11. Chernyshev VM, Astakhov AV, Chikunov IE, Tyurin RV, Eremin DB, Ranny GS,
Khrustalev VN, Ananikov VP (2019) Pd and Pt catalyst poisoning in the study of reaction
mechanisms: what does the mercury test mean for catalysis? ACS Catal 9:2984–2995
12. Chiba M, Thanh MN, Hasegawa Y, Obora Y, Kawasaki H, Yonezawa T (2015) Synthesis of
binary solid solution Cu–Pd nanoparticles by DMF reduction for enhanced photoluminescence
properties. J Mater Chem C 3:514–520
13. Clark JR, Feng K, Sookezian A, White MC (2018) Manganese-catalysed benzylic C(sp3)–H
amination for late-stage functionalization. Nat Chem 10:583–591
14. Collins G, Schmidt M, O’Dwyer C, Holmes JD, McGlacken GP (2014) The origin of shape
sensitivity in palladium-catalyzed Suzuki–Miyaura cross coupling reactions. Angew Chem Int
Ed 53:4142–4145
15. Collins KD, Honeker R, Vásquez-Céspedes S, Tang D-TD, Glorius F (2015) C–H arylation of
triphenylene, naphthalene and related arenes using Pd/C. Chem Sci 6:1816–1824
16. Crabtree RH (2012) Resolving heterogeneity problems and impurity artifacts in operationally
homogeneous transition metal catalysts. Chem Rev 112:1536–1554
17. Crabtree RH, Lei A (2017) Introduction: CH activation. Chem Rev 117:8481–8482
18. Crabtree RH, Mingos DM (2007) Comprehensive organometallic chemistry III: from fundamentals to applications, vol 5. Elsevier Science, Amsterdam
19. De Ornellas S, Williams TJ, Baumann CG, Fairlamb IJS (2013) Chapter 12. Catalytic C–H/C–
X bond functionalisation of nucleosides, nucleotides, nucleic acids, amino acids, peptides and
proteins. In: C–H and C–X bond functionalization: transition metal mediation. RSC Publishing,
Cambridge, pp 409–447
20. de Vries AHM, Mulders JMCA, Mommers JHM, Henderickx HJW, de Vries JG (2003)
Homeopathic ligand-free palladium as a catalyst in the heck reaction. A comparison with a
palladacycle. Org Lett 5:3285–3288
21. Deraedt C, Astruc D (2014) “Homeopathic” palladium nanoparticle catalysis of cross Carbon–
Carbon coupling reactions. Acc Chem Res 47:494–503
22. Dey A, Sinha SK, Achar TK, Maiti D (2018) Game of directors: accessing remote meta- and
Para-C--H bonds with covalently attached directing groups. Angew Chem Int Ed 58
(32):10820–10843
23. Eisenstein O, Milani J, Perutz RN (2017) Selectivity of C–H activation and competition
between C–H and C–F bond activation at fluorocarbons. Chem Rev 117:8710–8753
24. Ellis PJ, Fairlamb IJS, Hackett SFJ, Wilson K, Lee AF (2010) Evidence for the surfacecatalyzed Suzuki–Miyaura reaction over palladium nanoparticles: an operando XAS study.
Angew Chem Int Ed 49:1820–1824
25. Eremin DB, Ananikov VP (2017) Understanding active species in catalytic transformations:
from molecular catalysis to nanoparticles, leaching, “cocktails” of catalysts and dynamic
systems. Coord Chem Rev 346:2–19
26. Fairlamb IJS (2005) Palladium catalysis in synthesis: where next? Tetrahedron 61:9661–9662
27. Fairlamb IJS (2016) Chapter 11. Pd-catalysed cross-couplings for the pharmaceutical sector and
a move to cutting-edge C–H bond functionalization: is palladium simply too precious? In:
Green and sustainable medicinal chemistry. Royal Society of Chemistry (RSC) Publishing,
Cambridge, pp 129–139
28. Fairlamb IJS, Lee AF (2013) Chapter 3. Fundamental Pd0/PdII redox steps in cross-coupling
reactions: homogeneous, hybrid homogeneous–heterogeneous to heterogeneous mechanistic
pathways for C–C couplings. In: Ribas X (ed) C–H and C–X bond functionalization: transition
metal mediation. RSC, Cambridge, pp 72–107
29. Ferlin F, Santoro S, Ackermann L, Vaccaro L (2017) Heterogeneous C–H alkenylations in
continuous-flow: oxidative palladium-catalysis in a biomass-derived reaction medium. Green
Chem 19:2510–2514
30. Gaikwad AV, Rothenberg G (2006) In-situ UV-visible study of Pd nanocluster formation in
solution. Phys Chem Chem Phys 8:3669–3675
Pd Nanoparticles in C–H Activation and Cross-coupling Catalysis
201
Khrustalev VN, Ananikov VP (2019) Pd and Pt catalyst poisoning in the study of reaction
mechanisms: what does the mercury test mean for catalysis? ACS Catal 9:2984–2995
12. Chiba M, Thanh MN, Hasegawa Y, Obora Y, Kawasaki H, Yonezawa T (2015) Synthesis of
binary solid solution Cu–Pd nanoparticles by DMF reduction for enhanced photoluminescence
properties. J Mater Chem C 3:514–520
13. Clark JR, Feng K, Sookezian A, White MC (2018) Manganese-catalysed benzylic C(sp3)–H
amination for late-stage functionalization. Nat Chem 10:583–591
14. Collins G, Schmidt M, O’Dwyer C, Holmes JD, McGlacken GP (2014) The origin of shape
sensitivity in palladium-catalyzed Suzuki–Miyaura cross coupling reactions. Angew Chem Int
Ed 53:4142–4145
15. Collins KD, Honeker R, Vásquez-Céspedes S, Tang D-TD, Glorius F (2015) C–H arylation of
triphenylene, naphthalene and related arenes using Pd/C. Chem Sci 6:1816–1824
16. Crabtree RH (2012) Resolving heterogeneity problems and impurity artifacts in operationally
homogeneous transition metal catalysts. Chem Rev 112:1536–1554
17. Crabtree RH, Lei A (2017) Introduction: CH activation. Chem Rev 117:8481–8482
18. Crabtree RH, Mingos DM (2007) Comprehensive organometallic chemistry III: from fundamentals to applications, vol 5. Elsevier Science, Amsterdam
19. De Ornellas S, Williams TJ, Baumann CG, Fairlamb IJS (2013) Chapter 12. Catalytic C–H/C–
X bond functionalisation of nucleosides, nucleotides, nucleic acids, amino acids, peptides and
proteins. In: C–H and C–X bond functionalization: transition metal mediation. RSC Publishing,
Cambridge, pp 409–447
20. de Vries AHM, Mulders JMCA, Mommers JHM, Henderickx HJW, de Vries JG (2003)
Homeopathic ligand-free palladium as a catalyst in the heck reaction. A comparison with a
palladacycle. Org Lett 5:3285–3288
21. Deraedt C, Astruc D (2014) “Homeopathic” palladium nanoparticle catalysis of cross Carbon–
Carbon coupling reactions. Acc Chem Res 47:494–503
22. Dey A, Sinha SK, Achar TK, Maiti D (2018) Game of directors: accessing remote meta- and
Para-C--H bonds with covalently attached directing groups. Angew Chem Int Ed 58
(32):10820–10843
23. Eisenstein O, Milani J, Perutz RN (2017) Selectivity of C–H activation and competition
between C–H and C–F bond activation at fluorocarbons. Chem Rev 117:8710–8753
24. Ellis PJ, Fairlamb IJS, Hackett SFJ, Wilson K, Lee AF (2010) Evidence for the surfacecatalyzed Suzuki–Miyaura reaction over palladium nanoparticles: an operando XAS study.
Angew Chem Int Ed 49:1820–1824
25. Eremin DB, Ananikov VP (2017) Understanding active species in catalytic transformations:
from molecular catalysis to nanoparticles, leaching, “cocktails” of catalysts and dynamic
systems. Coord Chem Rev 346:2–19
26. Fairlamb IJS (2005) Palladium catalysis in synthesis: where next? Tetrahedron 61:9661–9662
27. Fairlamb IJS (2016) Chapter 11. Pd-catalysed cross-couplings for the pharmaceutical sector and
a move to cutting-edge C–H bond functionalization: is palladium simply too precious? In:
Green and sustainable medicinal chemistry. Royal Society of Chemistry (RSC) Publishing,
Cambridge, pp 129–139
28. Fairlamb IJS, Lee AF (2013) Chapter 3. Fundamental Pd0/PdII redox steps in cross-coupling
reactions: homogeneous, hybrid homogeneous–heterogeneous to heterogeneous mechanistic
pathways for C–C couplings. In: Ribas X (ed) C–H and C–X bond functionalization: transition
metal mediation. RSC, Cambridge, pp 72–107
29. Ferlin F, Santoro S, Ackermann L, Vaccaro L (2017) Heterogeneous C–H alkenylations in
continuous-flow: oxidative palladium-catalysis in a biomass-derived reaction medium. Green
Chem 19:2510–2514
30. Gaikwad AV, Rothenberg G (2006) In-situ UV-visible study of Pd nanocluster formation in
solution. Phys Chem Chem Phys 8:3669–3675
Pd Nanoparticles in C–H Activation and Cross-coupling Catalysis
201