Topics in Current Chemistry (2018) 376:41
1 3
47. Ma S, Sadakiyo M, Heima M, Luo R, Haasch RT, Gold JI, Yamauchi M, Kenis PJA (2017) Electroreduction of carbon dioxide to hydrocarbons using bimetallic Cu–Pd catalysts with different mixing patterns. J Am Chem Soc 139:47–50
48. Singh S, Gautam RK, Malik K, Verma A (2017) Ag–Co bimetallic catalyst for electrochemical
reduction of CO 2 to value added products. J CO2 Util 18:139–146
49. Clark EL, Hahn C, Jaramillo TF, Bell AT (2017) Electrochemical CO 2 reduction over compressively
strained CuAg surface alloys with enhanced multi-carbon oxygenate selectivity. J Am Chem Soc
139:15848–15857
50. Monzo J, Malewski Y, Kortlever R, Vidal-Iglesias FJ, Solla-Gullon J, Koper MTM, Rodriguez P
(2015) Enhanced electrocatalytic activity of Au@Cu core@shell nanoparticles towards CO 2 reduction. J Mater Chem A 3:23690–23698
51. Chang Z-Y, Huo S-J, He J-M, Fang J-H (2017) Facile synthesis of Cu–Ag bimetallic electrocatalyst
with prior C2 products at lower overpotential for CO 2 electrochemical reduction. Surf Interfaces
6:116–121
52. Zhang S, Kang P, Bakir M, Lapides AM, Dares CJ, Meyer TJ (2015) Polymer-supported CuPd
nanoalloy as a synergistic catalyst for electrocatalytic reduction of carbon dioxide to methane. Proc
Natl Acad Sci 112:15809–15814
53. Hoang TTH, Verma S, Ma S, Fister TT, Timoshenko J, Frenkel AI, Kenis PJA, Gewirth AA (2018)
Nanoporous copper-silver alloys by additive-controlled electrodeposition for the selective electroreduction of CO 2 to ethylene and ethanol. J Am Chem Soc 140:5791–5797
54. Peterson AA, Nørskov JK (2012) Activity descriptors for CO 2 electroreduction to methane on transition-metal catalysts. J Phys Chem Lett 3:251–258
55. Kuhl KP, Hatsukade T, Cave ER, Abram DN, Kibsgaard J, Jaramillo TF (2014) Electrocatalytic
conversion of carbon dioxide to methane and methanol on transition metal surfaces. J Am Chem Soc
136:14107–14113
56. Hansen HA, Shi C, Lausche AC, Peterson AA, Norskov JK (2016) Bifunctional alloys for the electroreduction of CO 2 and CO. Phys Chem Chem Phys 18:9194–9201
57. Nie X, Esopi MR, Janik MJ, Asthagiri A (2013) Selectivity of CO 2 reduction on copper electrodes:
the role of the kinetics of elementary steps. Angew Chem Int Ed 52:2459–2462
58. Nie X, Wang H, Janik MJ, Chen Y, Guo X, Song C (2017) Mechanistic insight into C–C coupling
over Fe–Cu bimetallic catalysts in CO 2 hydrogenation. J Phys Chem C 121:13164–13174
59. Garza AJ, Bell AT, Head-Gordon M (2018) Mechanism of CO 2 reduction at copper surfaces: pathways to C2 products. ACS Catal 8:1490–1499
60. Kuhl KP, Cave ER, Abram DN, Jaramillo TF (2012) New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces. Energ Environ Sci 5:7050–7059
61. Grote J-P, Zeradjanin AR, Cherevko S, Savan A, Breitbach B, Ludwig A, Mayrhofer KJJ (2016)
Screening of material libraries for electrochemical CO 2 reduction catalysts—improving selectivity
of Cu by mixing with Co. J Catal 343:248–256
62. Ma S, Sadakiyo M, Luo R, Heima M, Yamauchi M, Kenis PJA (2016) One-step electrosynthesis of
ethylene and ethanol from CO 2 in an alkaline electrolyzer. J Power Sources 301:219–228
63. Manthiram K, Beberwyck BJ, Alivisatos AP (2014) Enhanced electrochemical methanation of carbon dioxide with a dispersible nanoscale copper catalyst. J Am Chem Soc 136:13319–13325
64. Luc W, Collins C, Wang S, Xin H, He K, Kang Y, Jiao F (2017) Ag–Sn bimetallic catalyst with a
core-shell structure for CO 2 reduction. J Am Chem Soc 139:1885–1893
65. Cai F, Gao D, Si R, Ye Y, He T, Miao S, Wang G, Bao X (2017) Effect of metal deposition sequence
in carbon-supported Pd–Pt catalysts on activity towards CO 2 electroreduction to formate. Electrochem Commun 76:1–5
66. Kortlever R, Peters I, Koper S, Koper MTM (2015) Electrochemical CO 2 reduction to formic acid at
low overpotential and with high faradaic efficiency on carbon-supported bimetallic Pd–Pt nanoparticles. ACS Catal 5:3916–3923
67. Kortlever R, Balemans C, Kwon Y, Koper MTM (2015) Electrochemical CO 2 reduction to formic
acid on a Pd-based formic acid oxidation catalyst. Catal Today 244:58–62
68. Bai X, Chen W, Zhao C, Li S, Song Y, Ge R, Wei W, Sun Y (2017) Exclusive formation of formic
acid from CO 2 electroreduction by a tunable Pd–Sn alloy. Angew Chem Int Ed 56:12219–12223
69. Furuya N, Yamazaki T, Shibata M (1997) High performance RuPd catalysts for CO 2 reduction at
gas-diffusion electrodes. J Electroanal Chem 431:39–41
70. Lee S, Park G, Lee J (2017) Importance of Ag–Cu biphasic boundaries for selective electrochemical
reduction of CO 2 to ethanol. ACS Catal 7:8594–8604
Reprinted from the journal
124
1 3
47. Ma S, Sadakiyo M, Heima M, Luo R, Haasch RT, Gold JI, Yamauchi M, Kenis PJA (2017) Electroreduction of carbon dioxide to hydrocarbons using bimetallic Cu–Pd catalysts with different mixing patterns. J Am Chem Soc 139:47–50
48. Singh S, Gautam RK, Malik K, Verma A (2017) Ag–Co bimetallic catalyst for electrochemical
reduction of CO 2 to value added products. J CO2 Util 18:139–146
49. Clark EL, Hahn C, Jaramillo TF, Bell AT (2017) Electrochemical CO 2 reduction over compressively
strained CuAg surface alloys with enhanced multi-carbon oxygenate selectivity. J Am Chem Soc
139:15848–15857
50. Monzo J, Malewski Y, Kortlever R, Vidal-Iglesias FJ, Solla-Gullon J, Koper MTM, Rodriguez P
(2015) Enhanced electrocatalytic activity of Au@Cu core@shell nanoparticles towards CO 2 reduction. J Mater Chem A 3:23690–23698
51. Chang Z-Y, Huo S-J, He J-M, Fang J-H (2017) Facile synthesis of Cu–Ag bimetallic electrocatalyst
with prior C2 products at lower overpotential for CO 2 electrochemical reduction. Surf Interfaces
6:116–121
52. Zhang S, Kang P, Bakir M, Lapides AM, Dares CJ, Meyer TJ (2015) Polymer-supported CuPd
nanoalloy as a synergistic catalyst for electrocatalytic reduction of carbon dioxide to methane. Proc
Natl Acad Sci 112:15809–15814
53. Hoang TTH, Verma S, Ma S, Fister TT, Timoshenko J, Frenkel AI, Kenis PJA, Gewirth AA (2018)
Nanoporous copper-silver alloys by additive-controlled electrodeposition for the selective electroreduction of CO 2 to ethylene and ethanol. J Am Chem Soc 140:5791–5797
54. Peterson AA, Nørskov JK (2012) Activity descriptors for CO 2 electroreduction to methane on transition-metal catalysts. J Phys Chem Lett 3:251–258
55. Kuhl KP, Hatsukade T, Cave ER, Abram DN, Kibsgaard J, Jaramillo TF (2014) Electrocatalytic
conversion of carbon dioxide to methane and methanol on transition metal surfaces. J Am Chem Soc
136:14107–14113
56. Hansen HA, Shi C, Lausche AC, Peterson AA, Norskov JK (2016) Bifunctional alloys for the electroreduction of CO 2 and CO. Phys Chem Chem Phys 18:9194–9201
57. Nie X, Esopi MR, Janik MJ, Asthagiri A (2013) Selectivity of CO 2 reduction on copper electrodes:
the role of the kinetics of elementary steps. Angew Chem Int Ed 52:2459–2462
58. Nie X, Wang H, Janik MJ, Chen Y, Guo X, Song C (2017) Mechanistic insight into C–C coupling
over Fe–Cu bimetallic catalysts in CO 2 hydrogenation. J Phys Chem C 121:13164–13174
59. Garza AJ, Bell AT, Head-Gordon M (2018) Mechanism of CO 2 reduction at copper surfaces: pathways to C2 products. ACS Catal 8:1490–1499
60. Kuhl KP, Cave ER, Abram DN, Jaramillo TF (2012) New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces. Energ Environ Sci 5:7050–7059
61. Grote J-P, Zeradjanin AR, Cherevko S, Savan A, Breitbach B, Ludwig A, Mayrhofer KJJ (2016)
Screening of material libraries for electrochemical CO 2 reduction catalysts—improving selectivity
of Cu by mixing with Co. J Catal 343:248–256
62. Ma S, Sadakiyo M, Luo R, Heima M, Yamauchi M, Kenis PJA (2016) One-step electrosynthesis of
ethylene and ethanol from CO 2 in an alkaline electrolyzer. J Power Sources 301:219–228
63. Manthiram K, Beberwyck BJ, Alivisatos AP (2014) Enhanced electrochemical methanation of carbon dioxide with a dispersible nanoscale copper catalyst. J Am Chem Soc 136:13319–13325
64. Luc W, Collins C, Wang S, Xin H, He K, Kang Y, Jiao F (2017) Ag–Sn bimetallic catalyst with a
core-shell structure for CO 2 reduction. J Am Chem Soc 139:1885–1893
65. Cai F, Gao D, Si R, Ye Y, He T, Miao S, Wang G, Bao X (2017) Effect of metal deposition sequence
in carbon-supported Pd–Pt catalysts on activity towards CO 2 electroreduction to formate. Electrochem Commun 76:1–5
66. Kortlever R, Peters I, Koper S, Koper MTM (2015) Electrochemical CO 2 reduction to formic acid at
low overpotential and with high faradaic efficiency on carbon-supported bimetallic Pd–Pt nanoparticles. ACS Catal 5:3916–3923
67. Kortlever R, Balemans C, Kwon Y, Koper MTM (2015) Electrochemical CO 2 reduction to formic
acid on a Pd-based formic acid oxidation catalyst. Catal Today 244:58–62
68. Bai X, Chen W, Zhao C, Li S, Song Y, Ge R, Wei W, Sun Y (2017) Exclusive formation of formic
acid from CO 2 electroreduction by a tunable Pd–Sn alloy. Angew Chem Int Ed 56:12219–12223
69. Furuya N, Yamazaki T, Shibata M (1997) High performance RuPd catalysts for CO 2 reduction at
gas-diffusion electrodes. J Electroanal Chem 431:39–41
70. Lee S, Park G, Lee J (2017) Importance of Ag–Cu biphasic boundaries for selective electrochemical
reduction of CO 2 to ethanol. ACS Catal 7:8594–8604
Reprinted from the journal
124