patent 9458067B2
130. Truffault R (1934) Bull Soc Chim 1:391
S. M. Pai et al.