68
derivatives (279, 280, and 306), six cacalol derivatives (322, 323, 332, 335, 547, and
548), bakkane (635), as well as two dimers (571 and 622). Compound 571 was named
virgaurin A [45], but the same name was already used in Refs. [12, 173]. Accordingly,
the name in Ref. [45] should be changed. Virgaurin C (622) is a dimer consisting of
cacalol-type and bicyclic compound units. Therefore, this sample was grouped as
H/C, a mixture of both types [45]. Sample 17 produced 6-acetoxyeuryopsyn (251),
neoadenostylone (283), and virgaurenone A (274) as major constituents, and this sample was grouped to the H/N/V type. Their derivatives, virgaurenone B (273), virgaurenospirolide B (639), 6β-acetoxyeremophil-1(10)-en-9-one (278), and
11βH-6β-acetoxy-7α,8α-epoxy-2-oxoeremophil-1(10)-en-12,8β-olide (531) were
Fig. 6 Noreremophilanes (1)
M. Tori and C. Kuroda
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