1 3
Topics in Current Chemistry (2018) 376:41
24. Zhao Z, Chen Z, Lu G (2017) Computational discovery of nickel-based catalysts for CO 2 reduction to formic acid. J Phys Chem C 121:20865–20870
25. Takashima T, Suzuki T, Irie H (2017) Electrochemical carbon dioxide reduction on coppermodified palladium nanoparticles synthesized by underpotential deposition. Electrochim Acta
229:415–421
26. Yin Z, Gao D, Yao S, Zhao B, Cai F, Lin L, Tang P, Zhai P, Wang G, Ma D, Bao X (2016)
Highly selective palladium-copper bimetallic electrocatalysts for the electrochemical reduction
of CO 2 to CO. Nano Energy 27:35–43
27. Zhao X, Luo B, Long R, Wang C, Xiong Y (2015) Composition-dependent activity of Cu–Pt
alloy nanocubes for electrocatalytic CO 2 reduction. J Mater Chem A 3:4134–4138
28. Sarfraz S, Garcia-Esparza AT, Jedidi A, Cavallo L, Takanabe K (2016) Cu–Sn bimetallic catalyst
for selective aqueous electroreduction of CO 2 to CO. ACS Catal 6:2842–2851
29. Katoh A, Uchida H, Shibata M, Watanabe M (1994) Design of electrocatalyst for CO 2 reduction.
V. Effect of the microcrystalline structures of Cu–Sn and Cu–Zn alloys on the electrocatalysis of
CO 2 reduction. J Electrochem Soc 8:2054–2058
30. Kim D, Xie C, Becknell N, Yu Y, Karamad M, Chan K, Crumlin EJ, Nørskov JK, Yang P (2017)
Electrochemical activation of CO 2 through atomic ordering transformations of AuCu nanoparticles. J Am Chem Soc 139:8329–8336
31. Lee H, Kim S-K, Ahn SH (2017) Electrochemical preparation of Ag/Cu and Au/Cu foams for
electrochemical conversion of CO 2 to CO. J Ind Eng Chem 54:218–225
32. Ma M, Hansen HA, Valenti M, Wang Z, Cao A, Dong M, Smith WA (2017) Electrochemical
reduction of CO 2 on compositionally variant Au–Pt bimetallic thin films. Nano Energy 42:51–57
33. Morimoto M, Takatsuji Y, Yamasaki R, Hashimoto H, Nakata I, Sakakura T, Haruyama T (2017)
Electrodeposited Cu–Sn alloy for electrochemical CO 2 reduction to CO/HCOO
− . Electrocatalysis 9:323–332
34. Yoshio H, Akira M, Shin-ya I (1990) Enhanced evolution of CO and suppressed formation of
hydrocarbons in electroreduction of CO 2 at a copper electrode modified with cadmium. Chem
Lett 19:1231–1234
35. Rasul S, Anjum DH, Jedidi A, Minenkov Y, Cavallo L, Takanabe K (2015) A highly selective
copper–indium bimetallic electrocatalyst for the electrochemical reduction of aqueous CO 2 to
CO. Angew Chem Int Ed 54:2146–2150
36. He J, Dettelbach KE, Salvatore DA, Li T, Berlinguette CP (2017) High-throughput synthesis of
mixed-metal electrocatalysts for CO 2 reduction. Angew Chem Int Ed 56:6068–6072
37. Kim D, Resasco J, Yu Y, Asiri AM, Yang P (2014) Synergistic geometric and electronic effects
for electrochemical reduction of carbon dioxide using gold–copper bimetallic nanoparticles. Nat
Commun 5:4948
38. Li Q, Fu J, Zhu W, Chen Z, Shen B, Wu L, Xi Z, Wang T, Lu G, J-j Zhu, Sun S (2017) Tuning
Sn-catalysis for electrochemical reduction of CO 2 to CO via the core/shell Cu/SnO 2 structure. J
Am Chem Soc 139:4290–4293
39. Sun K, Cheng T, Wu L, Hu Y, Zhou J, Maclennan A, Jiang Z, Gao Y, Goddard WA, Wang Z
(2017) Ultrahigh mass activity for carbon dioxide reduction enabled by Gold–iron Core–Shell
nanoparticles. J Am Chem Soc 139:15608–15611
40. Watanabe M, Shibata M, Kato A, Azuma M, Sakata T (1991) Design of alloy electrocatalysts for
CO 2 reduction: III. The selective and reversible reduction of on Cu alloy electrodes. J Electrochem Soc 138:3382–3389
41. Yoshio H, Akira M, Shin-ya I, Yuzuru Y, Osamu K (1989) Nickel and iron modified copper electrode for electroreduction of CO 2 by in situ electrodeposition. Chem Lett 18:1567–1570
42. Luc W, Jiang C, Chen JG, Jiao F (2018) Role of surface oxophilicity in copper-catalyzed water
dissociation. ACS Catal 8:9327–9333
43. Hammer B, Morikawa Y, Nørskov JK (1996) CO chemisorption at metal surfaces and overlayers.
Phys Rev Lett 76:2141–2144
44. Alayoglu S, Nilekar AU, Mavrikakis M, Eichhorn B (2008) Ru–Pt core–shell nanoparticles for
preferential oxidation of carbon monoxide in hydrogen. Nat Mater 7:333
45. Gorzkowski MT, Lewera A (2015) Probing the limits of d-band center theory: electronic
and electrocatalytic properties of Pd-shell–Pt-core nanoparticles. The J Phys Chem C
119:18389–18395
46. Chen JG, Menning CA, Zellner MB (2008) Monolayer bimetallic surfaces: experimental and theoretical studies of trends in electronic and chemical properties. Surf Sci Rep 63:201–254
Reprinted from the journal
123
Topics in Current Chemistry (2018) 376:41
24. Zhao Z, Chen Z, Lu G (2017) Computational discovery of nickel-based catalysts for CO 2 reduction to formic acid. J Phys Chem C 121:20865–20870
25. Takashima T, Suzuki T, Irie H (2017) Electrochemical carbon dioxide reduction on coppermodified palladium nanoparticles synthesized by underpotential deposition. Electrochim Acta
229:415–421
26. Yin Z, Gao D, Yao S, Zhao B, Cai F, Lin L, Tang P, Zhai P, Wang G, Ma D, Bao X (2016)
Highly selective palladium-copper bimetallic electrocatalysts for the electrochemical reduction
of CO 2 to CO. Nano Energy 27:35–43
27. Zhao X, Luo B, Long R, Wang C, Xiong Y (2015) Composition-dependent activity of Cu–Pt
alloy nanocubes for electrocatalytic CO 2 reduction. J Mater Chem A 3:4134–4138
28. Sarfraz S, Garcia-Esparza AT, Jedidi A, Cavallo L, Takanabe K (2016) Cu–Sn bimetallic catalyst
for selective aqueous electroreduction of CO 2 to CO. ACS Catal 6:2842–2851
29. Katoh A, Uchida H, Shibata M, Watanabe M (1994) Design of electrocatalyst for CO 2 reduction.
V. Effect of the microcrystalline structures of Cu–Sn and Cu–Zn alloys on the electrocatalysis of
CO 2 reduction. J Electrochem Soc 8:2054–2058
30. Kim D, Xie C, Becknell N, Yu Y, Karamad M, Chan K, Crumlin EJ, Nørskov JK, Yang P (2017)
Electrochemical activation of CO 2 through atomic ordering transformations of AuCu nanoparticles. J Am Chem Soc 139:8329–8336
31. Lee H, Kim S-K, Ahn SH (2017) Electrochemical preparation of Ag/Cu and Au/Cu foams for
electrochemical conversion of CO 2 to CO. J Ind Eng Chem 54:218–225
32. Ma M, Hansen HA, Valenti M, Wang Z, Cao A, Dong M, Smith WA (2017) Electrochemical
reduction of CO 2 on compositionally variant Au–Pt bimetallic thin films. Nano Energy 42:51–57
33. Morimoto M, Takatsuji Y, Yamasaki R, Hashimoto H, Nakata I, Sakakura T, Haruyama T (2017)
Electrodeposited Cu–Sn alloy for electrochemical CO 2 reduction to CO/HCOO
− . Electrocatalysis 9:323–332
34. Yoshio H, Akira M, Shin-ya I (1990) Enhanced evolution of CO and suppressed formation of
hydrocarbons in electroreduction of CO 2 at a copper electrode modified with cadmium. Chem
Lett 19:1231–1234
35. Rasul S, Anjum DH, Jedidi A, Minenkov Y, Cavallo L, Takanabe K (2015) A highly selective
copper–indium bimetallic electrocatalyst for the electrochemical reduction of aqueous CO 2 to
CO. Angew Chem Int Ed 54:2146–2150
36. He J, Dettelbach KE, Salvatore DA, Li T, Berlinguette CP (2017) High-throughput synthesis of
mixed-metal electrocatalysts for CO 2 reduction. Angew Chem Int Ed 56:6068–6072
37. Kim D, Resasco J, Yu Y, Asiri AM, Yang P (2014) Synergistic geometric and electronic effects
for electrochemical reduction of carbon dioxide using gold–copper bimetallic nanoparticles. Nat
Commun 5:4948
38. Li Q, Fu J, Zhu W, Chen Z, Shen B, Wu L, Xi Z, Wang T, Lu G, J-j Zhu, Sun S (2017) Tuning
Sn-catalysis for electrochemical reduction of CO 2 to CO via the core/shell Cu/SnO 2 structure. J
Am Chem Soc 139:4290–4293
39. Sun K, Cheng T, Wu L, Hu Y, Zhou J, Maclennan A, Jiang Z, Gao Y, Goddard WA, Wang Z
(2017) Ultrahigh mass activity for carbon dioxide reduction enabled by Gold–iron Core–Shell
nanoparticles. J Am Chem Soc 139:15608–15611
40. Watanabe M, Shibata M, Kato A, Azuma M, Sakata T (1991) Design of alloy electrocatalysts for
CO 2 reduction: III. The selective and reversible reduction of on Cu alloy electrodes. J Electrochem Soc 138:3382–3389
41. Yoshio H, Akira M, Shin-ya I, Yuzuru Y, Osamu K (1989) Nickel and iron modified copper electrode for electroreduction of CO 2 by in situ electrodeposition. Chem Lett 18:1567–1570
42. Luc W, Jiang C, Chen JG, Jiao F (2018) Role of surface oxophilicity in copper-catalyzed water
dissociation. ACS Catal 8:9327–9333
43. Hammer B, Morikawa Y, Nørskov JK (1996) CO chemisorption at metal surfaces and overlayers.
Phys Rev Lett 76:2141–2144
44. Alayoglu S, Nilekar AU, Mavrikakis M, Eichhorn B (2008) Ru–Pt core–shell nanoparticles for
preferential oxidation of carbon monoxide in hydrogen. Nat Mater 7:333
45. Gorzkowski MT, Lewera A (2015) Probing the limits of d-band center theory: electronic
and electrocatalytic properties of Pd-shell–Pt-core nanoparticles. The J Phys Chem C
119:18389–18395
46. Chen JG, Menning CA, Zellner MB (2008) Monolayer bimetallic surfaces: experimental and theoretical studies of trends in electronic and chemical properties. Surf Sci Rep 63:201–254
Reprinted from the journal
123