Fairlamb IJS, Lee AF (2013) Chapter 3. Fundamental Pd0/PdII redox steps in cross-coupling
reactions: homogeneous, hybrid homogeneous–heterogeneous to heterogeneous mechanistic
pathways for C–C couplings. In: C–H and C–X bond functionalization. RSC, Cambridge,
pp 72–107. Discusses homogeneous and potential heterogeneous and components to catalytic
reactivity, focusing on classical cross-coupling processes
Pla D, Gomez M (2016) Metal and metal oxide nanoparticles: a lever for CÀH functionalization.
ACS Catal 6:3537–3552. Heterogeneous C–H-bond activation and functionalisation catalysis,
including Pd, Ru and CuNPs, focussing on ‘unactivated’ C–(sp
3
)H (a few examples) and C–
(sp
2
)H bonds
Reay A, Fairlamb IJS (2015) Catalytic C–H bond functionalisation chemistry: the case for quasiheterogeneous catalysis. Chem Commun 51:16289–16307. A discussion of heterogeneous
includes a wealth of practical examples of heterogeneous catalytic C–H bond functionalisation
chemistry
Santoro S, Ferlin F, Luciani L, Ackerman L, Vaccaro L (2017) Biomass-derived solvents as
effective media for cross-coupling reactions and C–H functionalization processes. Green
Chem 19:1601–1612. A review on use of green biomass-derived solvents or cross-coupling,
includes some heterogeneous catalytic examples
Santoro S, Kozhushkov SI, Ackermann L, Vaccaro L (2016) Heterogeneous catalytic approaches in
C–H activation reactions. Green Chem 18:3471
Pd Nanoparticles in C–H Activation and Cross-coupling Catalysis
205
reactions: homogeneous, hybrid homogeneous–heterogeneous to heterogeneous mechanistic
pathways for C–C couplings. In: C–H and C–X bond functionalization. RSC, Cambridge,
pp 72–107. Discusses homogeneous and potential heterogeneous and components to catalytic
reactivity, focusing on classical cross-coupling processes
Pla D, Gomez M (2016) Metal and metal oxide nanoparticles: a lever for CÀH functionalization.
ACS Catal 6:3537–3552. Heterogeneous C–H-bond activation and functionalisation catalysis,
including Pd, Ru and CuNPs, focussing on ‘unactivated’ C–(sp
3
)H (a few examples) and C–
(sp
2
)H bonds
Reay A, Fairlamb IJS (2015) Catalytic C–H bond functionalisation chemistry: the case for quasiheterogeneous catalysis. Chem Commun 51:16289–16307. A discussion of heterogeneous
includes a wealth of practical examples of heterogeneous catalytic C–H bond functionalisation
chemistry
Santoro S, Ferlin F, Luciani L, Ackerman L, Vaccaro L (2017) Biomass-derived solvents as
effective media for cross-coupling reactions and C–H functionalization processes. Green
Chem 19:1601–1612. A review on use of green biomass-derived solvents or cross-coupling,
includes some heterogeneous catalytic examples
Santoro S, Kozhushkov SI, Ackermann L, Vaccaro L (2016) Heterogeneous catalytic approaches in
C–H activation reactions. Green Chem 18:3471
Pd Nanoparticles in C–H Activation and Cross-coupling Catalysis
205