Fig. 4.4 (a) Structure of
pyridine modified poly(allyl
amine) Os
(II) (CN) 5
complex; (b, c) PM IRRA
spectra of the layer by layer
deposited (PAH-OsCN/
PAA)4 PAH-OsCN film on
the Au electrode surface (b)
in the ν(CN) stretching
mode region in 0.05 M NaF
(c) in the ν(NO) stretching
mode region in 0.05 M NaF
and 0.01 M NaNO 3 at the
following potentials: 0.40,
0.45, 0.50, 0.55, 0.60, 0.65,
0,7 and 0.75 V versus
Ag/AgCl. Copied with
permission from [3]
4.1 In Situ PM IRRAS Studies of Redox-Active Molecular Films...
103
pyridine modified poly(allyl
amine) Os
(II) (CN) 5
complex; (b, c) PM IRRA
spectra of the layer by layer
deposited (PAH-OsCN/
PAA)4 PAH-OsCN film on
the Au electrode surface (b)
in the ν(CN) stretching
mode region in 0.05 M NaF
(c) in the ν(NO) stretching
mode region in 0.05 M NaF
and 0.01 M NaNO 3 at the
following potentials: 0.40,
0.45, 0.50, 0.55, 0.60, 0.65,
0,7 and 0.75 V versus
Ag/AgCl. Copied with
permission from [3]
4.1 In Situ PM IRRAS Studies of Redox-Active Molecular Films...
103
