higher temperature. Decrease in the intensity of the amide I
0 mode indicates timeand potential-dependent reorientation of the collagen helices in the adsorbed film
leading to a continuous increase in the film thickness and slow dissolution of the
protein film [48].
First in situ PM IRRAS studies of protein films provide valuable information
concerning the structure of an adsorbed protein and its changes caused by external
impulses such as electric potential or temperature. It is an excellent experimental
method to elucidate in situ the secondary structure of a protein and its changes
caused by the adsorption process.
References
1. Chen EM, Buckingham MJ, Robins JL (1977) Potential energy of an isolated gold atom on the
(100) surface of alkali halide crystals. Surf Sci 67:285–298
2. Parsons R (1975) A primitive four state model for solvent at the electrode-solution interface. J
Electroanal Chem 59:229–237
3. Parsons R (1964) The description of adsorption at electrodes. J Electroanal Chem 7:136–157
4. Lipkowski J, Shi Z, Chen A, Pettinger B, Bilger C (1998) Ionic adsorption at the Au(111)
electrode. Electrochim Acta 43:2875–2888
5. Pajkossy T, Wandlowski T, Kolb DM (1996) Impedance spectra of anion adsorption on gold
single crystal electrodes. J Electroanal Chem 414:209–220
6. Valette G, Heamelin A, Parsons R (1978) Specific adsorption on silver single crystals in
aqueous solutions. Z Phys Chem 113:71–89
7. Valette G (1982) Double layer on silver single crystal electrodes in contact with electrolytes
having anions which are slightly specifically adsorbed Part II. The (100) face. J Electroanal
Chem 138:37–54
8. Hamm UW, Kramer D, Zhai RS, Kolb DM (1996) The pzc of Au(111) and Pt(111) in a
perchloric acid solution: an ex situ approach to the immersion technique. J Electroanal Chem
414:85–89
9. Silva F, Sottomayor MJ, Martins A (1994) Study of electrochemical properties of Au(210)
face electrode in nitrate solutions. Electrochim Acta 39:491–496
10. Stolberg L, Richer J, Lipkowski J (1986) Adsorption of pyridine at the polycrystalline goldsolution interface. J Electroanal Chem 207:213–234
11. Stolberg L, Morin S, Lipkowski J, Irish DE (1991) Adsorption of pyridine at the Au(111)solution interface. J Electroanal Chem 307:241–262
12. Richer J, Lipkowski J (1985) Measurement of physical adsorption of organic species at solid
electrodes. J Electrochem Soc 133:121–128
13. Bizzotto D, Pettinger B (1999) Fluorescence imaging studies of the electrochemical adsorption/desorption of octadecanol. Langmuir 15:8309–8314
14. Musgrove A, Bridges CR, Sammis GM, Bizzotto D (2013) Potential-dependent interaction of
DOPC liposomes with an octadecanol-covered Au(111) surface using electrochemical
methods coupled with in situ fluorescence microscopy. Langmuir 29:3347–3360
15. Nelson A, Benton A (1986) Phospholipid monolayers at the mercury/water interface. J
Electroanal Chem 202:253–270
16. Brosseau CL, Sheepwash E, Burgess IJ, Cholewa E, Roscoe SG, Lipkowski J (2007) Adsorption of N-decyl-N,N,N-trimethylammonium triflate (DeTATf), a cationic surfactant, on the Au
(111) electrode surface. Langmuir 23:1784–1791
17. Bełtowska-Brzezinska M, Łuczak T, Holze R (1998) On adsorption of monohydric alcohols
and diols at sp and sd metal electrodes. Surf Sci 418:281–294
90
3 In Situ PM IRRAS Studies of Redox-Inactive Molecular Films Adsorbed on. . .
0 mode indicates timeand potential-dependent reorientation of the collagen helices in the adsorbed film
leading to a continuous increase in the film thickness and slow dissolution of the
protein film [48].
First in situ PM IRRAS studies of protein films provide valuable information
concerning the structure of an adsorbed protein and its changes caused by external
impulses such as electric potential or temperature. It is an excellent experimental
method to elucidate in situ the secondary structure of a protein and its changes
caused by the adsorption process.
References
1. Chen EM, Buckingham MJ, Robins JL (1977) Potential energy of an isolated gold atom on the
(100) surface of alkali halide crystals. Surf Sci 67:285–298
2. Parsons R (1975) A primitive four state model for solvent at the electrode-solution interface. J
Electroanal Chem 59:229–237
3. Parsons R (1964) The description of adsorption at electrodes. J Electroanal Chem 7:136–157
4. Lipkowski J, Shi Z, Chen A, Pettinger B, Bilger C (1998) Ionic adsorption at the Au(111)
electrode. Electrochim Acta 43:2875–2888
5. Pajkossy T, Wandlowski T, Kolb DM (1996) Impedance spectra of anion adsorption on gold
single crystal electrodes. J Electroanal Chem 414:209–220
6. Valette G, Heamelin A, Parsons R (1978) Specific adsorption on silver single crystals in
aqueous solutions. Z Phys Chem 113:71–89
7. Valette G (1982) Double layer on silver single crystal electrodes in contact with electrolytes
having anions which are slightly specifically adsorbed Part II. The (100) face. J Electroanal
Chem 138:37–54
8. Hamm UW, Kramer D, Zhai RS, Kolb DM (1996) The pzc of Au(111) and Pt(111) in a
perchloric acid solution: an ex situ approach to the immersion technique. J Electroanal Chem
414:85–89
9. Silva F, Sottomayor MJ, Martins A (1994) Study of electrochemical properties of Au(210)
face electrode in nitrate solutions. Electrochim Acta 39:491–496
10. Stolberg L, Richer J, Lipkowski J (1986) Adsorption of pyridine at the polycrystalline goldsolution interface. J Electroanal Chem 207:213–234
11. Stolberg L, Morin S, Lipkowski J, Irish DE (1991) Adsorption of pyridine at the Au(111)solution interface. J Electroanal Chem 307:241–262
12. Richer J, Lipkowski J (1985) Measurement of physical adsorption of organic species at solid
electrodes. J Electrochem Soc 133:121–128
13. Bizzotto D, Pettinger B (1999) Fluorescence imaging studies of the electrochemical adsorption/desorption of octadecanol. Langmuir 15:8309–8314
14. Musgrove A, Bridges CR, Sammis GM, Bizzotto D (2013) Potential-dependent interaction of
DOPC liposomes with an octadecanol-covered Au(111) surface using electrochemical
methods coupled with in situ fluorescence microscopy. Langmuir 29:3347–3360
15. Nelson A, Benton A (1986) Phospholipid monolayers at the mercury/water interface. J
Electroanal Chem 202:253–270
16. Brosseau CL, Sheepwash E, Burgess IJ, Cholewa E, Roscoe SG, Lipkowski J (2007) Adsorption of N-decyl-N,N,N-trimethylammonium triflate (DeTATf), a cationic surfactant, on the Au
(111) electrode surface. Langmuir 23:1784–1791
17. Bełtowska-Brzezinska M, Łuczak T, Holze R (1998) On adsorption of monohydric alcohols
and diols at sp and sd metal electrodes. Surf Sci 418:281–294
90
3 In Situ PM IRRAS Studies of Redox-Inactive Molecular Films Adsorbed on. . .